Angewandte Chemie International Edition
Articles in this Issue
Modulating Electron Delocalization Structure in Covalent Organic Frameworks Through Conjugation and Hybridization to Boost Li‐ion Migration Dynamics
ABSTRACT The inherent factors influencing the growth of lithium (Li) dendrites and the kinetics of Li + migration in poly...
Magnesiation of Phenol Derivatives Catalyzed by a Rhodium─Aluminum Complex
ABSTRACT Here we describe the generation of aryl Grignard reagents from phenol derivatives via C─O bond activation cooper...
A Redox‐Active Mesoporous Cobalt–Pyrazolate Framework for Reversible O <sub>2</sub> Sorption
Abstract Expanding pyrazolate metal–organic frameworks (MOFs) beyond microporous architectures is a formidable synthetic challenge, as the strong and directional...
Methyl Asymmetric Interference‐Enhanced Dipole–Dipole Interaction for High‐Performance Potassium–Graphite Battery Electrolyte Design
ABSTRACT Potassium‐ion batteries are the only new alkali metal battery system, apart from lithium‐ion batteries, that can directly use graphite as the anode. How...
Machine Learning‐Guided Design of a Flexible Highly Conductive Additive‐Free Polymer Cathode
ABSTRACT Organic cathode materials (OCMs) are promising sustainable alternatives to inorganic counterparts for next‐generation batteries, yet their widespread ap...
Intrinsic Elastification of Ferroelectric Poly(vinylidene fluoride) Homopolymers
ABSTRACT Elastic ferroelectrics, distinguished by their softness, stretchability, and ferroelectric and piezoelectric responses, are promising candidates in next...
Synergistic Ion‐Pair/Lewis Acid Catalysis Enables Enantioselective Synthesis of Helically Chiral Oxa[6]Helicenes
ABSTRACT Helicenes are privileged chiral architectures with exceptional optical and electronic properties, underpinning their importance in asymmetric catalysis,...
The Simplest Phosphinylperoxy Radical and Its Isomers in the Photochemical Phosphorus‐Hydrogen‐Oxygen Network
ABSTRACT The oxidation of phosphine (PH 3 ) plays an important role in the photochemical phosphorus‐hydrogen‐oxygen netwo...
Bioinspired Mo‐on‐Cu Nanosheets Enable Potential‐Dependent Electrosynthesis of Urea and Methanol via Interfacial Electron Redistribution
ABSTRACT The electrochemical reduction of CO 2 and its co‐reduction with NO 3 −...
Electrolyte‐Regulated Conversion of Small Resource Molecules
ABSTRACT Electrocatalysis powered by renewable electricity is a promising strategy for clean energy transformation and achieving carbon neutrality goals. In reso...
Scalable Ru‐Doped Pt/NiFe‐LDH Catalyst via Pulse Electrolysis Enables Stable Glycerol Oxidation to Glyceric Acid at High Current Density
ABSTRACT Selective electrooxidation of glycerol (GLY) to glyceric acid (GLA) offers a promising route for GLY valorization but remains hindered by limited activi...
Proximity Engineering of Fe‒N <sub>4</sub> Twins for Oriented Generation of Singlet Oxygen for Hospital Wastewater Treatment
ABSTRACT Precisely tailoring the molecular configurations of single‐atom sites and elucidating their correlation with generated specific reactive species is cruc...
Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross‐Coupling
ABSTRACT Reductive cross‐couplings have emerged as a powerful strategy for forging C–C bonds directly from electrophiles, circumventing the need for preformed or...
Trimeric Acceptors with Fine‐Tuned Alkyl‐Linkage Sites for 20.23% Efficiency and Stable Organic Solar Cells
ABSTRACT Giant‐molecule acceptors (GMAs) have been proven to improve power‐conversion‐efficiency (PCE) and stability of organic solar cells (OSCs), while most high‐performance GMAs o...
Dynamic Self‐Organizing Lithium Bonds for High Energy Density Lithium Batteries
ABSTRACT To enhance the electrochemical performance of silicon electrodes, it is essential to comprehensively understand their underlying lithium storage mechani...
Cation‐Vacancy Induced Compressive Strain Localization in RuO <sub>2</sub> Catalyst for High‐Performance Acidic Oxygen Evolution
Abstract Designing acid‐stable RuO 2 catalysts capable of overcoming the activity‐stability trade‐off remains pivotal for...
FeCoN <sub>6</sub> Sites Unlock Superior Sodium‐Ion Storage Through Synergizing Capture‐Release and Orbital‐Mediated Charge Delocalization
ABSTRACT Sodium‐ion hybrid capacitors (SHCs) are severely hindered by sluggish sodiation kinetics in conventional anodes. Single‐atom sites, though promising, su...
Donor–Acceptor Engineering Enables Kinetic Control of Chirality Transfer in Side Chain Polymers
ABSTRACT Chirality transfer across hierarchical architectures represents a pivotal and underexplored challenge in the design of functional chiral materials. Thro...
Tailoring Hydrogenation Pathway to Redirect CO <sub>2</sub> Electroreduction From Ethylene to Ethanol
ABSTRACT Electrochemical CO 2 reduction to ethanol faces a fundamental challenge: competing ethylene formation through sh...
Tri(Thiophene‐Nitrile) Covalent Organic Frameworks With Low HOMO/LUMO Donor/Acceptor for High‐Potential‐Plateau Zinc Batteries
ABSTRACT Covalent organic frameworks (COFs) featuring desirable redox‐active sites have become competitive cathode materials for aqueous zinc‐organic batteries (...
Recyclable Thermoset Enabled by Copolymer of Elemental Sulfur and Acrylate With Controlled Disulfide Linkages
ABSTRACT Thermoset polymers have found a number of applications. However, their recycling faces a challenge due to their chemically crosslinked structure, which...
Outside Back Cover: Dynamic Spin Governing Asymmetric Coordination Fields in Trimetallic Single‐Atom Catalysts for Optimal Oxygen Reduction (Angew. Chem. Int. Ed. 12/2026)
Coumarin‐30 Enables Site‐Resolved Detection of Tubulin Ligands by Microscale Thermophoresis
Abstract Tubulins are among the most successful targets for cancer chemotherapy. However, the emergence of drug resistance stimulates the continuous search for novel chemotherapeutic...
Crown Ether Rotaxane‐Induced Construction of COF Membranes With Recognition Channels for High‐Efficiency Ion Sieving
ABSTRACT Biological ion channels can achieve high ion discrimination through the synergy between pore structure and microenvironment. However, constructing biomi...