Angewandte Chemie International Edition
Articles in this Issue
Giant Magnetostriction in Ferrimagnetic SmFe <sub>5</sub> As <sub>3</sub>
ABSTRACT Magnetostrictive materials are of interest not only from a fundamental perspective but also for their potential applications, spanning spintronics to en...
Fullerene Photosensitization Within a Self‐Assembled Hollow Pd (II) Architecture for Light‐Driven Oxidation Reactions in Water
ABSTRACT The efficient conversion of light into chemical energy in water is often hindered by the poor solubility and self‐aggregation of the photosensitizers, s...
Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity
ABSTRACT We highlight recent advances in nitration chemistry with emphasis on the development of sustainable and selective methodologies. A comprehensive overvie...
Precise Synthesis of Donor–Acceptor [17]Helicenes Exhibiting Circularly Polarized Emission
ABSTRACT Here we present a five‐step synthesis of two circular polarized light emitting donor–acceptor (D–A) [17]helicenes. The concise yet high‐yielding synthet...
Spin‐Polarized Chiral ZnIn <sub>2</sub> S <sub>4</sub> for Targeted Solar‐Driven CO <sub>2</sub> Reduction to Acetic Acid
ABSTRACT Acetic acid represents a pivotal target for CO 2 reduction due to its dual function as a carbon‐utilization prod...
Discovery of a Plant Pictet–Spenglerase With <i>R</i> ‐Stereoselectivity
ABSTRACT The class‐defining monoterpenoid indole alkaloid (MIA) scaffold strictosidine is generated by condensation of tryptamine and secologanin by the Pictet–S...
Biocatalytic Synthesis of Isoxazolines Enabled by Cryptic Nitrile Oxide Formation by a Vanadium‐Dependent Chloroperoxidase
ABSTRACT Isoxazolines are an important class of heterocycles with a broad range of biological activities. One of the most prevalent synthetic strategies to access isoxazolines is thr...
A Novel Acetylcholine Nanosensor for Single Vesicle Storage and Sub‐Quantal Exocytosis in Living Neurons and Organoids
Abstract Acetylcholine (ACh) is a critical neurotransmitter that regulates diverse physiological functions, such as cognition and muscle contraction, through syn...
Topology‐Dependent Coke Formation in the Catalytic Pyrolysis of Phenol Over HFAU and HZSM‐5 Zeolites
ABSTRACT Catalytic pyrolysis of lignin, the most abundant natural aromatic polymer, offers a route to obtain value‐added products with a low carbon footprint. In...
Correction to “High Spin Iron–Phosphinidene and Arsinidene Complexes With Attenuated Metal–Ligand Multiple Bond Character”
Multivalent Glycopolymer Design Unlocks Antimicrobial Activity of 2‐Deoxyglucose
ABSTRACT With the increasing prevalence of multidrug‐resistant (MDR) pathogens, last‐line therapeutics such as cyclic peptides are insufficient, underscoring the...
Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives
ABSTRACT Disentangling structure–property relationships and identifying high‐performance functional building units are essential for the rational design of ultra...
Diversifying Single‐Crystal Structures of Covalent Organic Polymers Through a Symmetry‐Broken Strategy
ABSTRACT Recently, growing single crystals of covalent organic polymers (COPs) through dative B←N bonds has been proven to be a promising strategy. Despite these...
A 12‐Crossing Vertex‐Fused Double‐Triangle [5]Catenane with Programmed Topological Handedness
ABSTRACT High‐crossing mechanically interlocked molecules are attractive because their dense entanglement can encode unusual stereochemistry, but predictable han...
Integrating Hydrogen Dissociation and Spillover Sites Into Platinum Confined SAPO‐34 Zeolite Unlocks Efficient CO <sub>2</sub> Hydrogenation to Light Alkanes
ABSTRACT The depressing of atmospheric CO 2 concentration necessitates sustainable chemical conversion strategies by dire...
Defects as Assets for Upcycling Spent Lithium‐Ion Battery Cathode Materials
ABSTRACT The rapid deployment of lithium‐ion batteries has intensified the accumulation of end‐of‐life cells, posing both environmental risks and resource challenges. Conventional re...
Alkyltransferase Ribozyme for Site‐Specific <i>N</i> <sup>4</sup> ‐Cytidine Alkylation
ABSTRACT Ribozymes for site‐specific RNA modification provide an elegant approach for the installation of diverse functional groups, fluorophores, affinity tags,...
Spin‐State Modulation of Atomic Iron Sites Enables Efficient CO <sub>2</sub> Electroreduction in Acid Medium
ABSTRACT Electrochemical carbon dioxide (CO 2 ) reduction (CO 2 RR) in acidic con...
Triple Long‐Range Charge‐Transfer Channels Enable Efficient LRCT/SRCT Hybridization in Narrowband Deep‐Blue TADF Emission
ABSTRACT To accelerate the reverse intersystem crossing (RISC) process of multi‐resonance thermally activated delayed fluorescence (MR‐TADF) emitters, constructi...
Synergistic Interface‐Bulk Regulation of Biopolymer Electrolytes for Advanced Zn‐Iodine Batteries With Four‐Electron I <sup>−</sup> /I <sup>0</sup> /I <sup>+</sup> Conversion
ABSTRACT Aqueous zinc||iodine batteries (AZIBs), which rely on the efficient I − /I 0...
MagNanoTrap Enrichment Empowers Ultra‐Sensitive Quantification of Mixed Nanoplastic Particles From Environmental Water Samples
ABSTRACT The detection and quantification of nanoplastic particles (NPs) in environmental waters are crucial for monitoring their fate and assessing health impac...
Ansamer‐Controlled Bicyclic Peptides as Integrin αvβ6 Targeting Agents
ABSTRACT Bicyclic peptides are promising candidates for peptide‐drug conjugates due to their structural rigidity and high target specificity. Recently, it became...
Visible‐Light Sensitized Isomerization in the Lipid Bilayer Enables Activation of a Transmembrane Transporter
ABSTRACT Currently, there is major interest in embedding light‐responsive (supra)molecular systems in phospholipid bilayer membranes, for example, to control transmembrane transport...
Reply to the Correspondence on “Carbon‐Dot‐Based Dual‐Emission Nanohybrid Produces a Ratiometric Fluorescent Sensor for in Vivo Imaging of Cellular Copper Ions”
ABSTRACT The Correspondence by Gharib et al. challenges our 2012 study on CQD‐based Cu 2+ sensors but introduces no new e...
Varying Carbene Persistence in Membrane as a Mechanism for Modulating Antibacterial Carbon Acid Oligomer Killing Efficacy
ABSTRACT We previously proposed that cationic oligoimidazolium (OIM) carbon acids kill bacteria via an N‐heterocyclic carbene (NHC)‐assisted translocation proces...