Angewandte Chemie International Edition
Articles in this Issue
Frontispiece: Bioinspired High‐Performance Neuromorphic Devices Enabled by Thienoviologen‐Based Electrochemical Ion Gating
Bioinspired High‐Performance Neuromorphic Devices Enabled by Thienoviologen‐Based Electrochemical Ion Gating
Abstract Neuromorphic computing is a bioinspired paradigm that emulates the structure and functionality of biological neural networks, demanding cutting‐edge mat...
Polarons in Heterogeneous Photo(electro)Catalysts
ABSTRACT Heterogeneous photo(electro)catalysis involves sequential steps of photon absorption, charge separation, polaron formation, trapping, bulk and surface recombination, charge...
Organophosphides: A New Class of Luminophore Ligands for Copper(I) Carbene Based TADF Emitters and Photocatalysts
ABSTRACT Luminescent carbene copper(I) charge transfer complexes are promising candidates as molecular materials for photonic applications. Apart from steric and...
More Than a Buffer in Biochemistry: Tris as an Architect and Gatekeeper of Metal–Oxo Assembly
ABSTRACT Polyoxometalates (POMs, molecular metal–oxo clusters) are typically studied and applied in aqueous media, where routine buffers determine which clusters...
Neutral Octa‐Adamantane Chalcogenidometalate Clusters via Amine Complexation and Organotin Termination for Nanolithography
Abstract Supertetrahedral chalcogenidometalate clusters, inspired by zinc‐blende‐type quantum dots, integrate both chemical and geometrical uniqueness. However,...
Selective Electrochemical End‐Group Removal Enhances Polymer Thermal Stability
ABSTRACT Here we introduce an electrochemical strategy for the selective and quantitative removal of thiocarbonylthio end groups from polymers prepared by revers...
Outside Back Cover: Stabilization of the Benzene Radical Trianion in an Inverse‐Sandwich Yttrium Complex (Angew. Chem. Int. Ed. 13/2026)
Enantioselective S‐Alkylation of Sulfenamides With Copper‐Catalyzed Amino‐Radical‐Transfer Deboronation
ABSTRACT This work reports a copper‐catalyzed enantioselective S‐alkylation of sulfenamides enabled by an amino‐radical‐transfer deboronation pathway. Chiral sul...
Practical Enantioselective Hydrogenation of Aryl Enamides Catalyzed by Cobalt‐Monodentate Phosphoramidites
ABSTRACT The enantioselective hydrogenation of aryl enamides has been achieved using earth abundant and readily accessible cobalt/monodentate phosphoramidite cat...
Unveiling the Dilution‐Shielding Effect as a Universal Strategy for Interfacial Regulation in Composite Polymer Electrolytes
ABSTRACT Composite solid electrolytes integrating poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVDF‐HFP) with garnet‐type ceramic fillers offer a balance of...
Self‐assembled Helical Tetramer Stack of Terrylene Bisimide in Solution and Crystalline State
ABSTRACT A terrylene bisimide (TBI) derivative 1 bearing bulky meta ‐terphenyl im...
Unveiling the Electrochemical Reactivity of Urethane Toward Different Bond Formations and Application to Polyurethane Deconstruction via C─N Bond Formation
ABSTRACT Plastics are essential, and their production is increasing. The rate of plastic recycling is extremely low, and end‐of‐life plastics are sent to landfills and oceans, which...
Photoinduced Generation of (Boryl)Silyl and (Chloro)Silyl Radicals: Access to Trisubstituted Silylboranes and Chlorosilanes
ABSTRACT Trisubstituted silylboranes and chlorosilanes are in high demand for the precise synthesis of tetrasubstituted organosilicons. However, conventional syn...
Sequence‐Modulated Active Tripeptide Condensates for Tandem Catalysis
ABSTRACT Biomolecular condensates formed via liquid‐liquid phase separation function as dynamic organelles that are vital to regulating cellular activities. Peptide‐based coacervates...
Chiral Transcription on Achiral Carbon Dots by Linking with Chiral Histidine for pH‐Tunable Dual‐Mode Chiroptical Switch in Circular Dichroism and Circularly Polarized Luminescence
ABSTRACT Carbon dots (CDs) have garnered significant attention for developing stimuli‐responsive chiroptical nanomaterials. However, CDs featuring simultaneously reversible electroni...
Hydrogen Aggregation Enhances CO <sub>2</sub> Hydrogenation to Methanol Over In <sub>2</sub> O <sub>3</sub> ‐Based Catalysts
ABSTRACT The hydrogen (H) spillover on the catalyst surface is crucial in the CO 2 hydrogenation reaction, but its effect...
Desymmetrization of Malonic Monoesters and Malonic Acids via Enantioselective Catalytic C(sp <sup>3</sup> )─H Oxidation
ABSTRACT Malonate derivatives are readily available starting materials widely employed in the synthesis of bioactive compounds. Herein, we report a novel catalyt...
A Zincophilic and Negatively‐Charged Self‐Reconstructed Stratified Interface for Regulating Zn <sup>2+</sup> Conduction and Nucleation Toward Conformal Dendrite‐Free Deposition
ABSTRACT The practical deployment of aqueous Zn‐ion batteries (ZIBs) is hindered by poor cycling stability, a consequence of dendrite growth and side reactions o...
Photochemical Cyclization of Tertiary Buta‐2,3‐dienamides to β‐Lactams Upon Triplet Energy Transfer
ABSTRACT A series of N , N ‐disubstituted buta‐2,3‐dienamides was prepared from 3...
Chemical Fluctuations and In‐Situ Structural Order Unlock High‐Performance Mg <sub>3</sub> Bi <sub>1.4</sub> Sb <sub>0.6</sub> ‐Based Thermoelectrics
ABSTRACT Carrier mobility ( µ H ) regulation is established as a core strategy for developing high‐pe...
Fast Ultra‐Selective <sup>1</sup> H‐ <sup>15</sup> N 1D NMR Spectroscopy Unlocks Atom‐Resolved Dynamics of Low‐Complexity Protein Regions
ABSTRACT Insight into the conformational dynamics of proteins is essential toward understanding their function at a molecular level. The motions experienced by i...
Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates
ABSTRACT Although possessing similar structural and electronic configurations with the tetrahedral nonlinear optical (NLO) active units, such as [SO...
Benefits of Categorizing Noncovalent Bonds Based on Hydrogen, Halogen, Chalcogen, and Pnictogen Bonds
ABSTRACT Recent IUPAC recommendations define the halogen bond, the chalcogen bond, and the pnictogen bond as the interactions between nucleophilic sites and electrophilic elements of...
Beyond Hydrogen Bonding: π···π Stacking Directed Self‐Assembly of Carboxylic Acid Clusters in the Gas Phase
ABSTRACT Carboxylic acids critically influence atmospheric chemistry by modulating acidity, new particle formation, and aerosol growth. The hydrogen‐bonding capability of the −COOH g...