Angewandte Chemie International Edition
Articles in this Issue
Modulating Ni‐O‐V Bridges in NiV‐Layered Double Hydroxides Microspheres for Robust Electrocatalytic Coupling of 1,5‐Pentanediol Oxidation and Nitrate Reduction
ABSTRACT The co‐electrolysis system that couples anodic oxidation of biomass‐derived polyols with cathodic nitrate reduction reaction (NO 3...
Fluorine‐Doped RuO <sub>2</sub> Anchored on TiO <sub>2</sub> via Proton‐Assisted Adsorption Evolution for Efficient and Stable Oxygen Evolution Reaction in Acid
ABSTRACT Although RuO 2 theoretically has superior oxygen evolution reaction (OER) activity and a relatively lower price...
Steering CO <sub>2</sub> Electroreduction to Methane via Secondary‐Sphere Noncovalent Interactions in NHC‐Protected Copper Clusters
ABSTRACT Copper‐based catalysts are promising for CO 2 reduction to hydrocarbons; however, selective CH...
Redirecting Excited‐State Proton Transfer Through Supramolecular Polymerization in Nanoconfinement
ABSTRACT The photoluminescence of photoacids in supramolecular assemblies provides crucial insights into proton transfer (PT) processes within biologically relevant confinement. In t...
Entropy‐Stabilized Aluminate Catalysts That Break the Activity–Stability Tradeoff in CF <sub>4</sub> Hydrolysis
ABSTRACT Tetrafluoromethane (CF 4 ) is a potent, long‐lived greenhouse gas widely used in semiconductor dry‐etching proce...
Steering Electron Transport in Intrinsically Piezoelectric Covalent Organic Frameworks for Efficient CO <sub>2</sub> Reduction
ABSTRACT Photocatalytic CO 2 reduction represents a transformative route to sustainable fuels, yet remains limited by slu...
Surface Chemical Disorder Engineering Enabled Superior Anion Redox for Li‐Rich Mn‐Based Cathode
ABSTRACT The Li‐rich Mn‐based oxides have attracted extensive attention due to the specific anion redox reaction to provide high capacity. However, the poor reve...
Promoting CO <sub>2</sub> Conversion With Terminal Alkynes Over ZSM‐5 Zeolite‐Confined Uniform Ag Nanoparticles
ABSTRACT Heterogeneous catalysis‐mediated terminal alkyne carboxylation enabled the construction of stable C─C bonds via direct C─H bond activation, achieving ef...
Conformationally Adaptive Crown Ether Embedded in a Metal Sulfide for Exceptional Strontium Capture
ABSTRACT Precise conformational control of flexible supramolecular moieties (e.g., crown ethers) in crystalline‐state adsorbents is essential for efficient host–...
Recyclable Green Synthesis of Cu <sub>2</sub> O Octahedra via Coordination‐Induced Surface Reconstruction With Exceptional Glucose Electrooxidation
ABSTRACT Coordination‐chemistry‐driven reconstruction offers a powerful yet largely unexplored route for transforming bulk metals into functional nanomaterials w...
High‐Spin Pt Sites of Intermetallic Compound via Pinning Effect Boost Oxygen Reduction Performance
ABSTRACT The commercialization of proton exchange membrane fuel cells (PEMFCs) is hindered by sluggish oxygen reduction reaction (ORR) kinetics at the cathode, d...
Ru/RuO <sub>2</sub> Heterostructures for Stable and Active Acidic Water Oxidation via Interfacial Charge Redistribution and Lattice‐Oxygen Participation
ABSTRACT The rational design and synthesis of Ir‐free acidic oxygen evolution catalysts combining high activity with long‐term durability remains a formidable ch...
Structure‐Informed Design of Distinct Parallel G‐Quadruplex Stabilizers for <i>KRAS</i> ‐Driven Cancer Therapy
ABSTRACT Targeting oncogene promoter G‐quadruplexes (G4s) is a compelling therapeutic strategy against human malignancies. However, clinical progress has been hi...
Simple‐Synthesis Isomer‐Free Multi‐Adduct Fullerenes as Electron Transport Materials Enable 26.66% Efficiency of Perovskite Solar Cells
ABSTRACT The laggard advancement in electron transport layer materials is one of the bottleneck problems, impeding the further improvement of photovoltaic perfor...
Hybrid Seeding‐Template Modulation of Sn–Pb Perovskite Crystallization for High‐Efficiency All‐Perovskite Tandem Solar Cells
ABSTRACT Narrow‐bandgap (NBG) Sn–Pb perovskites are indispensable for achieving high‐efficiency all‐perovskite tandem solar cells (TSCs). However, the pronounced...
Interface Passivation Inhibition Enabled by Anode–Cathode Synergistic Engineering for High‐Efficiency Electrodeposition of Transition Metals
ABSTRACT Room‐temperature electrodeposition is widely used to fabricate transition‐metal materials and alloys, but severe interfacial passivation drastically red...
Correction to “Imaging‐Based High‐Content Screening With Clickable Probes Identifies XPB Inhibitors”
Designing Pyridinium‐Catalyzed Interfacial Polymerization for High‐Performance Acid‐Resistant Nanofiltration Membranes
ABSTRACT The “acyl ∼ amine” interfacial polymerization is widely studied to synthesize polyamide membranes, which, despite broad separation applications, suffer...
Asymmetric Iron‐Catalyzed Vicinal C(sp <sup>3</sup> )─H Diamination of Carboxylic Acids
ABSTRACT The direct construction of chiral 1,2‐diamines through the stereoselective functionalization of two vicinal C(sp 3...
Substrate‐Controlled Enantiodivergence in Ni‐Catalyzed Access to Phosphorylated Oxindoles With Quaternary Stereocenters
ABSTRACT A Ni‐catalyzed enantioselective intermolecular Heck‐phosphorylation of N‐aryl acrylamides with phosphine oxides is developed. This redox‐neutral cascade simultaneously forge...
Modulation of Crystal Plane Growth for Efficient and Stable Perovskite Solar Cells
ABSTRACT Achieving accurate manipulation over perovskite crystal orientation and phase purity is pivotal for realizing efficient and durable perovskite solar cel...
Axial Coordination Orchestrates Antibonding‐State Fermi‐Level Proximity and Oxygen Affinity in Single‐Atom Iron for Selective Chemiluminescence
ABSTRACT Selective chemiluminescence sensing systems face challenges due to poor specificity of radical pathways in aqueous environments. To address this issue,...
Spatial Orientation‐Dependent Double Hydrogen Bond/Photoredox Cooperative Catalysis in Metal–Organic Frameworks
ABSTRACT Catalyst activity is typically the primary priority in designing a catalytic system. The higher catalyst activity is envisioned to confer more powerful...
Energy‐Transfer Catalysis Enables the Birch‐Type Reduction of 2‐Pyridones
ABSTRACT Partially saturated heteroarenes are key intermediates in drug development, as their increased C(sp 3 ) characte...
Data‐ and Theory‐Guided Design of Dual‐Role V‐Doped RuO <sub>2</sub> for High‐Performance Acidic Oxygen Evolution
ABSTRACT Developing efficient acidic oxygen evolution reaction (OER) catalysts is crucial for proton exchange membrane water electrolyzers (PEMWE). By mining a d...