Angewandte Chemie International Edition
Articles in this Issue
Phenothiazine‐Phenoxazine Hybrid Cross Hole‐Transporting Material for High Performance Perovskite Solar Cell
Abstract Hole transport materials (HTMs) critically influence perovskite solar cell (PSC) performance through three key mechanisms: facilitating hole transport,...
Frontispiece: Harnessing the Magic Methyl Effect: Manipulating Photoluminescence and Photochromism of Salicylaldehyde Benzoylhydrazones in the Solid State
Frontispiece: Exceptional Two‐ to Five‐Photon Absorption at Mono/Bis(Donor)‐Porphyrin‐Mono/Bis(Donor) Triads and Pentads
Correction to “Oligoether Chain Engineering in Covalent Organic Frameworks: Enhancing Transport Pathways and Oxygen Reduction Activity for Efficient Electrocatalytic Hydrogen Peroxide Production”
Dual Circularly Polarized Luminescence from Chiral Boron‐Embedded Polycyclic Aromatic Hydrocarbons
Abstract Reversible coordination bonds between boron and heteroatoms endow boron‐based π‐conjugated frameworks with dynamic functionality, as interconversion between tri‐ and tetraco...
(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications
Abstract (Poly)borylated species, molecules bearing multiple carbon–boron groups, have emerged as powerful building blocks in modern synthetic chemistry owing to...
Acid‐ and Nucleophile‐Gated Photoisomerization of Phosphaindirubin
Abstract Nature uses protonation and microenvironmental effects to modulate photoisomerization, as seen in rhodopsins and GFP. Inspired by this, we report phosph...
Ethane Chlorination Toward Vinyl Chloride Synthesis: Mechanistic and Catalytic Perspectives
ABSTRACT Ethane chlorination has emerged as a promising alternative to conventional ethylene‐ and acetylene‐based routes for the production of vinyl chloride monomer (VCM). Unlike co...
Local Polarity Engineering via Unsaturated Cu–N <sub>3</sub> Sites for Enhanced Iodine Redox Chemistry in Zinc‐Iodine Batteries
Abstract Rational engineering of the local microenvironment in catalytic host materials is pivotal for high‐performance zinc‐iodine batteries, as it governs iodi...
Stability Thresholds of Atomically Dispersed Platinum Catalysts for Solar Hydrogen Production
Abstract The structural fluidity of single‐atom photocatalysts under illumination challenges conventional assumptions about catalytic identity, prompting a reeva...
Electron Cloud Polarization of Single‐Atom Cu Boosts Electrocatalytic Reduction of High‐ and Low‐Concentration CO <sub>2</sub> to Methanol
ABSTRACT Catalysis of the conversion of CO 2 from industrial exhaust gases to methanol at dynamically varying concentrati...
Regulating Lithium Bond to Reduce Polysulfide Parasitic Reactivity for High‐Stability Lithium Metal Anode
ABSTRACT Lithium–sulfur (Li–S) batteries hold great potential as high‐energy‐density energy storage devices, yet their practical application is hindered by rapid...
Rhodium‐Catalyzed Enantioselective Synthesis of Planar‐Chiral Macrocycles via De Novo Isoquinoline Formation
ABSTRACT De novo formation of the aromatic ring is an attractive strategy for atroposelective synthesis, but its application to planar‐chiral macrocycles remains challenging. Herein,...
Multi‐Scale Architecture Regulation of Hard Carbons for High‐Efficiency Sodium Storage Across Ambient and Subzero Conditions
ABSTRACT Hard carbons, despite their cost‐efficient production and precursor availability, face critical electrochemical performance constraints from excessive d...
Deciphering the Transition From Tunneling to Band‐Like Transport in Protein‐Templated Biohybrid Junctions
ABSTRACT Protein‐templated metal nanoclusters (MNCs) offer a unique strategy for integrating the structural precision of biological scaffolds with the quantum electronic characterist...
Dual Chemical Looping/Catalytic Process for Alkylation of Benzene With Ethane and Propane Yielding Ethylbenzene and Cumene Over Copper‐Containing Mordenite
ABSTRACT Given the sustained demand for alkylated aromatics and the strained olefin market, there is an urgent need to develop efficient one‐step processes for the direct alkylation...
From Phenols to Proteins: One‐Pot Biosynthesis and Genetic Encoding of Chalcogen‐Containing Tyrosine Analogues
ABSTRACT Expanding the genetic code with unnatural amino acids (UAAs) offers powerful opportunities to engineer proteins with novel redox and catalytic functions...
Phosphorus‐Induced Charge Redistribution and Lattice Self‐Regulation in Cu <sub>3</sub> PSe <sub>4</sub> Enables Low <i>N</i> / <i>P</i> Ratio and Durable Zn–I <sub>2</sub> Batteries
ABSTRACT Zn–I 2 batteries is a promising large‐scale energy storage technology, yet conventional Zn metal anode faces cha...
Molecular Electrocatalyst Enables Direct Electrochemical Capture and Conversion of CO <sub>2</sub> up to Atmospheric Concentration
ABSTRACT The conversion of low‐concentration CO 2 streams into fuel is highly desirable for industrial applications, avoi...
Biocatalytic Regioselective C‐Formylation of Resorcinol Derivatives
ABSTRACT Although aromatic formylation reactions are highly valuable from a synthetic perspective, a biocatalytic version has not yet been reported. Here, the co...
Construction of Agonistic Bivalent Double‐Stranded Aptamers Targeting c‐MET
ABSTRACT Aptamers, single‐stranded oligonucleotides selected via SELEX technology, exhibit high‐affinity and selective binding to target molecules by folding into specific intramolec...
Exceptional Two‐ to Five‐Photon Absorption at Mono/Bis(Donor)‐Porphyrin‐Mono/Bis(Donor) Triads and Pentads
Abstract Porphyrins are key components of biologically‐active molecules involved in oxygen transport, light harvesting, and electron transfer; their photophysical properties are cons...
Highly Efficient Deep‐Blue Room‐Temperature Phosphorescence With Tunable Long‐Lived Afterglow and Reversible Photoactivation Behavior
ABSTRACT Wide band gap organic molecule with ultralong room‐temperature phosphorescence (RTP) remains a big challenge in optoelectronic field due to the intrinsi...
Iridium‐Catalyzed Enantioselective Allylation of Alkynylboronates to Access Chiral 1,4‐Dienes
ABSTRACT Skipped dienes, particularly 1,4‐dienes, play significant roles in pharmaceuticals and organic synthesis as they serve as key intermediates for the cons...
Enzyme‐Mimicking Metal–Phosphide Tandem Catalytic Centers for Efficient Electrochemical Nitrate‐to‐Ammonia Conversion and Zinc–Nitrate Battery
ABSTRACT Achieving spatially coupled and functionally complementary active sites in synthetic catalysts remains a significant challenge. Inspired by the enzymati...