Angewandte Chemie International Edition
Articles in this Issue
In Situ Chemical Construction of Ultrathin Zn <sup>2+</sup> ‐Conductive Interphase for Dendrite‐Free Zinc Metal Batteries
Abstract Aqueous zinc (Zn) interfacial chemistry is inherently safe but encounters significant challenges with irreversibility, as exemplified by low Coulombic e...
Self‐Stabilized Heterometallic Pair Sites for Selective Ethanol Dehydrogenation on Pt–Cr–Ag Alloy Catalysts
Abstract Self‐stabilized, heterometallic pair‐sites can enable fine‐tuning of catalytic functionality while also mitigating dynamic structural changes that degra...
Reactive Oxygen Species‐Responsive Biomimetic Nanoplatelets for Thrombus‐Mediated Photothermal Immunotherapy of Tumor
Abstract One of the biggest advantages of photothermal therapy (PTT) as a compelling cancer treatment is its spatiotemporal nature. However, there are still significant challenges in...
High‐Throughput Electron Transfer in Inorganic–Organic Interfacial Electric Field Enabling Selective CO <sub>2</sub> Photoreduction
Abstract The efficiency of photocatalytic CO 2 reduction has long been limited by the competing H 2...
Materials Innovation and the Changing Face of Photocatalytic and Electrocatalytic Carbon Dioxide Reduction Research: From Metal Nanoclusters to Extended Frameworks
Abstract The accelerating rise in atmospheric CO 2 levels, driven by anthropogenic emissions, underscores the urgent need...
C─H Amination of Polypropylene with Sodium <i>N</i> ‐Chloro‐Amides
Abstract Polypropylene (PP) is one of the most produced polymers. To meet the requirements of many modern technologies, it is very urgent to introduce diverse fu...
A Crystalline Bismuth(II) Radical Anion: Synthesis, Characterization, and Reactivity
Abstract We report the synthesis of a planarized tris‐amidobismuthane supported by a rigid, bulky NNN pincer ligand, which enforces a T‐shaped geometry at the bi...
Lattice Oxygen Activation Through Redox‐Induced δ‐MnO <sub>2</sub> /Co <sub>3‐x</sub> Mn <sub>x</sub> O <sub>4</sub> Interfaces for Enhanced N <sub>2</sub> O Decomposition
Abstract N 2 O decomposition over spinel catalysts suffers from a spin‐forbidden oxygen recombination step, resulting in...
The Role of Intimate Dipole Carbonyl–Carbonyl and Hydrogen–Carbonyl Interactions in the Stereocomplexation and Crystallization: The Case of Poly(Cyclohexene Carbonate)
Abstract Enantiopure isotactic poly(cyclohexene carbonate) (PCHC) has been synthesized with chiral Zn‐β‐diiminate catalyst. PCHC crystallizes both as enantiopure...
Nitrogen‐Rich MOF‐Material‐Derived Metal Dual‐Atom Platforms for Efficient Electrochemical Nitrate Reduction
Abstract The rational design of asymmetrically coordinated dual‐atom catalysts (DACs) offers new opportunities to overcome intrinsic limitations in selective mul...
High‐Throughput Engineering and Modification of Non‐Ribosomal Peptide Synthetases Based on Golden Gate Assembly
Abstract Non‐ribosomal peptide synthetases (NRPS) are multimodular enzymes that produce complex peptides with diverse biological activities, potentially being us...
Engineered Thermostable Chemically Responsive GlowCas9 System for Real‐Time Therapeutic Monitoring Applications
Abstract Clustered regularly interspaced short palindromic repeats (CRISPR)/CRISPR‐associated protein (Cas) has revolutionized gene therapy applications due to i...
Photooxidation‐Induced Ultrabright and Ultraphotostable NIR‐II Emissive Water‐Soluble Gold Nanoclusters
Abstract The long‐standing issues of photobleaching and low photoluminescence quantum yield (QY) in the second near‐infrared (NIR‐II) region greatly hinder the l...
EDA Complex‐Driven Desaturation of Heterocyclic Carbonyl Compounds Enabled by HFIP
Abstract Recently, electron donor–acceptor (EDA) complex‐mediated organic synthetic strategies have emerged as powerful tools for diverse bond‐forming transformations; however, their...
Photocatalytic Partial Water Dissociation by Protonated Carbon Nitride for Hydrogenation Reactions
Abstract Catalytic hydrogenation using pressurized hydrogen at elevated temperature is of utmost importance in refinery and fine chemical industries, but heavily...
Synergistic Mechanism of Nanochannels and Chain Migration in Bioinspired Solid‐State Gel Electrolytes for Ultrahigh‐Rate, Long‐Life Flexible Tin‐Air Batteries
Abstract Flexible high‐performance tin‐air batteries (FTABs) exhibit transformative potential for wearable electronics. Nonetheless, the rate performance and cyc...
Mapping Boryl Radical Properties and Reactivity Using Machine Learning: The B‐Rad and React‐B‐Rad Maps
Abstract Boryl radicals have become indispensable in organic synthesis, yet, translating their complex steric and electronic properties into actionable reactivit...
Cu–Ce Dual–Atom Sites Embedded in Zeolites Boost Resistance to Impurity Interference for Environmental Catalysis
Abstract Biodiesel, a carbon‐neutral alternative to fossil fuels, plays a vital role in decarbonizing transportation, with global production exceeding 40 million...
A Reversible Chemoenzymatic Labeling Strategy for Profiling of Protein O‐Glucosylation
Abstract O‐linked glucose (O‐Glc), the β‐linked modification of serine residues, is a rare form of protein glycosylation first identified on proteins containing epidermal growth fact...
Chemical Fuel‐Driven Stiffening of Transient Hydrogels via Vitrifiable Phase Separation
Abstract Fuel‐driven transient materials that can temporally adjust their mechanical properties are ubiquitous in living systems, enabling biological functions to be maintained far f...
Spatiotemporally Controlled Protein Corona‐Armored DNA Nanomachine for Multitype Biomarker Imaging in Living Cells
Abstract DNA nanomachines have significant potential for biosensing because of their high programmability, signal amplification ability, and excellent biocompatibility. However, unde...
Choline Iodide‐Mediated Sulfur Conversion and Zinc Plating/Stripping Chemistry in Aqueous Zn–S Batteries
Abstract Aqueous Zn–S batteries are promising candidates for future energy storage due to their intrinsic safety, environmental friendliness, and low cost. Howev...
Multiple‐Birth‐Acceptor: Easily‐Synthesized Mixture for Easily‐Fabricated Quaternary Organic Solar Cells with Beyond 20% Efficiency
Abstract Ternary strategy has been proved very effective to improve the power conversion efficiency (PCE) of organic solar cells (OSCs). However, quaternary OSCs...
Methanol Upcycling Toward Glycolaldehyde Synthesis Enabled by New High‐Performance Photoredox Route
Abstract Glycolaldehyde (GA) possesses great potential to serve as the feedstock for the C 2 ‐based chemical industry and...
Binding Modes Tuning Nitrite Reduction Reactivity at Iron(III) Centers Triggered by Hydrogen Atom, Hydride, and Proton Transfers
Abstract To elucidate the mechanisms of iron‐mediated nitrite reduction, we synthesized and fully characterized Fe(III)‐NO 2...