Pyridine Into Pyrrole Transformation Induced Within the Confinement of the Macrocycle
Abstract
ABSTRACT The pyridine contracted to form the pyrrole ring. This transformation belongs to a unique class of reactions with the fundamental characteristic of the cleavage of the aromatic structure. By investigating the unusual coordination chemistry of N‐confused pyriporphyrin with silver and gold ions, we observed this process and obtained several complexes that exhibited remarkable reactivity. This includes the reversible cleavage of C–O bonds and the selective demetallation of the outer metal ion.
Article Details
Authors (6)
Paulina Krzyszowska
Department of Chemistry University of Wroclaw Wroclaw Poland
Agata Burska‐Jabłońska
Department of Chemistry University of Wroclaw Wroclaw Poland
Mateusz Oberski
Department of Chemistry University of Wroclaw Wroclaw Poland
Michał J. Białek
Department of Chemistry University of Wroclaw Wroclaw Poland
Lechosław Latos‐Grażyński
Department of Chemistry University of Wroclaw Wroclaw Poland
Karolina Hurej
Department of Chemistry University of Wroclaw Wroclaw Poland