Angewandte Chemie International Edition
Articles in this Issue
Controlled Interruption of Electrochemical Nitrite Reduction for Switchable NH <sub>2</sub> OH and Formamide Synthesis
ABSTRACT Electrochemical nitrite reduction has the potential to yield a wide range of nitrogen‐containing products, yet it typically converges to fully reduced N...
Electrolyte‐Replacement‐Free Continuous Electrocatalytic Desalination Coupled With CO <sub>2</sub> Reduction at Record Throughput and Low Cost
ABSTRACT Integrating seawater desalination with electrocatalytic reactions offers an attractive pathway to address freshwater scarcity and reduce emissions simul...
Merging Biocatalysis and Chemocatalysis in Flow: State‐of‐the‐Art and Future Directions for Sustainable Synthesis
ABSTRACT The growing demand for complex molecules continues to drive innovation in organic synthesis, yet challenges in sustainability, selectivity, scalability, and harsh reaction c...
Photoactivated Signaling Networks using DNA‐Based Synthetic Organelles as Biomimetic Protocells
ABSTRACT Membraneless organelles formed by phase‐separated nucleic acid or protein condensates play vital roles in regulating cellular functions. Integrating suc...
Lead‐Based Metal‐Organic‐Framework Engineering Enables the Efficiency of Pure‐Red Perovskite CsPbI <sub>3</sub> Quantum Dot‐Based Light‐Emitting Diodes Exceeding 30%
ABSTRACT CsPbI 3 quantum dots (QDs) are promising for meeting the Rec. 2020 specified red emission but still face the iss...
Structurally Constrained Stibenium: Metallomimetic C−Si Bond Activation
ABSTRACT The chemistry of structurally constrained pnictogen centers continues to attract interest within the field of metallomimetic main‐group catalysis. Herei...
Interface‐Engineered Electron‐Deficient Nickel Species for Efficient Depolymerization of Polyethylene Terephthalate
ABSTRACT Polyethylene terephthalate (PET) is the most abundant polyester plastic. Its chemical recycling mainly relies on homogeneous catalysis, often suffering...
Regulating Mechano‐Electrochemical Process for Uniform Lithium‐Ion Extraction in Ni‐Rich Single‐Crystal Cathodes
ABSTRACT Both mechanical and electrochemical processes critically govern the performance of single‐crystal Ni‐rich cathodes of lithium‐ion batteries. Although el...
Stepwise Kinetics Promotion for High‐Rate Aqueous Zn Metal Batteries
ABSTRACT Metallic zinc anodes in aqueous zinc batteries suffer from uncontrolled dendrite growth and parasitic side reactions, leading to poor cycling stability,...
Amorphous MoO <sub>x</sub> Interfaces Activate Pt Nanoclusters for Ultralow‐Overpotential Chlorine Evolution
ABSTRACT Direct seawater electrolysis offers a pathway to co‐produce hydrogen and industrial chlorine, yet chlorine evolution at low chloride concentrations is l...
Modulating Intermediate Adsorption and Interfacial Water Structure to Unlock the Potential of Nickel for Ammonia Electrosynthesis and Zn‐NO <sub>3</sub> <sup>−</sup> Battery
ABSTRACT Metallic Ni stands out to be a promising electrocatalyst for nitrate reduction reaction (NO 3 RR) to ammonia (NH...
Pre‐Cluster Controlled Assembly of Oriented Mesopores in MOF Crystals
ABSTRACT Directional alignment of mesoporous channels in anisotropic crystals defines an unexplored paradigm, unlocking host‐guest interactions, mass transport, and catalytic functio...
Surface Oxide Species on Metal Cocatalysts Mediate Pathways in Water‐Oxidation‐Coupled CO <sub>2</sub> Photoreduction: Insights From Pd
ABSTRACT Photocatalytic overall CO 2 reduction using H 2 O as an electron donor i...
Dual‐Cation Batteries via Synergistic Cation‐Sieving Electrodes and Tailored Electrolytes
ABSTRACT This study presents a dual‐cation battery enabled by electrolyte engineering and cation‐sieving electrodes. The design leverages the high capacity, low...
Mechanistic Insights Into Protonation of Imine‐Linked Covalent Organic Frameworks: The Correlations With Photocatalytic Processes and High‐Performance Hydrogen Evolution
ABSTRACT Covalent organic frameworks (COFs), especially imine‐linked ones, are promising due to facile synthesis, stability, and tunable electronics. In these CO...
A Polyurea‐Crosslinked Gel Polymer Electrolyte for Solvation and Interphase Regulation in Lithium Metal Batteries
ABSTRACT Polyurea (PUR) electrolytes offer molecular tunability, robust mechanics, and strong Li‐salt affinity for lithium metal batteries, but their application...
From Cucurbit[7]Uril Armor‐Equipped Ferrocene to Nitrogen Self‐Doped Porous Carbon Hosting Fe Single Atoms and Atomic Clusters for ORR and Zinc‐Air Batteries
ABSTRACT Achieving both high activity and metal loading of atomically dispersed metal sites in M─N─C catalysts remain a formidable challenge. Herein, we employ t...
Probing Steady‐State Carrier Properties and Charge Transport in Covalent Organic Framework by Frequency‐Domain Terahertz Spectroscopy
ABSTRACT Terahertz (THz) spectroscopy is an emerging tool for probing charge transport and optical properties in covalent organic frameworks (COFs). Existing studies have predominant...
Smart Sonoafterglow Nanobombs for High‐Contrast Imaging and Synergistic Gas‐Sonodynamic Therapy of Hypoxic Tumors
ABSTRACT Precise diagnosis and effective eradication of hypoxic tumors remain formidable challenges in cancer therapy. Here, we report a smart sonoafterglow nano...
Mechanically Induced Switching Between Orbital‐ and Fano‐Resonance Rectification in a Dual‐Anchored Molecular Junction
ABSTRACT Achieving precise control over charge transport through individual molecules is central to advancing single‐molecule electronics. In short molecular junctions can exhibit re...
Consequences of Medium‐Pore Zeolite Constraints for Alkene Cracking—The Case of <i>n</i> ‐Pentene
ABSTRACT The catalytic cracking of alkenes in zeolites is of fundamental and industrial significance, yet the elementary steps of the mechanism are surprisingly...
Qing Tang
Fused‐Ring Acceptor–π–Acceptor Architecture Enables Near‐Infrared‐Absorbing Mesoporous Covalent Organic Frameworks for Enhanced H <sub>2</sub> O <sub>2</sub> Photosynthesis
ABSTRACT Covalent organic frameworks (COFs) featuring donor–acceptor architectures have shown great promise as photocatalysts. However, their performance is ofte...
Positional Isomerism Controls Polarity and Nonlinear Optical Properties in One‐Dimensional Hybrid Germanium Halides
ABSTRACT Organic–inorganic hybrid perovskites (OIHPs) exhibit abundant electronic configurations and structural versatility, rendering them promising candidates...
Remarkable Effect of Odd–Even Spacer in Supramolecular Polymerization and Piezoresponse of Amide‐Functionalized Naphthalene Diimides
ABSTRACT This study reports an unprecedented odd–even spacer‐length effect on the supramolecular polymerization and piezoelectricity of a series of amide‐functio...