Angewandte Chemie International Edition
Articles in this Issue
Imine Reductase–Catalyzed Remote Stereocontrol for Enantiodivergent Synthesis of Cyclohexylidene‐Based Axially Chiral Amines
Abstract Cyclohexylidene‐based amines exhibit unique axial chirality arising from the restricted double bond and have shown great potential in medicinal chemistry. However, their asy...
Harnessing Solvation Chemistry of Pentavalent Vanadium for Wide‐Temperature Range Vanadium Flow Batteries
Abstract Vanadium flow batteries (VFBs) are safe, cost‐effective, and scalable solutions for storing renewable energies. However, the poor thermal stability of p...
Host–Guest Antimicrobial Based on Conjugated Oligoelectrolyte and Cyclodextrin
Abstract The escalating global threat of antimicrobial resistance necessitates the development of new antimicrobial agents. In this study, we prepared a resverat...
Unlocking Precision in Biomass Conversion Through Functional Ligand Engineering of Lewis Acidic MOFs
Abstract Glucose isomerization to fructose is a key factor in cellulosic biomass utilization. Thus, achieving highly efficient fructose production and understand...
Photogenerated Holes Induced Deep Sodium Storage of TiO <sub>2</sub> /CdSe/NFPP Cathode for High‐Efficiency Photorechargeable Sodium Batteries
Abstract Resource‐friendly photorechargeable sodium batteries (PRSBs) integrate energy storage devices with solar cells, offering a promising path for sustainabl...
Homogenized Self‐Assembled Molecules for Inverted Perovskite Solar Cells
Abstract Inverted perovskite solar cells (PSCs) have rapidly improved, driven by advancements in self‐assembled molecules (SAMs). However, achieving homogeneous...
Deconstructive Functionalization of Cyclic Ketones via Electrochemical Interrupted Dowd–Beckwith Reaction
Abstract Deconstructive functionalization of cyclic molecules has recently emerged as a prominent strategy to access unique architectures that are challenging to prepare through trad...
Highly Efficient and Selective Photocatalytic CO <sub>2</sub> Reduction to Ethanol by Cu <sub>4</sub> Clusters with Adjacent Cu Single Atoms Anchored on Carbon Nitride
Abstract An efficient photocatalyst for CO 2 ‐to‐CH 3 CH 2...
Modulating the Polarity of Imine Bonds in Donor–Acceptor Covalent Organic Frameworks for Enhanced Photocatalytic H <sub>2</sub> Production
Abstract The development of imine‐linked covalent organic frameworks (COFs) has also drawn attention to the influence of the nature of imine binding, including i...
Copper‐Photoredox‐Catalyzed C(sp <sup>3</sup> )–C(sp <sup>3</sup> ) Reductive Cross‐Coupling of Alkyl Bromides with BCP‐Thianthrenium Reagents
Abstract Herein, we report a reductive cross‐coupling reaction of bicyclo[1.1.1]pentyl (BCP)‐thianthrenium reagents and alkyl bromides. The reaction is catalyzed by a copper/photored...
Liquid Coordination Polymers with Anhydrous Proton Conductivity
Abstract Liquid states in coordination polymers (CPs) and metal‐organic frameworks (MOFs) are typically considered transient intermediates in the crystal‐to‐glas...
Mechanically and Chemically Co‐Robust Ni‐Rich Cathodes with Ultrahigh Capacity and Prolonged Cycle Life
Abstract Ni‐rich layered oxide (NRLO) materials are considered highly promising cathode for lithium‐ion batteries. However, their practical application is limite...
A Synergistic Photocatalysis–Electrocatalysis System for Efficient Hydrogen Generation and Energy‐Saving Benzylamine Oxidative Upgrading
Abstract Photocatalytic hydrogen iodide (HI) splitting represents a promising tactic for H 2 generation, but the light‐sh...
Dynamic Hydrogen Bonding Tuned Enantioselectivity Control in Cobaloxime‐Chiral Amine Cooperative Catalysis
Abstract Cobaloxime is a versatile 3 d ‐metal catalyst for dehydrogenative radical coupling reactions. Prior mechanistic...
Utilizing the Mn(II) Dissolution‐Induced Vacancy for Optimum Mg <sup>2+</sup> Storage of Spinel Mn <sub>3</sub> O <sub>4</sub>
Abstract Manganese‐based oxide can theoretically exert the multivalent advantages of an aqueous magnesium‐ion cathode due to its redox activity and abundant crys...
Designing Low‐Cost High‐Conductivity and Nonflammable Phosphate Electrolytes Toward High‐Energy Sodium‐Ion Batteries
Abstract Safety hazard induced by flammable electrolytes are troubling the advancement of practical sodium‐ion batteries (SIBs). Non‐flammable phosphate electrol...
Self‐Activated Heterogeneous Fenton Process for Accelerated Degradation of Aromatic Pollutants over Copper Oxide Catalysts
Abstract Metal‐based heterogeneous catalysts have been commonly adopted for Fenton‐like oxidation of organic pollutants, but generally suffer from inadequate act...
Enantioselective Total Synthesis of (–)‐Psiguadial A
Abstract The first enantioselective total synthesis of the antiproliferative natural product (–)‐psiguadial A is reported. This approach features the enantiosele...
Atomic Cu–O–Zr Sites for Highly Selective Production of <i>p</i> ‐xylene from Tandem Upcycling of PET and CO <sub>2</sub>
Abstract Exploring an efficient catalytic system for tandem upcycling of CO 2 and polyethylene terephthalate (PET) is hig...
Selective Electrocatalytic Hydrodimerization of Acetylene to 1,3‐Butadiene Over Neighboring Cu Dual Sites
Abstract Selective electrocatalytic hydrodimerization of acetylene to 1,3‐butadiene is a promising alternative to the energy‐intensive naphtha steam cracking rou...
Photoredox Catalysts Based on <i>N</i> ‐(Hexyl)benzothioxanthene‐3,4‐dicarboximide for Photopolymerization and 3D Printing Under Visible Light
Abstract Photoredox catalytic systems are widely used in free radical polymerization as an important photoinitiating approach. However, many reported photoredox...
Au <sub>6</sub> Cu <sub>2</sub> Clusters with High Electron Affinity and Oxygen‐Mimetic Properties for Hypoxic Tumor Radiosensitization
Abstract Hypoxia‐induced radioresistance primarily contributes to the failure of radiotherapy because it hinders the effective fixation of DNA damage. Despite th...
Air‐Level Oxygen Enables 100% Selectivity in Urea Synthesis via Photocatalytic C─N Coupling of CO and Ammonia
Abstract The clean‐energy‐driven synthesis of urea from carbon‐ and nitrogen‐containing small molecules has garnered significant interest but remained great chal...
In Situ Observation of Post‐CO Intermediates to Decode C─C Coupling Pathways in CO <sub>2</sub> Electroreduction
Abstract Electrocatalytic carbon dioxide (CO 2 ) reduction reaction (CO 2 RR) has...
Employment of <scp>l</scp> ‐Citrulline as an Effective Molecular Bridge for Regulating the Buried Interface of Perovskite Solar Cells to Achieve High Efficiency and Good Stability
Abstract Suppressing the defects from SnO 2 and perovskite interface is essential for the fabrication of large‐area n–i–p...