Angewandte Chemie International Edition
Articles in this Issue
Ultrafast and Persistent Electrolyte Acid Scavenger for Stable High‐Voltage Lithium Batteries
ABSTRACT Hydrofluoric acid (HF) generation in carbonate‐based electrolytes with LiPF 6 is a primary failure cause in high...
Beyond <i>para</i> ‐ and <i>meta</i> ‐Substitution: Synthesis and Biological Validation of Chalcogen‐Rich Thiabicyclo[3.1.1]heptanes as Bioisosteres of Aryl Thioether Derivatives
ABSTRACT While bicyclo[3.1.1]heptanes (BCHeps) and oxa‐/aza‐BCHeps have emerged as valuable arene bioisosteres, the corresponding thia‐analogs remain underdevelo...
Revealing Spatially Resolved Exciton Dynamics of Dual Active Centers for Dehydrogenation Oxidation of Benzyl Alcohol Coupled by Hydrogen Evolution
ABSTRACT Photooxidation of biomass alcohols coupling H 2 evolution has received increasing attention due to its higher ec...
Selenium‐Atom‐Enhanced Triplet Exciton Kinetics in MR‐TADF Photocatalysts for Ultrafast, High‐Resolution, and Open‐Air 3D Printing
ABSTRACT The photoinitiating system is a decisive factor governing the speed, resolution, and operational robustness of digital light processing (DLP) 3D printin...
Molecular Pinning Effect in Composite Self‐Assembled Monolayers Enabling Efficient Perovskite/TOPCon Tandem Solar Cells
ABSTRACT Perovskite‐based single junction and tandem solar cells (TSCs) based on self‐assembled monolayers (SAMs) still suffer from interfacial losses related to...
Defect‐Engineered Metal–Organic Frameworks via Coordination Competition Induction for Long‐Life Aqueous Zinc–Ion Batteries
ABSTRACT Metal–organic frameworks (MOFs) with well‐defined crystalline structures provide ideal platforms for elucidating the intrinsic relationship between stru...
Isolation of a Highly Reactive CBNC Heterocumulene via Azidoborylene Photolysis: Facile Access to a Crystalline Dioxaborirane
ABSTRACT Oxidation of the formal boron(0) complex Me CAAC 2 B in the presence of...
Modulating the Swelling Behavior of Polymer Brushes via Interfacial Chemistry
ABSTRACT Polymer brushes composed of densely grafted end‐tethered polymer chains are often used in the solvent‐swollen state, for example, as boundary lubricants or non‐fouling surfa...
Pyridine C─N Transposition via Cycloaddition–Cycloreversion
ABSTRACT The selective incorporation of nitrogen atoms is fundamental to the design and synthesis of drugs and other functional molecules. Here, we describe a sk...
Halogen Bonding‐Sustained Accumulation of Polyiodide in Hierarchically Open Micellar Film for Shuttle‐Free Long‐Duration Zn‐I <sub>2</sub> Battery
ABSTRACT Polyiodides shuttling normally leads to low coulombic efficiency and rapid capacity fading under extended charging‐discharging durations, thereby limiti...
Facile Preparation of a Poly[2]Catenane Network Using Self‐Assembled [2]Catenane Unit
ABSTRACT Polycatenanes are an emerging class of polymeric materials linked through interlocked rings, possessing a higher degree of conformational freedom and mobility. However, the...
Strong Donor–Acceptor Effect Enables Efficient Polyiodides Confinement and Fast Redox Kinetics Toward Zinc–Iodine Batteries
ABSTRACT Aqueous zinc–iodine batteries (ZIBs) based on iodine (I 2 ) redox conversion suffer from severe polyiodides shut...
Supramolecular‐Derived Heterostructured Carbon Supported with Mo Single Atoms for High‐Capacity and Long‐Cycle Sodium Dual‐Ion Batteries
ABSTRACT Owing to their inherent advantages of high operating voltage, low cost, and environmental friendliness, all‐carbon sodium dual‐ion batteries (SDIBs) are...
Precisely Modulating the Interfacial Oxygen Radicals for Selective Photocatalytic Methane Partial Oxidation to Methanol
ABSTRACT Selective photocatalytic partial oxidation of methane (CH 4 ) under ambient conditions offers a sustainable rout...
Integration of Metal‐Organic Framework With Polymer Electrolyte Enables Efficient and Robust Organic Solar Cells
ABSTRACT Electron transport layers (ETLs) are crucial for reducing the interfacial energy barrier in organic solar cells (OSCs). However, conventional polymer‐ba...
Copper‐Catalyzed Asymmetric Hydroboration of Alkynes to C‐N Axially Chiral Azaborines via Dynamic Kinetic Resolution
ABSTRACT Despite the substantial application potential of C–N axially chiral motifs across diverse fields, and the growing interest in azaborine frameworks owing...
Reenvisioning the De Mayo Reaction: A Boron‐Enabled Cycloaddition Approach
ABSTRACT The De Mayo reaction is an established process in chemical synthesis for the synthesis of 1,5‐dicarbonyls or cyclobutanols in selected cases. Herein, we present a reevisione...