Angewandte Chemie International Edition
Articles in this Issue
High‐Efficiency Blue TADF Palladium(II) Complexes with Ligand‐to‐Ligand Charge Transfer Excited State
Abstract Electroluminescent complexes of the second‐row transition metals remain underdeveloped due to the challenge of simultaneously achieving fast radiative d...
Copper‐Catalyzed Regio‐ and Diastereoselective Dearomative Carbosilylation of Unactivated Arenes by Intercepting the Dienyl Radical
Abstract The radical‐mediated dearomatization of aromatic systems to generate cyclohexadienyl radical intermediates represents a crucial strategy for constructin...
Floor Temperature‐regulated Poly(ether‐alt‐ester) With Thermal Stability and Chemical Recyclability Enabled by Polycondensation—Depolymerization−Repolymerization Strategy
Abstract Creating innovative poly(ether‐ alt ‐ester)s (PEAEs) with alternating ether and ester groups to address the trad...
Bioinspired Backbone Editing Strategies for Rewriting Synthetic Polymers
Abstract The structure of a polymer backbone plays a central role in determining its physical properties, chemical reactivity, and function. In biological systems, biopolymers such a...
Novel Ferroelectric Mediated Dual S‐scheme Heterojunction with Multiple Built‐in Electric Fields for Enhanced Photoelectrochemical Seawater Splitting
Abstract Photoelectrochemical (PEC) seawater splitting is promising for direct utilization of solar energy and ocean resources for H 2...
Boosting the Nucleophilicity of the Diphenylphosphide Anion with Crown Ether Supported Heavy Alkali Metals to Facilitate Highly Efficient Catalytic Alkene Isomerisation
Abstract Caesium and rubidium have long experienced an interest drought in organoelement chemistry in comparison to the vast ocean of applications accomplished m...
Synergistic Regulation of <sup>*</sup> NO Coupling and <sup>*</sup> H Supply on Sulfur‐Doped Zero‐Valent Iron Aerogels Drives Efficient Electroreduction of Nitrate to N <sub>2</sub>
Abstract Electrochemical nitrate (NO 3 − ) reduction to dinitrogen (N 2...
SABRE Hyperpolarized Multichannel <sup>19</sup> F NMR for Sensitive Detection of Multiple Disease Marker Enzymes on a Benchtop NMR
Abstract The unique multichannel capability of 19 F nuclear magnetic resonance (NMR) stands as a pivotal and rapidly adva...
Atomic‐Precision Triple‐Enzyme Nanozyme Synchronizes Mitochondrial Dual‐Pathway Disruption for Precision Oncology
Abstract Although nanozyme‐mediated disruption of mitochondrial homeostasis holds significant therapeutic potential, precise spatiotemporal regulation using single‐function catalysts...
Mapping Antibiotic Photocatalytic Transformation and Resistance Risks with a DFT‐Informed Machine Learning Workflow
Abstract The photocatalytic degradation of antibiotics is effective but may yield transformation products (TPs) that sustain or amplify ecological risks, including antibiotic resista...
Surface Electrostatic Gradient of Perovskite Boosts Metal in Situ Exsolution and CO <sub>2</sub> Electrolysis in Solid Oxide Electrolyzer
Abstract The in situ exsolution of nanoparticles (NPs) has brought new opportunities for the application of perovskite‐based catalysts in solid oxide electrolyze...
Minimizing H <sub>2</sub> O <sub>2</sub> Loss in Industrial Electrosynthesis via Asymmetric Main‐Group Sn Single‐Atom Catalysts
Abstract The electrosynthesis of hydrogen peroxide (H 2 O 2 ) via the two‐electro...
Unlocking High‐Performance Na‐CO <sub>2</sub> Batteries via a d‐p Orbital Hybridization Descriptor for Rational Catalyst Design
Abstract Metal‐based catalysts show great promise for efficient Na‐CO 2 batteries. However, the absence of a universal pr...
Proteasome Cap Targeting Chimeras for Ubiquitination‐Independent Targeted Protein Degradation
Abstract Selective degradation of a disease‐associated protein of interest (POI) is a powerful therapeutic strategy. FDA‐approved and investigational glue and degrader drugs function...
Sequential Radical‐Anionic Polymerizations via Consecutive Photo‐Reduction
Abstract Polymeric properties are intimately entwined with the diversities of structures, making the development of polymerization methods highly valuable to both academic research a...
Sanger Sequencing of Xeno‐Nucleic Acid
Abstract Xeno‐nucleic acids (XNAs) offer biostable genetic polymers for biotechnology and information technology, but are incompatible with prevailing DNA sequencing methodologies. H...
Competitive Ni/Mn Reduction and Microstrain‐Coupled Negative Thermal Expansion in Delithiated Li‐Rich Cathodes
Abstract The demand for high energy density in the field of Li‐ion batteries has intensified interest in lithium‐rich Mn‐based layered oxide cathodes (LRLOs) owi...
Chloride Chemistry in Multivalent‐Metal Batteries: From Interphase to Bulk Phase
Abstract Rechargeable magnesium (Mg) batteries are promising candidates for next‐generation energy storage due to their high energy density, intrinsic safety, an...
Reinventing Phosphorus Anodes: Taming Pulverization via Strain‐Induced Interfacial Coupling
Abstract Alloy‐type anodes offer high theoretical capacity, yet their practical application is hindered by substantial volume expansion and particle pulverizatio...
Toward Industrial Electrosynthesis of Ethylene: Energy‐Efficient and Stable Acetylene Semi‐Hydrogenation on a Copper Phosphide/MXene Electrocatalyst
Abstract Electrocatalytic semi‐hydrogenation of acetylene to ethylene (EHAE) using renewable electricity represents a promising alternative approach for ethylene...
Unlocking Full State‐of‐Charge of Polyoxometalate for High‐Energy‐Density Redox Flow Batteries via Concerted Proton‐Electron Transfer
Abstract Polyoxometalates (POMs) exhibit exceptional multi‐electron transfer capacity for next‐generation high‐energy‐density redox flow batteries (RFBs), while...
Insights into the Controlled Formation of Zr‐Based Metal–Organic Gels: Linking Macroscopic Properties with Molecular Information from Solution State NMR
Abstract Understanding and controlling the formation mechanisms of metal–organic gels is crucial for their rational design with well‐defined properties for diverse applications. Howe...
Photoactivatable Time‐Evolving Afterglow of Carbon Dots via Coupled Triplet and Exciplex Persistent Emission for Programmable Photonic Encoding
Abstract Photoactivatable time‐evolving afterglow color (TEAC) materials offer programmable delayed emission for dynamic photonic applications. However, achieving light‐triggered and...
Reoriented Interfacial Water Structure Around Pd Enhances Oxygen Reduction Kinetics in Zn–Methanol–Air Batteries
Abstract The dynamics of interfacial water within the electrical double layer (EDL) play a pivotal role in governing charge transfer during electrocatalysis. Whi...
Interfacial Radical Reaction Enables High‐Performance Graphite Anode for Potassium‐Ion Batteries
Abstract The reversible K‐intercalation chemistry in graphite anode plays a critical role in advancing the development of potassium‐ion batteries (PIBs) for larg...