Angewandte Chemie International Edition
Articles in this Issue
In Situ Tracking of Programmable Reconstruction in Metal‐Organic Frameworks Toward Ampere‐Level Urea Oxidation
ABSTRACT Understanding the dynamic evolution of catalyst coordination structures during electrochemical nucleophilic oxidation reactions (NORs) is essential for...
Correction to “Discovery of Selective and Potent ATR Degrader for Exploration Its Kinase‐Independent Functions in Acute Myeloid Leukemia Cells”
Biomimetic Supramolecular Assemblies With Programmable Structural and Chiroptical Dynamics
ABSTRACT The kinetic–thermodynamic synergy in protein folding has inspired out‑of‑equilibrium nanostructures; however, precise control and real‑time visualizatio...
Accelerating SuFEx Reactions via Aryl Fluorosulfate Structural Engineering for Enhanced Covalent Targeted Cancer Therapy
ABSTRACT Aryl fluorosulfate warheads, possessing sulfur(VI) fluoride exchange (SuFEx) reaction, hold significant promise for the development of covalent protein...
A High‐Performance, Low‐Cost and Recyclable Solid Electrolyte for Practical All‐Solid‐State Lithium‐Based Batteries
ABSTRACT The commercialization of all‐solid‐state lithium metal batteries (ASSLMBs) is constrained by the absence of a suitable solid electrolyte (SE) that simul...
Synergy Between Ru <sub>3</sub> Nanoclusters and Pt Nanoparticles for High‐Efficiency Alkaline Hydrogen Evolution Reaction
ABSTRACT To achieve efficient alkaline hydrogen evolution reaction (HER), catalysts should be rationally designed with optimized water adsorption energy, low H‐O...
Converting One In Vitro Selected DNA Molecule Into Two Bacteria‐Responsive DNAzymes by Regulation of Reaction Conditions
ABSTRACT Bacteria‐responsive DNAzymes have been widely used in pathogen detection. We report a “one stone, two birds” strategy that uses one selected DNA molecul...
Cation Modulation of Layered Self‐Assembled Polyoxometalates Enables Efficient and Robust Hydrogen Evolution
ABSTRACT Superstructures assembled from polyoxometalate (POM) with alkyl trimethyl ammonium bromide (TAB) surfactants have generated rising attention owing to th...
Andrey Lvov
Site‐Dependent Hydrogen Adsorption of Pt Single Atoms for Ampere‐Level Alkaline Hydrogen Evolution
ABSTRACT The intermediate adsorption on single‐atom sites critically governs the catalytic performance of single‐atom catalysts. Site‐specific single atoms exhib...
Atomically Dispersed Mn Synergized With LiBaH <sub>3</sub> on MgO Enables Efficient Ammonia Synthesis via an H <sup>−</sup> Assisted N <sub>2</sub> Dissociation Mechanism
ABSTRACT Ammonia is an essential chemical feedstock and a promising hydrogen energy carrier, motivating the development of efficient ammonia synthesis catalysts....
Supramolecular Near‐Infrared Photocatalysts for Efficient and Oxygen‐Tolerant Aqueous RAFT Polymerization
ABSTRACT Near‐infrared (NIR) photocontrolled polymerization in aqueous media is promising for bioapplications. However, it typically suffers from low polymerization efficiency and re...
Electrochemically‐Triggered Spin Switching Enables Anti‐Passivation of Active Sites in Lithium–Sulfur Catalytic Chemistry
ABSTRACT The irreversible accumulation of insulating Li 2 S in lithium–sulfur batteries (LSBs) constitutes a central bott...
Automated Dynamic Flow Experimentation for Rapid Kinetic Fitting of Transition Metal Catalysis
ABSTRACT Automated flow platforms are well‐established in the context of chemical reaction optimization leveraging techniques such as Design of Experiments and self‐optimization. How...
Skeletal Rearrangement of Indazoles to Indoles With α‐Trifluoromethyl Diazosilanes
ABSTRACT Heterocycle interconversion represents a powerful strategy for molecular diversification. Despite its potential, the direct conversion of indazoles into...
Acidic Electron Acceptors in Imine‐Linked Covalent Organic Framework for Enhanced Gas Sensing With Field‐Effect Transistor Evaluation
ABSTRACT Semiconducting covalent organic frameworks (COFs) that combine structural order with porous characteristics are promising candidates for chemiresistive...
Controlling Exsolution Dynamics in High‐Entropy Oxides for Highly Active and Selective Acetylene Semi‐Hydrogenation
ABSTRACT Exsolution‐derived catalysts feature robust metal–support interactions that enhance catalytic performance; yet achieving precise control over exsolution...
Light‐Activated Isolation of High‐Quality Mitochondria for Therapeutic Transplantation
ABSTRACT Artificial mitochondrial transplantation (AMT) holds great promise for reprogramming cellular metabolism and restoring cell function. Its clinical trans...
Boosting Formic Acid Production in Methane Oxidation by Zeolite Confined Single‐Site Rh Catalyst
ABSTRACT The selective oxidation of methane to value‐added oxygenates remains a long‐standing challenge in catalysis, often constrained by poor reactivity (and s...
Mechanically Adaptive Polyrotaxane Interlayers for Low‐Pressure High Energy Density Sulfide‐Based All‐Solid‐State Batteries
ABSTRACT All‐solid‐state batteries (ASSBs) employing lithium (Li) metal anodes or an anode‐less configuration, despite their superior energy density, suffer from...
Porous Organic Cages for CO <sub>2</sub> Capture and Confined Reduction
ABSTRACT Porous organic cages (POCs) are discrete molecular materials that combine intrinsic porosity with solution processability and well‐defined, chemically t...
Molecular Bridge Enables Dual‐Intermediate Synergy for Selective CO <sub>2</sub> Electroreduction to Multicarbon Products
ABSTRACT CO 2 electroreduction to multicarbon products offers a sustainable pathway for chemical synthesis, yet its pract...
Comment on “Can Charge Transfer Across C─H···O Hydrogen Bonds Stabilize Oil Droplets in Water?”
ABSTRACT Kinetically stable oil nanodroplets in water display an electrophoretic mobility linked to a negative surface charge. The source of this charge is propo...
Role of Water in Low‐Temperature CO <sub>2</sub> Reduction at Defect‐Rich TiO <sub>2</sub>
ABSTRACT Point defects in titanium dioxide (TiO 2 ) are the most relevant reaction sites for the activation of oxygenates...
Enzymatic Encoding of Topology in an Intrinsically Disordered Single‐Chain Protein
ABSTRACT Controlling the three‐dimensional topology of single‐chain nanoparticles (SCNPs) remains a central challenge in polymer and protein chemistry, particularly for intrinsically...