Angewandte Chemie International Edition
Articles in this Issue
Tuning Redox Potentials in NASICON Cathode via Covalent Lattice Modulation
ABSTRACT NASICON‐type Na 3 MnTi(PO 4 ) 3...
Decoupling Kinetically Coupled Steps via Hierarchical Relay Catalysis on High‐Entropy Alloy for Efficient Ammonia Decomposition
ABSTRACT Ammonia (NH 3 ) is a promising hydrogen carrier owing to its high gravimetric hydrogen storage density (17.6 wt%...
Lock‐and‐Key Assembly Enables Record Birefringence in Monocyclic π‐Conjugated Crystals via Spatial Confinement of Linear Polyhalide
ABSTRACT Birefringent crystals are central to polarization optics, yet pushing birefringence (Δ n ) beyond 1.0 while reta...
Chiral Micellar Assemblies for Circularly Polarized Luminescence Amplification, Dye Encapsulation, and Multilevel Information Encryption
ABSTRACT Chiral micelles provide confined asymmetric environments that are attractive for diverse functional and technological applications. Here we report a BIN...
Surface Spin‐State Manipulation via a Strong Electronegative Ligand Field Enables Direct Regeneration of Spent Lithium‐Ion Battery Cathodes
ABSTRACT The rapid growth of lithium‐ion batteries has intensified the need for efficient recycling of spent LiNi 0.5 Co...
Hydrophobic Tag Degraders Overcome Endocrine‐Resistant Breast Cancer by Recruiting HSP27‐Mediated E3 Ligase Complex for ERα Proteasomal Degradation
ABSTRACT Hydrophobic tag (HyT)‐mediated protein degradation has emerged as a pivotal tool for targeted protein degradation (TPD), yet its underlying degradation...
Color‐Pure Organic Luminophores: Characteristics, Definitions, Physical Basis and Fundamental Design Principles
ABSTRACT Color‐pure all‐organic emitters, i.e., with narrow spectral characteristics, are intensively studied for high‐definition organic LEDs (mainly based on m...
Topology‐Engineered Coordination Polymers for Enhanced Hole Transport in Organic Solar Cells
ABSTRACT The commercialized PEDOT:PSS is the most commonly used hole‐transporting material in organic solar cells (OSCs) due to its solution processability, good transparency, and un...
Vapor‐Phase Grain‐Boundary Anchoring Enables Molecular Toughening and Record Bending Endurance in Pilot‐Scale Roll‐to‐Roll‐Printed Flexible Perovskite Modules
ABSTRACT Flexible lead‐halide perovskite solar modules with carbon electrodes (C‐fPSMs) are promising for printed photovoltaics due to their low cost and compati...
Self‐Assembled Liquid Crystal Interphase Enabling Long‐Life All‐Iron Redox Flow Batteries
ABSTRACT Aqueous all‐iron redox flow batteries (AIRFBs) are an attractive avenue for large‐scale energy storage due to the safety and cost‐effectiveness of iron....
Spatiotemporally Resolved Protein Tagging for Dynamic and Tissue‐Specific Secretome Profiling In Vivo
ABSTRACT The dynamic and tissue‐specific nature of protein secretion underlies a wide range of physiological and pathological processes, yet tools for profiling...
Self‐Limiting Covalent Ligation Mechanism Enabling Anomalously High Interfacial Compatibility in Organic‐in‐Sulfide All‐Solid‐State Lithium Batteries
ABSTRACT Polymer‐in‐sulfide composite electrolytes have emerged as highly promising candidates for all‐solid‐state lithium batteries (ASSLBs) due to their on‐dem...
Photocatalytic Methane Oxidation to Carbonyl Products
ABSTRACT Direct photocatalytic oxidation of methane (CH 4 ) to value‐added carbonyl compounds, such as formaldehyde (HCHO...
Mechanically Regulated Nanozymes for Remote Metabolic Reprogramming and Precise Cancer Therapy
ABSTRACT Mechanoenzymes, featuring catalytic activity controlled by mechanical stimuli, play key roles in maintaining metabolic order and cellular homeostasis. However, artificial na...
A Ruthenium‐(Ph‐BPE) Catalyst for Asymmetric Alkynylation of Fluoral: Enantioselection From 1 of 12 Fluxional Stereogenic‐at‐Ruthenium Complexes
ABSTRACT An iodide‐bound ruthenium catalyst derived from RuHCl(CO)(PPh 3 ) 3 and...
Latent Catalysis as a Platform for Accessing Diverse Material Properties in Vat Photopolymerization 3D Printing
ABSTRACT Vat photopolymerization (VP) 3D printing is an attractive strategy to manufacture customized polymer parts. The properties of printed materials are limited by the need to em...
Br‐Mediated Pd Catalysis Promotes Intermediates Stabilization and Coupling for Anodic Electrosynthesis of Dimethyl Carbonate
ABSTRACT Electrosynthesis of dimethyl carbonate (DMC) from methanol (MeOH) and CO on a Pd‐based catalyst has shown high selectivity; however, most of the corresp...
Reversing the Hydrogenation Pathways of Nitrogen‐Containing Intermediates for the Kinetics‐Matched Urea Electrosynthesis
ABSTRACT Urea electrosynthesis from carbon dioxide (CO 2 ) and nitrate (NO 3 −...
Novel Non‐Cytotoxic Acylphosphinates and Acylphosphine Oxides Photoinitiators
ABSTRACT This study focused on the design and synthesis of a series of novel acylphosphine oxide (APO) and acylphosphinate photoinitiators based either on diphenylphosphine oxide (DP...
Correction to “Borohydride Oxidation as Counter Reaction in Reductive Electrosynthesis”
Stabilizing the Hexacyanotrimethylenecyclopropane Electron Acceptor—Structural and Photophysical Characterization
ABSTRACT Hexacyanotrimethylenecyclopropane ( CN6CP ) is an exceptionally strong organic electron acceptor in its neutral...
Tailored Nanogel Network Topology Enables Clinical Ultrasound‐Induced Mechanochemical Activation for In Vivo Therapy
ABSTRACT Polymer mechanochemistry enables the selective mechanophore activation for precise molecular release. However, this field has long relied on the strong...
Matching the Coupling of Valence Electrons in the Oxide Interface to Perturb the Magnetic Order Enhancing Oxygen Reduction in Zinc–Air Batteries
ABSTRACT The inherently locked spin state between the metal sites and oxygen‐containing intermediates imposes an intrinsic limitation on the maximum achievable o...
Synergistic High‐Connectivity and Nonplanar Conformation Generates a Stable Hydrogen‐Bonded Organic Framework for Benchmark Methanol‐to‐Olefin Product Separation
ABSTRACT Hydrogen‐bonded organic frameworks (HOFs) are promising porous materials, yet their development is hindered by an inherent trade‐off between structural...
Unveiling Aziridine‐Containing Natural Products by Genomic and Spectroscopic Approaches
ABSTRACT Aziridine‐containing natural products are prized for their potent bioactivities, yet their scarcity and poorly understood biosynthesis have limited syst...