Angewandte Chemie International Edition

Multilevel Artificial Intelligent Framework Accelerates Electrolytes Design for Aqueous Batteries

ABSTRACT The lack of clear guidance for designing novel aqueous electrolytes with wide electrochemical stability window (ESW) and strong resistance to hydrogen e...

Dual Metal‐Bridged 2D COF for High Performance of H ₂ O ₂ Photosynthesis Across Wide pH Range Activated by Dual Route Linkage

ABSTRACT Successfully converting water and oxygen into H 2 O 2 by covalent organi...

Joseph Derosa

Nickel‐Catalyzed Enantioconvergent Arylation of Unactivated Cyclic Electrophiles: Asymmetric Synthesis of 3‐Substituted Pyrrolidines

ABSTRACT The enantioconvergent substitution of unactivated alkyl electrophiles by carbon nucleophiles is a largely unsolved challenge in asymmetric catalysis, wi...

Creating Anionic Microenvironment Around Single‐Atom Fe Sites in Metal–Organic Frameworks for Enhanced Nitrate Electroreduction

ABSTRACT The electrocatalytic nitrate reduction reaction (eNO 3 RR) offers a sustainable strategy for both NO...

Mixed‐Functionalized Acylgermanes Result in Wavelength‐Controlled Fragmentation

ABSTRACT Control over the radicals that a Type I photoinitiator releases without changing the formulation offers a direct handle on polymer microstructure. To ad...

Intrinsically Spin‐Flip‐Induced Circularly Polarized Electroluminescence: A Strategy Spanning Deep Blue to Deep Red With Achiral MR and Perovskite Emitters

ABSTRACT Integrating circularly polarized electroluminescence (CPEL) into light‐emitting diodes (LEDs) is crucial for advanced optical applications. However, its...

pH‐Dependent Behavior of Ru‐Based Hydrogen‐Oxidation Electrocatalysis by a Reconstructed Hydrogen‐Bond Network

ABSTRACT Hydrogen oxidation reaction (HOR) exhibits a pH dependent behavior that the kinetics in acidic media are two to three orders of magnitude compared to th...

Tunable Synthesis of Porous Iron Powder From Fe‐Based MOFs via Shell‐Protection Strategy for Enhanced N ₂ Electroreduction

ABSTRACT The electrochemical nitrogen reduction reaction (NRR) offers a sustainable transformation of nitrogen (N 2 ) int...

Inside Back Cover: Giant Magnetostriction in Ferrimagnetic SmFe ₅ As ₃ (Angew. Chem. Int. Ed. 20/2026)

Outside Front Cover: Out‐of‐Equilibrium Supramolecular Assembly Sustained by Photocatalysis (Angew. Chem. Int. Ed. 20/2026)

Bent N‐Heterocyclic Allenes From a Well‐Defined Titanium Vinylidene Complex

ABSTRACT Allenes typically display a linear geometry. A notable exception occurs in allenes bearing two electron‐donating N‐heterocyclic capping groups, which ca...

Synergistic Orbital Hybridization and Steric Shielding for Stabilizing High‐Voltage Interfaces in 4.3 V Sodium‐Ion Batteries

ABSTRACT High‐voltage polyanionic cathodes, such as Na 3 V 3 (PO...

High‐Temperature Liquid‐Phase Phosphorescence of Carbon Dot‐Zinc Hydroxide Nitrate Coordination Networks

ABSTRACT Achieving persistent phosphorescence in liquid phases at elevated temperatures remains a formidable challenge, as thermally induced structural disruption and solvent‐assiste...

The Far Side of Carboranes: Anticancer Active Monocations and Ambiently Stable Dications

ABSTRACT Polyhedral carboranes are highly biologically stable, non‐toxic clusters. Whereas they are typically encountered in anionic or neutral forms, positively...

Benzaldehyde‐Tagged Cell‐Penetrating Peptides Enable Efficient Cytosolic Delivery of Bioactive Cargos via Dynamic Covalent Anchoring

ABSTRACT Cytosolic delivery of biomacromolecules constitutes an indispensable component in cell therapies, genome editing, and a diversity of fundamental research applications but re...

Neutral‐Condition Hydrogen Peroxide Electrosynthesis at Industrial‐Level Current Density Over Bipyridine‐Bridged Cobalt‐Based Conductive Metal‐Organic Frameworks

ABSTRACT Conductive metal‐organic frameworks (c‐MOFs) have been widely adopted for catalyzing two‐electron oxygen reduction reaction (2e −...

Lead‐Doping Enabled Band Engineering and Phonon Transport Modulation: Key to High‐Performance Thermoelectric AgSbTe ₂

ABSTRACT AgSbTe 2 is a promising mid‐temperature thermoelectric (TE) material but has instability and limited performance...

Out‐of‐Equilibrium Supramolecular Assembly Sustained by Photocatalysis

ABSTRACT Some supramolecular structures persist because they are stable; others persist because they work. Here, we report a platinum(II) supramolecular system i...

Coupling Electrochemical CO ₂ Reduction With Ethanol Oxidation for Acetate Production in a Dual‐Electrolyzer System

ABSTRACT Bioethanol production from biomass is suggested as a strategy for greener fuel production. However, an equimolar amount of CO 2...

Cathodic‐Potential‐Induced Amorphous TiO _x Layer for Glycerol Valorization

ABSTRACT Electrochemical oxidation offers a low‐carbon pathway for glycerol valorization, yet it remains constrained by the inherent trade‐off between activity a...

Aggregation‐State Dynamics Drive Double Cooperativity Between Antimicrobial Peptides LL‐37 and HNP1

ABSTRACT The double cooperative effect between two major antimicrobial peptides, LL‐37 and HNP1, where their combination enhances antimicrobial efficiency while reducing cytotoxicity...

Electron‐Deficient Amines Enable Halide‐Anchoring Hydrogen Bonding for Stable Wide‐Bandgap Perovskites Toward Perovskite/Organic Tandem Solar Cells

ABSTRACT Perovskite/organic tandem solar cells (TSCs) represent a compelling pathway toward high‐efficiency, solution‐processed photovoltaics; however, their per...

Charge Accumulation Engineering in Covalent Organic Frameworks for Enhancing Photocatalytic H ₂ O ₂ Production

ABSTRACT A charge accumulation strategy in multicomponent covalent organic frameworks (COFs) is developed to maximize photocatalytic H 2...

Constructing Face‐Shared Configuration at the Hetero‐Interface in Li‐Rich Layered Oxide Cathodes

ABSTRACT Lithium‐rich cathodes are promising candidates for next‐generation high‐energy‐density batteries owing to their high capacity and low cost. While the in...