Angewandte Chemie International Edition

Design Considerations of Ionic Conductive Elastomeric Electrolyte for Solid‐State Zinc Metal Batteries with High Safety and Long Life

Abstract Zn−ion batteries are regarded as one of the most promising candidates for energy storage, but the severe hydrogen evolution reaction (HER) and dendrite...

Frontispiece: Highly Enantioselective Organocatalysis with Bidentate Halogen Bond Donors

Stabilizing the Quinoidal Form of Polycyclic Aromatic Hydrocarbons by O─B←N Units to Give a > 1000 nm Redshift in the Absorption Wavelength

Abstract Polycyclic aromatic hydrocarbons (PAHs) have distinct chemical structures and excellent optoelectronic properties. Although PAHs with ultra‐large π‐conj...

Frontispiece: Utilizing the Mn(II) Dissolution‐Induced Vacancy for Optimum Mg ²⁺ Storage of Spinel Mn ₃ O ₄

Dual‐Responsive Ultrathin Polymersomes with Reversible Transitions on Acidochromism and Fluorochromism Performances for Multiple Information Encryption

Abstract Endowing dual‐responsive ultrathin polymersomes (UTPSs) with reversible stimuli‐chromic and fluorochromic performances offers a prospective yet challenging strategy for achi...

Ryo Inoue

Reengineering of a Proteomimetic Pan‐Ras Inhibitor into a Ras Degrader

Abstract Bifunctional ligands that can coax protein–protein interactions have become attractive therapeutic modalities. Herein, we describe conformationally defi...

Giant Negative Thermal Expansion Induced by Topological Phase Transition in a Potassium Zinc Phosphate Material

Abstract Negative thermal expansion (NTE) materials exhibit the counterintuitive property of volume contraction upon heating, which is critical for precision eng...

Outside Front Cover: Boosting Current Density of Electrocatalytic CO ₂ Reduction using Metal‐Enzyme Hybrid Cathodes (Angew. Chem. Int. Ed. 30/2025)

Enzyme Induced Solid‐Like Condensates Formation of Engineered Peptide in Living Cells for Prostate Cancer Inhibition

Abstract This work describes the rational design and synthesis of hepsin‐recognized amphiphilic‐branched peptides ( DMN‐SIPL...

Type I‐B Main‐Chain Polyrotaxane Network

Abstract Polyrotaxanes (PRs) are recognized for their outstanding conformational flexibility, making them ideal candidates for the design of high‐performance mechanically interlocked...

H ₂ S Donor Functionalized Molecular Machine for Combating Multidrug‐Resistant Bacteria Infected Chronic Wounds

Abstract Chronic wounds are a worldwide medical challenge due to the complex and multifaceted etiologies, including bacterial infection, persistent inflammation,...

Structural Insight Into a Human H Ferritin@Gold‐Monocarbene Adduct: Aurophilicity Revealed in a Biological Context

Abstract Human H ferritin (HuHf) has excellent potential as a nanocarrier for the selective delivery of anticancer metal‐based drugs to tumor cells. Here, we addressed the interactio...

Tailoring Oxygen Vacancies with Atomically Dispersed Cu Sites for Stable and Efficient Photothermal CO ₂ Conversion

Abstract Photothermal catalysis under mild conditions represents a promising and sustainable approach for CO 2 conversion...

Nonconjugated Structural Distortion Promoting the Formation of NIR Triplet States in Phenothiazine Dyes for Cancer Photoimmunotherapy

Abstract Near‐infrared (NIR) triplet‐state dyes are pivotal for advanced biomedical and material science applications. Although numerous strategies have been pro...

Correction to “Supramolecularly Engineered Reporters with Superoxide Anion Triggered Chemiluminescence for Early Diagnosis and Efficient Amelioration of Acute Kidney Injury”

Breaking Symmetry of Active Sites in Metal‐Organic Frameworks for Efficient Photocatalytic Valorization of Polyester Plastics

Abstract Chemical upcycling of waste plastics offers a promising way toward achieving a circular economy and alleviating environmental pollution but remains a hu...

Plasmonic DNA‐Barcoded Virion Nano‐Oscillators for Multiplexed Quantification of Small‐Molecule Binding Kinetics to Membrane Proteins

Abstract A high‐density nano‐oscillator platform using self‐assembled DNA‐barcoded virion sensors is developed to address the critical need for high‐throughput label‐free measurement...

Phenylene Cage Synthesized by Metal‐Mediated Assembly of Phenylene Macrocycle and Its Piezofluorochromic Behavior

Abstract A phenylene macrocycle containing two meta‐phenylene units positioned opposite each other was used as a building block to construct phenylene cages via platinum‐mediated C─C...

Introducing Functional Groups Into B←N Organic Frameworks with Permanent Porosity

Abstract Crystalline organic frameworks incorporating dative B←N and reversible B─O bonds (BNOFs) have garnered increasing interest on account of their crystalli...

Selective C ₂ Electroproduction via Back Bonding in Asymmetric Copper‐Copper Motifs

Abstract CO 2 reduction reaction (CO 2 RR) is considered a highly attractive appr...

π‐Bridge‐Linked Ionic Covalent Organic Framework with Fast Reaction Kinetics for High‐Rate‐Capacity Lithium‐Ion Batteries

Abstract Covalent organic frameworks (COFs) have emerged as promising cathode materials for high‐performance lithium‐ion batteries (LIBs) due to their well‐defin...

Enantioselective Immobilization of Nonprecious Metal Complexes on Chiral Covalent Organic Frameworks for Improved Single‐Site Photocatalytic Hydrogen Evolution

Abstract The noncovalent assembly of molecular catalysts into photocatalytic systems represents a pivotal strategy for exploring single‐site heterogenous catalys...

Hydroxyl‐Promoted C─C Coupling for Selective Methane Conversion into Ethane on Cerium Oxide Photocatalyst

Abstract Converting methane into high‐value chemicals under mild conditions offers substantial environmental and energy benefits but is challenged by the difficu...

Switchable Regiodivergent Reductive Alkyl–Alkyl Coupling by Nickel Catalysis: Sorting Different Alkyl–Nickel Intermediates

Abstract Site‐selective and divergent functionalizations on saturated alkyl chain at specific unfunctionalized positions is a key challenge in organic chemistry...