Angewandte Chemie International Edition
Articles in this Issue
Conversions of Tungsten(IV) Cycloalkene Complexes to Metathesis‐Active Cycloalkylidene Complexes Are Catalyzed by Cycloalkene and Can be Inhibited by Cycloalkene
ABSTRACT Olefin metathesis reactions catalyzed by molybdenum or tungsten alkylidene (M═CRR’) complexes are robust methods of forming carbon‐carbon double bonds,...
Enantioselective Synthesis of Axially Chiral Diaryl Ethers via Rhodium‐Catalyzed [2 + 2 + 2] Cycloaddition
ABSTRACT Axially chiral diaryl ethers are important structural motifs in biologically active molecules, functional materials, and chiral catalysts. However, their enantioselective sy...
Photothermal‐Responsive Artificial Enzyme Assembly Engineering for Near‐Unity Nitrate‐to‐Ammonia Electrocatalysis
ABSTRACT Natural enzymatic nitrate (NO 3 ‒ ) conversion exhibits inherent limitations under anthropog...
A Crystalline and Thermally Stable Selenocysteine Selenenic Acid
ABSTRACT Despite more than half a century of research on selenoproteins, the central catalytic intermediate, selenocysteine selenenic acid (Sec–SeOH), has remain...
Hydrogen Radical‐Mediated Nitric Oxide Reduction to Ammonia Over Synergistic Pd <sup>0</sup> /Pd <sup>2+</sup> Dual Sites
ABSTRACT The photocatalytic nitric oxide reduction reaction (NORR) to NH 3 offers a promising route for ammonia (NH...
Customized O─O Radical Coupling Route on High‐Density Fe─N─C Catalysts for Stable Industrial‐Scale Water Oxidation
ABSTRACT Low‐cost, efficient, and durable oxygen evolution reaction (OER) catalysts are essential for advancing large‐scale hydrogen production via anion‐exchang...
Transition Metal‐Free Heteroarene Insertion Into C─C Bonds of Benzocyclobutenones
ABSTRACT The insertion of five‐membered heteroarenes into the C─C bonds of benzocyclobutenones (BCBs) has been achieved. This process proceeds under mild conditions and does not requ...
Copper‐Catalyzed Amino Radical Transfer‐Mediated Deborylation for Chiral Ester Synthesis
ABSTRACT The asymmetric functionalization of nonactivated alkylboronic pinacol esters (APEs) represents a longstanding challenge, owing to their intrinsic inertn...
Stereoselective Ring‐Opening Polymerization of Racemic Dithiolactones Assisted by Non‐Classical C─H⋯X Interactions
ABSTRACT Stereoselective polymerization offers a powerful route to the synthesis of high‐performance recyclable polymers, yet achieving rapid, controlled, and st...
Precise Structure Regulation Induced Morphological Ordering Enables All‐Polymer Solar Cells With 20.29% Efficiency and Extreme Mechanical Robustness
ABSTRACT All polymer organic solar cells (APSCs) demonstrate distinctive advantages in balancing device efficiency while enhancing operational stability, particularly regarding mecha...
Mitochondria‐Damaging Self‐Reporting Probe for Cancer Therapy
ABSTRACT Mitochondrial damage induced by chemotherapeutic agents through disruption of the mitochondrial membrane potential (Δ...
Regio‐, Stereo‐, and Enantioselective C(sp <sup>3</sup> )─H Monofluoroalkenylation via Photo‐HAT/Nickel Dual Catalysis
ABSTRACT Stereoselective functionalization of C(sp 3 )─H bonds in hydrocarbons constitutes a revolutionary strategy for a...
Non‐Benzenoid π‐Electronic Perturbation Enables Frontier‐Orbital Symmetry Reconstruction in Ultra‐Narrowband Organic Luminophores
ABSTRACT Organic luminophores with ultra‐narrow full widths at half‐maximum (FWHMs) are highly demanding for high‐definition displays; however, the current strat...