Angewandte Chemie International Edition
Articles in this Issue
Encapsulation Enhances the Quantum Coherence of a Solid‐State Molecular Spin Qubit
Abstract Spins within molecules benefit from the atomistic control of synthetic chemistry for the realization of qubits. One advantage is that the quantum superp...
Intramolecular Phosphinyl‐Zincation of Alkynes: A Powerful Entry to Benzophosphole Oxides
Abstract Upon reacting ortho ‐alkynylated secondary arylphosphine oxides with Et 2...
Regulation of Relay Catalytic Mechanism for Efficient Methanol Oxidation Reaction
Abstract The methanol oxidation reaction serves as a representative model for multistep catalytic processes involving diverse intermediates. Catalyst design stra...
Acid‐Alkaline Double Electrolytes for High‐Energy Aqueous Proton Batteries
Abstract Aqueous proton batteries offer a promising energy storage solution due to their inherent safety, rapid ion mobility, and low cost. However, their perfor...
Correction to “Hyperpolarization of <sup>15</sup> N‐Pyridinium by Using Parahydrogen Enables Access to Reactive Oxygen Sensors and Pilot In Vivo Studies”
Hydrogen Bridge‐Mediated Efficient Electrooxidation of 5‐Hydroxymethylfurfural on Ni(OH) <sub>2</sub> ─PO <sub>4</sub> <sup>3−</sup> /Ni <sub>3</sub> (PO <sub>4</sub> ) <sub>2</sub> Heterojunctions
Abstract Accelerating proton deintercalation and transfer on the catalyst surface is crucial for the electrochemical oxidation of 5‐hydroxymethylfurfural (HMF) i...
Heteroporous Donor‐Acceptor Covalent Organic Framework Cathode for High‐Rate‐Capacity Lithium‐Ion Battery
Abstract Covalent organic frameworks (COFs), a conspicuous porous material, harvest great promise for rechargeable batteries, owing to well‐defined pore structur...
Generalizing Vinyl Halide Cross‐Coupling Reactions with Photoredox and Photoredox/Nickel Dual Catalysis
Abstract Reliable, broadly applicable cross‐coupling conditions that deliver the desired products with minimal optimization are essential in pharmaceutical resea...
Potent Fluorescent Probe for Target‐Engagement Studies of Allosteric Pyruvate Kinase Modulators
Abstract Pyruvate kinases (PKs) are highly allosterically regulated enzymes that play a central role in cellular metabolism and are increasingly recognized as va...
Peptidic Tryptophan Halogenation by a Promiscuous Flavin‐Dependent Enzyme
Abstract Amino acids undergo numerous enzymatic modifications. However, the broad applicability of amino acid‐modifying enzymes for synthetic purposes is limited by narrow substrate...
Olefin Ligand Metathesis for Colloidal Emissive Nanocrystals with Enhanced Stability and Photosensitivity
Abstract High‐resolution patterning of colloidal perovskite nanocrystals (PNCs) is essential for next‐generation display technologies, yet conventional approaches relying on exogenou...
Enantioselective Synthesis of Cyclobutane‐fused Heterocycles via Lewis Acid‐Catalyzed Dearomative [2+2] Photocycloaddition of Indoles, Benzofurans, and Benzothiophenes with Alkenes
Abstract Cyclobutane‐fused heterocycles are important motifs in biologically active molecules, yet their enantioselective synthesis remains a significant challenge. We report a broad...
Isolable Arylphosphinidene Chalcogenides and their Radical Anions
Abstract We report the synthesis, characterization, and reactivity of isolable arylphosphinidene chalcogenides (Ar─P═E; 2...
Strong Dipole Moments and Increased Charge Transfer in Polymer‐Based Solid Electrolyte Enable Wide‐Temperature Solid‐State Lithium Metal Batteries
Abstract The development of solid electrolyte interfaces (SEI) using lithium and nitrate salts represents a promising approach to enhancing the performance of li...
Poly(benzoxazine)‐Based Gel Polymer Electrolytes for Lithium Metal Batteries With Ultralong Lifespans
Abstract Gel polymer electrolyte (GPE) is a desirable candidate for high‐safety lithium batteries but is still plagued by the dynamic fluctuations of liquid elec...
Catalytic Strategies for Stereoselective Carbohydrate Synthesis: Emerging Concepts for Accessing Challenging Glycosides
Abstract The development of innovative catalytic strategies for stereoselective carbohydrate synthesis is rapidly emerging as a theme of general synthetic interest. This research fro...
Transsulfurase‐Catalyzed Reversible Modification of C‐Terminal Cysteine and Application for Orthogonal Dual Labeling of Proteins
Abstract Protein thiol bioconjugation in combination with reversible modification of cysteine is a powerful strategy for orthogonal dual labeling of protein cyst...
The Crucial Role of Solvent and Bound Oxygen on the Interplay of Cerium (III) and Cerium (IV) Chloride in a Photocatalytic Cycle for Organic Transformations
Abstract Here, we investigate the fundamental interactions between Ce (III) chloride, molecular oxygen, and various solvent environments to elucidate their colle...
3D Hydrogen‐Bonded Organic Framework Assembled from 1D Coordination Polymers for Efficient Gas Dehydration
Abstract Two ‐(2D) and three‐dimensional (3D) porous coordination polymers have been extensively explored for their porous nature and thus gas separation, but on...
Monomer‐Dependent Selectivity in Sulfur‐Containing Ring‐Opening Copolymerisation: Bimetallic Catalysis for Predictive Design of Degradable Polymers
Abstract Sulfur‐containing polymers offer unique opportunities for advanced materials due to their inherent degradability, high refractive indices, and potential...
Copper‐Stabilized Nitrene Radical in N─N Coupling: Facile Synthesis of Hydrazides and Pyrazole
Abstract Despite extensive studies of electrophilic copper‐nitrenoid species in nitrene transfer chemistry, the formation and application of Cu‐nitrene radicals...
Catalytic Stereoselective Silyl‐ and Boraformylations: Charting a Challenging Road Ahead
Abstract This minireview highlights key milestone discoveries in (stereoselective) silylformylation and boraformylation reactions—formal additions of a formyl group (CHO) and a silyl...
In Situ Cation‐Switched Organometallic Cage Reconfiguration Enables Highly Selective Li <sup>+</sup> Recognition and Extraction
Abstract Biomacromolecular selectivity paradigms, epitomized by the “induced‐fit” concept, motivate adaptive supramolecular designs; however, cationic guest‐dire...
Pyrrole‐Linked Benzimidazolyl Hydrazone Self‐Assembly Forms HCl Channels and Induces Apoptosis in Cancer Cells
Abstract Modulation of intracellular chloride ion concentration by artificially developed ion transporters has been known to induce apoptosis in cancer cells. Ho...
Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide
Abstract This paper describes the fabrication of multifunctional electronic textiles (e‐textiles) capable of simultaneous detection and uptake of hydrogen sulfid...