Angewandte Chemie International Edition
Articles in this Issue
Flow Pyrolysis Synthesis of Single‐Atom Catalysts With Tunable Crumple and Electronic Structures for 2‐Electron Oxygen Reduction
ABSTRACT Single‐atom catalysts (SACs) are attractive due to their high metal utilization efficiency and intriguing properties. Developing a facile and general me...
Color‐Fidelity Stepwise Charge‐Transfer Modulation Enables Highly Efficient BT.2020‐Compliant Deep‐Blue OLEDs
ABSTRACT Achieving deep‐blue organic emitters that combine high efficiency with the strict color purity required for the BT.2020 display standard remains one of...
One‐Dimensional Polycyclic Aromatic Hydrocarbons Incorporating Multiple Dithiafulvene Units—Novel Multi‐Redox and Electrochromic Systems
ABSTRACT The combination of polycyclic aromatic hydrocarbons (PAHs) and dithiafulvene (DTF) units provides large π‐conjugated scaffolds with multi‐redox behavior. Here, we present th...
Multidentate Molecular Suturing at Dual Interfaces Enables Highly Efficient Perovskite Light‐Emitting Diodes
ABSTRACT Perovskite light‐emitting diodes (PeLEDs) have emerged as a promising technology for future displays owing to their prominent optoelectronic properties....
Multiferroic Orders and Piezoelectric Sensing in an Organic‐Inorganic Bismuth Halide
ABSTRACT Multiple ferroic orders integrated into a single material pose great potential for next‐generation sensing, memory and switching devices. Organic‐inorga...
Structural Insights Into CO <sub>2</sub> Transport Pathways in a W‐Formate Dehydrogenase: Structural Basis for CO <sub>2</sub> Reduction
ABSTRACT Mo/W‐dependent formate dehydrogenases (Fdhs) catalyze the reversible reduction of CO 2 to formate and are key bi...
Anion‐Controlled Structural Interconversion of Palladium Cages Enables Separations by Selective Guest Capture and Release
ABSTRACT Self‐assembled host–guest systems provide a powerful platform for molecular recognition and binding. Achieving the controlled and selective release of b...
Salt‐Regulated Confinement of FeO Microcrystallites on Amorphous Mn <sub>3</sub> CoO <sub>x</sub> for Boosting Sustainable Acidic Water Oxidation
ABSTRACT Nanomaterials with amorphous surface have attracted significant attention in the oxygen evolution reaction (OER), which still needs further investigatio...
CD44‐Assisted Transcytosable Chimeras for Extracellular Protein Depletion in Deep Tumors
ABSTRACT Extracellular targeted protein degradation (eTPD) typically uses antibody‐derived bifunctional chimeras to direct extracellular targets toward lysosomal degradation. However...
Engineered Biomimetic Nanoparticles With Targeted Delivery of Chlorothiazide for the Treatment of Inflammatory Bowel Disease
ABSTRACT While conventional treatment strategies for inflammatory bowel disease (IBD) focus primarily on suppressing overactive immunity, there is still a lack o...
Conformational Editing Drives Covalent Hybridization for Nonlinear Optical Crystals
ABSTRACT The covalent integration of planar organic molecules with inorganic tetrahedra into crystalline solids is fundamentally constrained by steric repulsion....
Engineering Amino Acid Functionalized Chiral Carbon‐Organic Frameworks for Enhanced Photocatalytic Hydrogen Production
ABSTRACT The spin‐dependent recombination behavior of photogenerated charges has long been overlooked in the study of photocatalytic hydrogen (H...
Zwitterionic Engineering of Vinylene‐Linked Covalent Organic Frameworks for Superior Protonic Electrolytes
ABSTRACT Solid protonic electrolytes are a promising avenue for advanced solid‐state proton batteries, offering enhanced safety, long‐term cycling stability, and...
Tailored Pyridine Enables Diverse Electrochemical Benzylic C–H Functionalization
ABSTRACT C─H diversification strategies that enable access to various C─X (X = heteroatom) and C─C bonds are of central importance in synthetic chemistry. Here we present a benzylic...
Enantioselective Synthesis of Axially Chiral Anthracenes via [4+2] Cycloaddition and Cycloreversion of Cyclopentadienones
ABSTRACT The sequential inverse‐electron‐demand [4+2] cycloaddition and cycloreversion of cyclopentadienones with alkynes or alkenes represent one of the most important approaches fo...
Dynamic Decoupling of Pt─H Intermediates Formation From Water Dissociation for Efficient Alkaline Hydrogen Evolution
ABSTRACT The formation of metal–hydrogen intermediates (M─H*) is critical for the alkaline hydrogen evolution reaction (HER), but is kinetically hindered by the...
Surface Dynamic Redox Modulation of CuFe Achieving Near‐Unity Selectivity in Solar‐Integrated Nitrate‐to‐Ammonia Conversion
ABSTRACT Electrocatalytic nitrate reduction (NO 3 − RR) provides a sustainable pathway for NH...
A Real‐Time Antifouling Multivalent Aptamer Platform for Wash‐Free Electrochemical Detection of Low‐Abundance Biomarkers in Human Plasma
ABSTRACT Sensitive and specific detection of low‐abundance proteins in complex biofluids is essential for early disease diagnosis and real‐time health monitoring...
Highly Active Nodules on Concave–Convex Channel Walls of Covalent Organic Frameworks for Photocatalytic Hydroperoxide Production
ABSTRACT Covalent organic frameworks (COFs) are promising photocatalysts for hydrogen peroxide (H 2 O...
Photocatalytic Cross‐Coupling of Phenols and Heteroaryl Halides With Machine Learning‐Guided Reaction Prediction
ABSTRACT Developing sustainable methods for C(sp 2 )─C(sp 2 ) bond formation that...
Electronic‐Effect‐Guided Bifunctional Iron Catalyst for the Copolymerization of Epoxides and Anhydrides: Enabling the Synthesis of High Molecular Weight Polyesters
ABSTRACT Ring‐opening copolymerization (ROCOP) of epoxides and anhydrides using metal‐based catalysts is a promising route to synthesize polyesters. However, conventional catalysts s...
Direct Oxidation of Methane to Formaldehyde With Molecular Oxygen Catalyzed by Gold‐Tungsten Oxide Cluster Cations
ABSTRACT Catalytic direct oxidation of methane with molecular oxygen can be highly exothermic in thermodynamics. It offers a promising green method for productio...
Water‐Soluble Pd <sub>8</sub> L <sub>4</sub> Barrel for Binding of Versatile Hydrophobic Dyes and Visible‐Light Promoted Catalysis in Aqueous Medium
ABSTRACT Achieving efficient supramolecular recognition of hydrophobic dyes and their use as photosensitizers in water remain a major challenge because of their...
A Convenient, Safe, and Atom‐Economical Route to a Large Portfolio of Grubbs‐Type Catalysts for Olefin Metathesis via Four‐Coordinate Ruthenium Alkylidynes
ABSTRACT p ‐Tolyl(trimethylsilyl)diazomethane is a readily accessible and easy‐to‐handle net carbyne donor reagent. It reacts with [(...
Nanotwinning of the Nickel Nitride Nanosheets for Robust Hydrogen Oxidation Electrocatalysis
ABSTRACT Nanotwinning of heterogeneous electrocatalysts represents an attractive tool to reconfigure the interfacial microenvironments with refined delivery and...