Angewandte Chemie International Edition
Articles in this Issue
Outside Front Cover: Subsurface Stabilization of Interstitial Pt Atoms on CeO <sub>2</sub> (111): Rethinking Single‐Atom Catalyst Architectures (Angew. Chem. Int. Ed. 25/2026)
Correspondence on the Correction to “Thermally‐Stable Single‐Site Pd on CeO <sub>2</sub> Catalyst for Selective Amination of Phenols to Aromatic Amines Without External Hydrogen”
Inside Front Cover: Stable Synapse‐Like Memory Switching in N‐Heterocyclic Carbene Monolayers (Angew. Chem. Int. Ed. 25/2026)
Enantioselective C–H Functionalization Reactions Enabled by Cobalt(III)‐Centered Chiral Pockets
ABSTRACT Due to the difficulty in achieving stereoselective recognition of three‐dimensional functionalization reagents, desymmetrization and (dynamic) kinetic resolution of such com...
Boosting Cobalt Porphyrin for Selective Nitrate Electroreduction
ABSTRACT The electrocatalytic reduction of nitrate (NO 3 − ) to ammonia (NH 3...
Radical Anion‐Driven Electron‐Ion Coupled Repair Chemistry for Direct Regeneration of Degraded LiFePO <sub>4</sub> Cathodes
ABSTRACT Direct regeneration of spent LiFePO 4 (LFP) cathodes is a sustainable alternative to conventional recycling meth...
Anthraquinone‐Based Electron Reservoir‐Pump Photosensitizer Generating Radical Ion Pairs for Metabolism‐Targeted Photodynamic Therapy
ABSTRACT Type I photodynamic therapy (PDT) overcomes oxygen (O 2 ) dependence of type II PDT, but developing hypoxia‐effi...
Stereoselective Biotransformation: Transfer of Learning to Advance Drug Metabolism and Biocatalysis
ABSTRACT Chirality is an important determinant of drug action, as enantiomers can exhibit markedly different pharmacological and toxicological profiles. Although the importance of st...
Beyond the Pre‐Equilibrium Approximation: Consequences of Elementary Step (Ir)reversibility on the Mechanistic Interpretation of Tafel Slope
ABSTRACT The relationship between electrochemical potential and reaction rate—or Tafel slope—is fundamental to the study of multi‐step charge transfer reactions....
Subsurface Stabilization of Interstitial Pt Atoms on CeO <sub>2</sub> (111): Rethinking Single‐Atom Catalyst Architectures
ABSTRACT Single‐atom catalysts (SACs) offer maximal efficiency by stabilizing isolated metal atoms on oxidic supports. Platinum on cerium oxide (CeO...
Selective Hydrogenation of Formamide to Methanol Over Supported Platinum Catalysts
ABSTRACT The rising global energy demand, driven by population and economic growth, continues to be met largely by fossil fuels. Consequently, atmospheric CO...
Sulfur‐Directed Construction of Vinyl Cyclopropanes from 1,3‐Dienes
ABSTRACT The stereoselective cyclopropanation of 1,3‐dienes remains a long‐standing challenge in the preparation of vinyl cyclopropanes (VCPs) due to the intrins...
Outside Back Cover: Fused‐Ring Acceptor–π–Acceptor Architecture Enables Near‐Infrared‐Absorbing Mesoporous Covalent Organic Frameworks for Enhanced H <sub>2</sub> O <sub>2</sub> Photosynthesis (Angew. Chem. Int. Ed. 25/2026)
Reservoir Computing‐Based Glucose Sensing With an Enzymatic Reaction Network
ABSTRACT The survival of living systems relies on their capacity to process physicochemical information from the environment and make distinct decisions. Inspired by this concept, we...
Correction to “Structurally Simple Osmium(II) Polypyridyl Complexes as Photosensitizers for Photodynamic Therapy in the Near Infrared”
Real‐Time Single‐Molecule Observation of a Chemical Reaction Reshaping the Energy Landscape of a Molecular Shuttle
ABSTRACT Artificial molecular machines often rely on chemical stimuli to switch between functional states, yet the real‐time dynamics of these transitions remain largely obscured by...
Stable Synapse‐Like Memory Switching in N‐Heterocyclic Carbene Monolayers
ABSTRACT We report a robust redox‐active N‐heterocyclic carbene (NHC) monolayer that exhibits synapse‐like behavior driven by proton‐coupled electron transfer (P...
Enabling Access to sp <sup>3</sup> ‐Enriched Targeted Protein Degraders via Redox‐Neutral Radical Cross‐Coupling
ABSTRACT Cullin‐RING Ligase 4 Cereblon (CRL4 CRBN )‐mediated targeted protein degradation (TPD) via cereblon (CRBN) E3 li...
Dual‐Site Substitution With Single Te Atoms in MoS <sub>2</sub> Boosting Hydrogen Evolution
ABSTRACT Heteroatom substitution is a promising strategy to enhance hydrogen evolution reaction (HER) activity of MoS 2 ,...
Reversible Structural Transformation Between a Hopf Link and a Solomon Link
ABSTRACT By utilizing the chemical reactivity of Ag(I) ions under mild conditions, we successfully demonstrated the reversible topological transformation between...
Operando Imaging Reveals Active Wrinkled Regions for Hydrogen Evolution in MoS <sub>2</sub> Electrocatalysts
ABSTRACT Under operando conditions, how local structural distortion influences electrocatalysis in non‐metallic materials remains poorly understood, largely beca...
Engineering Nanoemulsions to Maximize NIR‐II Fluorescence and Preserve Photothermal Performance of a Novel Boron Difluoride Formazanate Dye
ABSTRACT Boron difluoride formazanate (BDF) dyes possess intrinsic NIR‐I absorption and NIR‐II photoluminescence. However, their hydrophobic nature often leads t...
Photocatalytic Transfer Hydrogenation Using Plastic Hydrolysates as Hydrogen Donor
ABSTRACT The synthesis of aromatic amines requires harsh conditions or the use of fossil‐derived hydrogen (H 2 ). Here, w...
Supramolecular Assembly of Proteoliposomes Containing Photosensitizers Regulating Energy Synthesis
ABSTRACT We report that a biomimetic energy metabolism system can be constructed by integrating adenosine triphosphate (ATP) synthase and photosensitizer, and chlorin e6 (Ce6), into...
Aldehyde–Olefin Couplings by Photoinduced Reduction of Electron‐Deficient Olefins with Hantzsch Ester Anions
ABSTRACT Reductive couplings between aldehydes and olefins, both of which are low‐cost chemical feedstocks, provide facile access to valuable alcohol products. Recent advances in pho...