Angewandte Chemie International Edition
Articles in this Issue
Tailored Selectivity for CO and C<sub>2+</sub> in CO<sub>2</sub> Reduction: Insights into the Dynamic Evolution of Electrocatalysts
AbstractControlling product selectivity in electrochemical CO2 reduction (eCO2R) is critical for efficient CO2 conversion. However, the dynamic structural changes of Cu‐based catalysts during operatio...
Localized Hydrolysis‐Based Proximity Reporting Platform for Protein Hierarchical Structure Profiling
AbstractThe substrate‐specific bond cleavage capability of hydrolases provides a unique strategy for engineering off‐on switches. This prompted our hypothesis that confining hydrolases and substrates...
Toward Narrow‐Band, Stable Blue MR‐TADF Emission via Combined Heterocyclic Analogues Marching B.T.2020
AbstractThe development of efficient and stable ultra‐narrowband pure‐blue multi‐resonance thermally activated delayed fluorescence (MR‐TADF) emitters is critical for next‐generation wide‐gamut OLED d...
Hooked for Decay with Hydrophobic‐Coated Magnetic Beads to Grapple and Disintegrate Nanoplastics
AbstractDegradation of synthetic polymers inevitably leads to the formation of nanoplastics (NPs), and recent studies associate health risks with NPs. Therefore, catching and degrading NPs are importa...
Photoredox‐Catalyzed Radical Relay for C─N Cleavage and Ring Expansion: Accessing Medium‐Sized Lactams From Unstrained Cyclic Amines
AbstractThe synthesis of medium‐ring lactams constitutes a formidable yet pivotal frontier in modern chemical research. Persistent endeavors in this field are essential for overcoming the prevailing o...
Decoration of Metal‐Organic Frameworks with Coenzyme Mimics for Boosting Photocatalytic Hydrogen Production
AbstractDespite remarkable progress achieved in biomimetic catalysis, the majority of studies have primarily concentrated on mimicking the structures of catalytic sites in metalloenzymes, while freque...
Highly Stable Electrosynthesis of Hydrogen Peroxide Adapted to Fluctuating Renewable Energy
AbstractThe integration of renewable energy with electrocatalytic technology affords an effective pathway to reduce carbon emissions and enhance energy efficiency, thereby promoting the green electrif...
Alkaline Earth Metal‐Based Hybrid Organic‐Inorganic Perovskite‐Like Ferroelectrics
AbstractHybrid organic‐inorganic perovskites (HOIPs) with the ABX3 formula have garnered significant scientific interest owing to their substantial technological promise in photovoltaics, optoelectron...
Enantioselective Rhodium‐Catalyzed Cycloisomerization of 1,5‐Bis(allenes) to Access 1,2‐<i>cis</i>‐Ethynyl‐ and Vinyl‐Substituted Five‐Membered (Hetero)Cycles
AbstractIn this study, an enantioselective Rh‐catalyzed cycloisomerization of 1,5‐bis(allenes) to furnish 1,2‐cis‐ethynyl‐ and vinyl‐substituted five‐membered (hetero)cycles in high yields and with ex...
Jimin Park
A Donor–Acceptor‐Donor‐type Organic Molecule as an Effective Electrode to Form Rapid Diffusion Pathway for High‐Performance Sodium‐Ion Batteries
AbstractCarbonyl‐containing organic electrodes have been widely considered as ideal substitutes for traditional inorganic compounds in sodium‐ion batteries (SIBs) due to their excellent redox reversib...
Protein–Protein Complex Stability Controls Substrate Scope in a β‐Ketoacyl‐ACP Reductase Specific for Medium Chains
AbstractAssembly‐line enzymes carry out multistep synthesis of important metabolites by using acyl carrier proteins (ACPs) to shuttle intermediates along defined sequences of active sites. Despite lon...
Ultrafast Construct Local Acidic Microenvironment of Boron‐Intercalated Osmium with Anti‐Precipitation and Corrosion‐Resistant for Seawater‐splitting
AbstractSeawater electrolysis represents a promising avenue for hydrogen production, nevertheless, the Cl− corrosion and surface deposition of Ca(OH)2/Mg(OH)2 hinder its practical application by deact...
Interactome Profiling of a Lysine Deacetylase Trapping Probe Library Uncovers Crosstalk Between HDAC6 and NF‐κB Signaling
AbstractLysine or histone deacetylases (HDACs) remove acetyl groups from lysine residues of numerous proteins, thereby regulating their function and activity. HDAC6 is involved in multiple cellular pr...
Butterfly‐Shaped Folding Synthons for Designing Superselective and Ultrapermeable Artificial Water Channels
AbstractWater transport across biological membranes is essential for life, facilitated by water channel proteins like aquaporins (AQPs). Drawing inspiration from these natural systems, artificial wate...