Angewandte Chemie International Edition
Articles in this Issue
Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations
ABSTRACT Mechanochemistry and transition‐metal catalysis are converging into a platform in which mechanical energy reshapes catalyst formulation, speciation, and...
Phosphoryl Radicals from Trivalent Iminyl Phosphines: A Photocatalytic Approach to <i>N</i> ‐Phosphoryl Azetidines
ABSTRACT We report that iminyl phosphines, a class of bench‐stable and readily accessible trivalent P‐centered radical precursors, enable the synthesis of N‐phosphoryl azetidines via...
Spin‐State Dichotomy of On‐Cycle Cobalt(II) Organometallics Informs Polar Cobalt(0/II) Versus Radical Cobalt(I/II/III) Cross‐Coupling Mechanisms
ABSTRACT A well‐defined, single‐component precatalyst N , N ,...
Hierarchically Chiral Silver Nanoclusters Mediated Enantioselective Glutathione Depletion and Intracellular Self‐Assembly for Enhanced Anticancer Therapy
ABSTRACT Chiral nanomedicine design benefits from understanding enantioselective interactions between hierarchically chiral nanoclusters and tumor biomarkers. In...
In Situ Converted High‐Loading Membranes With Molecularly Dispersed Porous Organic Cages for Superior CO <sub>2</sub> /N <sub>2</sub> Separation
ABSTRACT Porous organic cages (POCs) based mixed‐matrix membranes with characteristics of molecular‐size pores and operation efficiency are promising for gas sep...
Unlocking Low‐Energy‐Barrier Pathways via Monoclinic Acceptor Induction for Homogeneous Regeneration of Spent LiMn <i> <sub>x</sub> </i> Fe <sub>1‐</sub> <i> <sub>x</sub> </i> PO <sub>4</sub> Cathodes
ABSTRACT As the next‐generation olivine‐type cathode, high energy‐density LiMn x...
Engineering Multiple Hydrogen‐Bond Sites With D‐π‐A Motifs for Strong Optical Nonlinearity and Giant Birefringence in Organic‐Inorganic Halides
ABSTRACT Organic‐inorganic metal halides (OIMHs) have emerged as promising nonlinear optical (NLO) materials, but simultaneously achieving large birefringence (Δ...
A Mononuclear Ruthenium(V)‐Imido Complex With Hydrogen Bonding in the Second Coordination Sphere Forming Aziridines Without <i>N</i> ‐Substituents From Alkenes in Water
ABSTRACT Aziridines are class of organic molecules that have a nitrogen‐containing three‐membered ring structure. These heterocyclic compounds have garnered rece...
Data‐Driven Approach to Understanding Tetrabutylammonium Decatungstate‐Catalyzed C(sp <sup>3</sup> )–H Functionalization Selectivity
ABSTRACT Photocatalytic hydrogen atom transfer (HAT) has emerged as a powerful strategy for selective C(sp 3 )–C bond for...
Biobased Cyclic Enoate Monomers: Enabling Intrinsically Crystalline, Chemically Recyclable, Ultratough Polymers
ABSTRACT Chemically recyclable polymers that depolymerize back to their monomers offer a promising alternative to non‑recyclable petroleum‑based plastics. Howeve...
Light‐Inducible Bispecific DNAzymes Reveal Mitochondrial Fe <sup>2+</sup> /Fe <sup>3+</sup> Dynamics During Ferroptosis
ABSTRACT Mitochondrial iron redox homeostasis plays critical roles in cellular function and disease progression; however, spatiotemporal measurement of Fe...
Metal‐Free Active Template: A Straightforward Route to 4‐Aminopyridinium‐Based Rotaxane Molecular Shuttles
ABSTRACT We report on the metal‐free active template synthesis of [2]rotaxanes through nucleophilic aromatic substitution between an amine and halogenopyridinium derivatives in the p...
Combining High‐Throughput Experimentation and Automated Flow for Bayesian Optimization of a Metallaphotoredox Reaction
ABSTRACT In this work, a metallaphotoredox C(sp 2 )–C(sp 3 ) coupling between ary...
Iodide Anion Anchoring by Silver Nanoparticles Enables Shuttle‐Free Zinc‐Iodine Batteries
ABSTRACT Zinc‐iodine (Zn‐I 2 ) batteries are gaining popularity due to cost‐effectiveness and ease of manufacturing. Howe...
Nitrile‐Assisted Hybrid‐Solvation Electrolyte Enables Wide‐Temperature, High‐Voltage, and Ultrafast‐Charging Lithium‐Metal Batteries
ABSTRACT The stable operation of lithium metal batteries (LMBs) requires simultaneous stabilization of anode and cathode interfaces, a challenge that intensifies...
Inside Back Cover: Large‐Diameter DNA‐Scaffolded Nanopores Enabled by Loosely Packed Peptides for Single‐Molecule Sensing (Angew. Chem. Int. Ed. 29/2026)
A >25 kDa Star‐Shaped Dodecamer Acceptor as a Heterogeneous Nucleation Agent Enables 20.50%‐Efficient Organic Solar Cells
ABSTRACT Star‐shaped molecules possess strong cohesive energy and welldefined molecular weights compared to polymers, making them promising additives for regulat...
Outside Back Cover: Facet‐Dependent Water Inhibition of Alkanol Dehydration on TiO <sub>2</sub> via Distinct Water–Alkanol Complexes (Angew. Chem. Int. Ed. 29/2026)
Orientation‐Entropy‐Mediated Derivative Cu Sites for Selective CO <sub>2</sub> Electroreduction to Ethylene
ABSTRACT Electrocatalytic conversion of CO 2 to ethylene (C 2 H...
Large‐Diameter DNA‐Scaffolded Nanopores Enabled by Loosely Packed Peptides for Single‐Molecule Sensing
ABSTRACT Creating alternative nanopores is crucial for advancing single‐molecule methodologies. Peptide nanopores scaffolded by DNA nanostructures have emerged as a promising class o...
Solvent‐Assisted Preparation of Recyclable Multidimensional Fluorescent Actuators
ABSTRACT Light‐responsive elastic crystals and polymers are widely used in the fabrication of smart actuators. However, crystal morphology, which is strongly dep...
Cyano‐Triggered Strong Anion‐π Interactions: Unlocking Anion–Cation Adsorption Bifunction
ABSTRACT Due to the inherent differences in anion and cation adsorption mechanisms, designing a single Faradaic material that functions as an efficient symmetric...
Thermostable Bioluminescent Intercalating Dyes for Real‐Time, Integrated Nucleic Acid Amplification and Detection
ABSTRACT Integrated nucleic acid amplification and detection methods that can be conducted at the point of care are critical to advancing infectious disease diagnostics. We previousl...
Facet‐Dependent Water Inhibition of Alkanol Dehydration on TiO <sub>2</sub> via Distinct Water–Alkanol Complexes
ABSTRACT Water is ubiquitous in biomass‐derived feeds, yet its molecular impact on oxygen‐elimination reactions remains poorly understood, particularly for catal...
Photoredox‐Catalyzed Chem‐ and Stereoselective Thiosulfonylation of Cyclopropylamides
ABSTRACT While the thiosulfonylation of C─C π‐bonds is well‐established, the analogous functionalization of kinetically inert C─C σ‐bonds remains a formidable challenge, particularly...