Angewandte Chemie International Edition
Articles in this Issue
Crystallization/Precipitation Driven Nonequilibrium Ring‐Opening Polymerization of Thiovalerolactone Toward Closed‐Loop Recyclable Polythioester with Excellent Barrier Properties
Abstract The development of closed‐loop recyclable polymers with comparable performances with commodity plastics remains as a challenge to establish a circular plastic economy. In th...
Selective Hydrogenation of Phenols to Cyclohexanones Over Hydrotalcite‐Supported Pd Single‐Atom Catalyst
Abstract Cyclohexanones are widely used chemicals and currently produced by the oxidation of the fossil feedstocks. Direct selective hydrogenation of lignin derivatives has great pot...
Spatiotemporal Super‐Resolution Imaging of Lipid Metabolism Dynamics in Physiological/Pathological Conditions
Abstract Dysregulated lipid metabolism plays a critical role in the pathogenesis of numerous diseases. However, due to the lack of effective solutions, the dynamic monitoring and dee...
Hydrogen‐Bonding‐Driven Site‐Selective Activation of α‐C(sp <sup>3</sup> )─H in Alcohols: A Straightforward Dual‐Catalysis Strategy for Efficient Acceptorless Dehydrogenation
Abstract The transformation of alcohols into corresponding carbonyl derivatives is of paramount importance for the construction of complex molecules. Current str...
Promoting the Intermediates Hydrogenation for Urea Electrosynthesis Over an “Active Hydrogen Pump” Catalyst
Abstract Electrocatalytic coupling of CO 2 and NO 3 − offers...
Ultrasound‐Responsive Lipid Nanosonosensitizers with Size Reduction and NO Release: Synergistic Sonodynamic‐Chemo‐Immunotherapy for Pancreatic Tumors
Abstract Pancreatic cancer (PC) remains difficult to treat due to its dense extracellular matrix (ECM), immunosuppressive tumor microenvironment (TME), and deep‐seated anatomy. To ad...
Achieving Uniform Phase Structure for Layer‐by‐Layer Processed Binary Organic Solar Cells with 20.2% Efficiency
Abstract Layer‐by‐layer (LBL) deposition has become a facile and promising method to fabricate highly efficient organic solar cells (OSCs). However, characterization and optimization...
“Electricity”‐Assisted Catalytic Solar‐to‐Fuel Processes
Abstract Efficient conversion of solar energy into chemical fuels is pivotal for establishing sustainable energy systems, yet persistent challenges in carrier dynamics and reaction s...
Lewis Acidity of the SbCl <sub>3</sub> / <i>o</i> ‐chloranil System
Abstract While SbCl 3 is typically inert toward oxidation by ortho ‐quinones, we...
Identifying the Role of Solvation Entropy for the Solvation Chemistry in Nonaqueous Electrolytes
Abstract Solvating power, a pivotal determinant of solvation structure, has been extensively studied in past few decades. However, extant descriptors such as don...
Tuning the Crystallization and Photothermal Aging Chemistry of CsPb <sub>0.4</sub> Sn <sub>0.6</sub> I <sub>3</sub> for Inorganic Perovskite Tandem Photovoltaics
Abstract The poor performance of inorganic narrow bandgap perovskite solar cells (PSCs) hinders the development of inorganic perovskite tandem solar cells (IPTSC...
From Amino Acids to α‐Keto Acids via β‐Elimination and Transamination Initiates a Pathway to Prebiotic Reaction Networks
Abstract α‐Keto acids, such as pyruvate and glyoxylate, may have been critical in generating reaction networks at the origins of life due to their facile carbon–carbon bond formation...
Modulating Electric Double Layers via Polymer Electric Dipole Effects to Enhance Stability in Quasi‐Solid‐State Sodium Metal Batteries
Abstract The interfacial instability of Na metal anodes poses a significant barrier to the practical applications of sodium metal batteries. According to electri...
Molecular Engineering of Weakly Solvating Dinitrile Electrolytes for Long‐Lasting Room‐Temperature Lithium Metal Batteries
Abstract The development of lithium metal batteries (LMBs) relies on advanced solid‐state electrolytes. Solid‐state polymer electrolytes (SPEs) offer advantages...
An All‐in‐One Nanohole Array for Size‐Exclusive Trapping and High‐Throughput Digital Counting of Single Extracellular Vesicles for Non‐Invasive Cancer Screening
Abstract The analysis of single small extracellular vesicles (sEVs) could distinguish the heterogeneity of sEVs thus better extract tumor‐related signatures. Current protocols for th...
High‐Performance Al–S Batteries by Spin Polarization Modulation via Catalytic Ni‐MoS <sub>2</sub> Nanosheets
Abstract Aluminum–sulfur (Al–S) batteries catalysts with adsorption and catalytic capabilities can effectively improve the slow redox kinetics, but the current r...
Engineering Charge Polarized Au Sites for Low‐Temperature Acetylene Hydrochlorination
Abstract Cationic gold catalyzed acetylene hydrochlorination represents a classical landmark in eliminating global mercury pollution, but their sustainable imple...
2D/2D MOF/MXene Schottky Junction: Prolonged Carrier Lifetime and Enhanced Hydrogen Evolution Efficiency
Abstract Harnessing sunlight for photocatalytic overall water splitting offers a sustainable approach to renewable hydrogen (H 2...
Imidazo[1,5‐ <i>a</i> ]pyridines – A Versatile Platform for Structurally Distinct <i>N</i> ‐Heterocyclic Olefins and π‐Extended Heterocycles
Abstract The synthesis of polarized N ‐heterocyclic olefins (NHOs) based on an imidazo[1,5‐ a...
Synthesis of Molecular Organo‐f‐Element‐Polyphosphides with Nonclassical Divalent Lanthanide Precursors
Abstract The coordination and functionalization of white phosphorus (P 4 ) by transition metal and main group element com...
An Oxidative Stress Nanoamplifier to Enhance the Efficacy of Cisplatin in Head and Neck Cancer
Abstract Cisplatin (CP) is a first‐line platinum‐based drug used for the treatment of head and neck cancer. However, tumor cells can diminish the therapeutic eff...
On the Role of Molecular Conformation of the Passivating Agents for High‐performance Perovskite Solar Cells
Abstract Molecular structure engineering of passivating agents has proven to be a pivotal strategy for developing high‐performance perovskite solar cells (PSCs). Although previous st...
Green Electrosynthesis of Hydroxylamines via CuS Suppressing N─O Bond Cleavage
Abstract Organic hydroxylamines, pivotal intermediates in pharmaceutical and polymer chemistry, face persistent challenges in selective synthesis. Its main diffi...
An Organic‐Inorganic‐Integrated Solid Electrolyte Interphase with High‐Resilience and Anti‐Corrosion for Sustainable Zinc Metal Anode
Abstract Aqueous zinc metal batteries (AZMBs) are highly regarded for their exceptional safety, low cost, environmental compatibility, and potential as a sustain...
Probing the Nonlinear Chiroptical Activity of Multiturn Aromatic Helices Using Linearly Polarized Light
Abstract Four quinoline‐based oligoamide foldamers of varying lengths, from 6 to 28 Å, were synthesized in both of their enantiomeric forms, exhibiting between 1.6 and 6 helical turn...