Angewandte Chemie International Edition
Articles in this Issue
Robert Luxenhofer
Introducing the Aziridination of Fluorinated Olefins by Metal‐Catalyzed Nitrene Transfer
AbstractAfter decades of development of the metal‐catalyzed nitrene transfer reactions to olefins, examples involving the use of fluorinated olefins is yet unknown, despite the current importance of f...
Isolated and Paired Metal Sites in Zeolites Using Solid‐State Ion Exchange
AbstractIsolated and paired extraframework transition metal cations in zeolites are emerging as top candidates for numerous applications, including, but not limited to, selective methane oxidation to...
Biomimetic Hierarchical Construction of Anti‐Tumor Polyoxopalladates for Cancer Therapy
AbstractInspired by the construction scheme of biomacromolecules, a hierarchical assembly based on the lacunary polyoxopalladate (POP) of [SrPd12O6(OH)3(PhAsO3)6(OAc)3]4− (SrPd12) has been achieved. A...
Tailored 3‐Alkoxy‐<i>N</i>,<i>N</i>,<i>N</i>,2,2‐Pentamethylpropan‐1‐Ammonium <i>Bis</i>(trifluoromethylsulfonyl)Imide Ionic Liquids for Room‐Temperature Fluoride‐Ion Batteries
AbstractTwo novel liquid electrolytes for room‐temperature fluoride ion batteries are presented. These electrolytes are based on ionic liquids with quaternary ammonium cations 3‐methoxy‐N,N,N,2,2‐pent...
Marvin Parasram
Synergistic Solvent and Composition Engineering of Perovskites for Tandems on Industrial Silicon
AbstractWide‐bandgap perovskites based on mixed formamidinium−cesium cation and iodide−bromide halide are promising materials in the top cells that are well‐matched with crystalline silicon bottom cel...
Enhanced <i>p–d</i> Orbital Coupling in Unconventional Phase RhSb Alloy Nanoflowers for Efficient Ammonia Electrosynthesis in Neutral Media
AbstractPhase control provides a promising approach for physicochemical property modulation of metal/alloy nanomaterials toward various electrocatalytic applications. However, the controlled synthesis...
Symmetry‐Breaking Strategy Yields Dopant‐Free Small Molecule Hole Transport Materials for Inorganic Perovskite Solar Cells with 20.58% Efficiency and Outstanding Stability
AbstractInorganic perovskites are known for their excellent photothermal stability; however, the photothermal stability of all‐inorganic n‐i‐p perovskite solar cells (PSCs) is compromised due to ion d...
Back Cover: Quantum Mechanical Tunnelling Probes With Redox Cycling for Ultra‐Sensitive Detection of Biomolecules (Angew. Chem. Int. Ed. 23/2025)
Linkages Chemistry of Covalent Organic Frameworks in Photocatalysis and Electrocatalysis
AbstractCovalent organic frameworks (COFs) have emerged as promising candidates for electrocatalysis and photocatalysis applications due to their structurally ordered architectures and tunable physico...
Photocatalytic Generation of a Ground‐State Electron Donor Through Water Activation
AbstractElectron donors that can be excited to higher energy states through light absorption can achieve oxidation potentials as low as −3.0 V (vs. SCE). However, ground‐state organic electron transfe...
Asymmetric Synthesis of Noradamantane Scaffolds via Diphenylprolinol Silyl Ether‐Mediated Domino Michael/Epimerization/Michael (or Aldol)/1,2‐Addition Reactions
AbstractTopologically unique chiral noradamantanes are synthesized using a diphenylprolinol silyl ether‐mediated domino Michael/epimerization/Michael/1,2‐addition or Michael/epimerization/aldol/1,2‐ad...
Regioselective Nickel‐Catalyzed Hydroarylation of <i>gem</i>‐Difluoroalkenes for the Synthesis of the ArCF2−${\rm{ArCF}}_{{2}^{-}}$ Moiety
AbstractThe incorporation of fluorine and fluorinated functional groups into organic molecules alters their physicochemical properties, thereby facilitating the advancement of novel therapeutics, agri...
Bright and Versatile Azetidinecarboxamide‐Based Fluorophore–Ligand Conjugates for High‐Resolution Cell Imaging
AbstractFluorophore–ligand conjugates play a pivotal role in cellular imaging, providing high target specificity. However, simultaneously achieving conjugates with high brightness and ligand‐targeting...
Pressure‐Induced Emission Luminogens Enable Optical Logic Gates Toward Lighting, Scintillators, and Anti‐Counterfeiting
AbstractThe pressure‐induced emission luminogens (PIEgens) opened the door to highly emissive materials. However, the high‐pressure phase with excellent optoelectrical properties is difficult to stabi...
Solid‐State Photoconversion of a Discrete Mixed Iodine(I) System to a 1D Polymer
AbstractThe first example of a mixed halogen(I) complex (2), containing three distinct iodine(I) moieties ([N―I―N]+, O―I―N, and [O―I―O]−) within the same structure, was synthesized with 4‐styrylpyridi...
Dynamic Borate Esterification for Evolved Supramolecular Chirality and Chiral Optics
AbstractTopological chemical reactions in confined environments offer unique opportunities for constructing dynamically tunable crystalline materials and architecturally defined polymers. However, the...
Modulating the Chromophores of Metal‐Covalent Organic Frameworks for Boosting Low‐Concentration CO<sub>2</sub> Photoreduction
AbstractThe development of efficient photocatalysts to convert low‐concentration CO2 into the value‐added chemicals and fuels is particularly interesting yet remains highly challenging. Herein, we des...
Monitoring Glycolysis by Endogenous <sup>31</sup>P CEST Magnetic Resonance Imaging
AbstractIn this study, we present a novel approach to investigate glycolysis by means of the 3¹P CEST technique applied to phosphate‐containing substrates at their endogenous concentration. The method...
A Nucleus‐Targeting Ruthenium(II) Complex Induces DNA Condensation in Cisplatin‐Resistant Tumor Cells
AbstractOne of the conventional ways to eradicate tumor cells is to utilize chemotherapy agents, e.g., cisplatin, to induce DNA damage. However, DNA damage repair mechanisms can significantly limit th...
Electron Acceptors Based on Resonant N─B←N Unit with Improved Exciton Dissociation for High‐Performance Short‐Wavelength Infrared Organic Photodetectors
AbstractDevice performance of photodiode‐type short‐wavelength infrared (SWIR) organic photodetectors (OPDs) is largely limited by poor exciton dissociation. In this work, we reported that downshifted...
Concise Total Syntheses of Leuconoxine‐Type Alkaloids Enabled by Palladium/Norbornene‐Catalyzed Pyrrole Difunctionalization
AbstractConcise total syntheses of five leuconoxine‐type alkaloids, i.e., chloromelodinine, leuconodine A, leuconodine F, melodinine E, and leuconoxine, are achieved through a pyrrole‐centered strateg...
Blocking the <i>Operando</i> Formation of Single‐Atom Spectators by Interfacial Engineering
AbstractAside from activity and selectivity, catalyst stability is a key focus in heterogeneous catalysis research. Although sintering of metal species has been considered the primary cause for deacti...
Interfacial Lithium Cations Catalyze Biomimetic Aerobic Oxygenation via Short‐Range Electrostatic Interaction
AbstractEnzymes often involve short‐range electrostatic interactions in the deliberate microenvironment for accelerating the catalysis. Comparatively, electrostatic interactions from ions in solutions...