Angewandte Chemie International Edition
Articles in this Issue
Dual‐ <i>Sabatier</i> Optima: How Reaction Mechanism Determines Activity Volcano Map of Dual‐Atom Catalysts for Oxygen Reduction Reaction
ABSTRACT Dual‐atom catalysts (DACs) have demonstrated superior potential in the oxygen reduction reaction (ORR). However, the single‐peak activity volcano derive...
Regio‐ and Site‐Selective Organic Synthesis With Single‐Atom Catalysts
ABSTRACT Organic synthesis underpins the manufacture of pharmaceuticals, agrochemicals, and advanced materials. A key challenge is to selectively transform a specific region or site...
Contra‐Diffusion Engineering of Single‐Atom Catalytic Interlayers Enables Reversible Sulfur Redox Chemistry
ABSTRACT Achieving durable lithium–sulfur batteries with minimal catalyst loading remains challenging, particularly for interlayer designs where catalytic effici...
High‐Throughput Single‐Cell‐Resolved Spatial Proteomics Enabled by an Ordered Colloidal Crystal Column
ABSTRACT Spatial proteomics is essential to elucidate biological function and pathogenesis, for which nanoLC–MS coupled with tissue microdissection is a powerful...
Multicomponent C−H Activation/Annulation Polymerizations Toward Structurally Regular Polyelectrolytes With Light‐Boosted Antibacterial Potency
ABSTRACT C−H activation/annulation polymerization (CAAP) has emerged as a powerful synthetic tool toward heteroaromatic polyelectrolytes, but its broader applica...
Synergistic Modulation of Triplet Density and Heavy‐Atom Effect Accelerates Reverse Intersystem Crossing for Narrowband Multi‐Resonance TADF Emitters
ABSTRACT Combining rapid triplet‐to‐singlet spin conversion with BT.2020‐relevant color purity in a single purely organic emitter remains a major challenge for O...
Minimal ATP‐Independent N <sub>2</sub> ‐Reducing Systems Defined by L‐Cluster‐Bound Nitrogenase Assembly Platforms
ABSTRACT The Mo‐nitrogenase, which consists of a reductase component (NifH) and a catalytic component (NifDK), catalyzes ATP‐dependent reduction of N...
Dual Polyamide Thin‐Film Composite Membrane With Multiscale Hetero‐Channels and Mosaic Charge Architecture for Boosting Ion Transport and Osmotic Energy Conversion
ABSTRACT Asymmetric ion‐selective membranes show promise for efficient osmotic energy harvesting. Most current asymmetric membranes adopt a bipolar structure to...
Engineering Plasmon‐Semiconductor Coupling in Spatially Ordered Supraparticles for Boosted Photocatalytic Hydrogen Evolution
ABSTRACT Organizing distinct nanocomponents into spatially ordered architectures offers a powerful strategy to regulate light‐matter interactions and enhance pho...
Rational Design of a {InCu <sub>6</sub> } Heterometallic Oxo Cluster for Superior Proton Conduction: Mechanistic Insights and Humidity Gradient‐Based Power Generation
ABSTRACT This study employs a template‐directed assembly strategy to synthesize the first In 3+ /Cu 2...
Unexpected Spontaneous Photochemical Formation of Hydrogen Peroxide in Water Microdroplets on Silicate Mineral Surfaces
ABSTRACT Hydrogen peroxide (H 2 O 2 ) is a vital reactive oxygen species with sig...
Mechanically Activated Luminescence in Polyurethanes Incorporating Calixarene Mechanophores
ABSTRACT The conformational properties of cone calix[4]arenes are exploited to develop the first example of a calixarene‐...
Electrochemical Divergent Synthesis of Azetidines via Strain Release of 1‑Azabicyclo[1.1.0]butanes
ABSTRACT Due to the favorable pharmaceutical properties of the azetidine ring, it can serve as a bioisostere to replace saturated heterocycles such as piperazine...
Harnessing Point–Planar Chirality Synergy: Crystallization‐Enabled Resolution of Pillar[5]arene Rotaxanes With Tunable Circularly Polarized Luminescence
ABSTRACT Immobilizing the planar chirality inherent to pillar[5]arene remains a challenge in supramolecular chemistry. Herein, we report a rational strategy for...
Subporphyrin Frameworks: A Missing Link Between Porphyrinoids and Porous Aromatic Networks
ABSTRACT Subporphyrins represent a distinctive class of bowl‐shaped, π‐conjugated, and intrinsically electron‐deficient macrocycles that exhibit photophysical and coordination behavi...
Green‐Emissive Ferroelectric Optical Thermometer Based on Cyclometalated Dicyanidoplatinate(II) Ions
ABSTRACT Multifunctional ferroelectrics combine switchable permanent polarization with other physical functionalities. Among them, luminescent ferroelectrics are...
Constructing Robust Cl‐Bridge for Ultrafast Leaching of Spent Cathodes in 180 s
ABSTRACT Reductive coordination medium, especially Cl − , play a pivotal role in leaching processes for spent batteries r...
NaO <sub>6</sub> Octahedron‐Engineered Sodium Iron Sulfate Cathodes for High‐Rate and Sustainable Sodium‐Ion Batteries
ABSTRACT The alluaudite‐type sulfate Na 2 Fe 2 (SO 4...
Highly Efficient Mechanochromic Thermally Activated Delayed Fluorescence in the Deep Red to Near‐Infrared in Copper(I) [2.2]Isoindolinophanyl‐Carbene Carbazolates
ABSTRACT Low energy triplet emitters are highly relevant for the development of OLEDs and fiber optics‐based IT applications, but typically suffer from nonradiat...
<i>o</i> ‐Terphenyl‐Based Family of Conjugated Macrocycles: Selective Recognition of Phenylalanine in Water and Interaction With Insulin
ABSTRACT The design of supramolecular receptors for amino acids presents a fundamentally challenging yet highly promising avenue of research. Phenylalanine attra...
Twisted Nanoribbon‐Like Electron Acceptor With Suppressed Non‐Radiative Loss and Seed‐Assisted Crystallization for High‐Efficiency Organic Solar Cells
ABSTRACT While large π‐conjugated nanoribbons possess highly tunable electronic properties, their potential in high‐performance organic photovoltaics (OPVs) rema...
Monoselective Mechanochemical Aromatic Nucleophilic Substitution Enabled by Crystal‐Engineering‐Guided Reaction Design
ABSTRACT Mechanochemical solid‐state organic transformations using ball milling not only represent a sustainable and efficient synthetic approach but also exhibi...
Bioinspired Starch‐Polyiodide Electrolytes for Self‐Healing Lithium‐Metal Interfaces and Stable Photoelectrochemical Energy Storage
ABSTRACT The development of high‐energy‐density power sources with integrated energy harvesting capabilities is crucial for advancing wearable electronics. Herein, inspired by the ho...
A Cu–La Dual‐Atomic Catalyst With Dual‐Site Adsorption Enables Synergistic Optimization of Thermodynamics and Kinetics of Electrocatalytic CO <sub>2</sub> Reduction
ABSTRACT Single‐atomic catalysts face the following major challenges in the rapidly advancing field of electrocatalytic CO 2...
Atomic‐Precision Engineering and Visualizing of Chiral Electronic States in Nitrogen‐Doped Nanographenes
ABSTRACT As a fundamental phenomenon in nature, chirality has been extensively studied in molecular structures; however, it remains underexplored at the electron...