Angewandte Chemie International Edition
Articles in this Issue
Poly(heptazine imide): Crystalline Allotrope of Polymeric Carbon Nitrides for Solar to Chemical Energy Conversion
ABSTRACT Polymeric carbon nitride (PCN), an emerging semiconductor photocatalyst, has drawn intense interest for solar to chemical energy conversion, owing to advantages of metal‐fre...
Chemical Proteomics Identifies Ketogenesis‐Mediated Cysteine Modifications Regulating Redox Function
Abstract All the studies of ketogenesis‐dependent post‐translational modifications (PTMs), notably those mediated by ketone bodies, β‐hydroxybutyrate (Bhb) and acetoacetate (Acac), h...
Facet‐Selective Nucleation Control for Constructing Multi‐Dimensional MOFs Heterostructures
Abstract Metal–organic framework (MOF) heterostructures featuring tunable morphologies and compositions have shown great promise for applications in high‐throughput sensing, anti‐cou...
Correction to “Magnetic and Peroxidase‐Specific Single‐Atom Nanozyme Through Cu‐Doping Engineering for Ultrasensitive and Visual Tumor Diagnosis”
Covalent Functionalization Strategies for Tailoring the Outer‐Sphere Microenvironments of Single‐Atom Catalysts Supported on Carbon Materials
ABSTRACT The design of single‐atom catalysts (SACs) with high activity, selectivity, and stability relies on careful modulation of the active sites. The active‐site structures of nat...
A Cooperative Structural Dimension and Clusters Chirality in Antimony Halide Hybrids for Efficient Circularly Polarized Electroluminescence
ABSTRACT Chiral metal–halide materials often suffer from inherent trade‐off between photoluminescence efficiency and chiroptical asymmetry (...
Synthesis, Crystal Structure, and Enantiomeric Resolution of a Chiral (18,15) Carbon Nanobelt
ABSTRACT Chiral carbon nanotubes (CNTs) show significant potential for applications in electronics and optics, yet the selective synthesis of single‐chirality CN...
Rapid Assignment of Chemical Shifts From Crystal Structures in Solid‐State NMR
ABSTRACT Chemical shift assignment in solid‐state nuclear magnetic resonance (NMR) is a challenging process that usually relies on a set of 1D and 2D experiments...
Singlet Exciton Drives Intracellular Photoredox Catalysis for Pyroptosis in Cancer Cells
ABSTRACT Hypoxia continues to pose a significant challenge in photodynamic therapy (PDT) due to the reliance of conventional photosensitizers on oxygen‐dependent...
Suppression of NO <sub>2</sub> Generation During One‐Step Deep Oxidation of NO at a Semi‐Artificial Photoenzyme Based on Cytochrome <i>c</i>
ABSTRACT Solar‐driven catalysis holds promise in molecular oxygen activation and low‐concentration NO x elimination but a...
Aminal‐linked Covalent Organic Frameworks for Light Energy Upconversion
ABSTRACT The conversion of two low‐energy photons into a single higher‐energy photon at low irradiance is highly desirable for bioimaging and solar energy harves...
Elucidating the Stereodirecting Effect of C‐4 Acyl Groups on Galactosyl Donors
ABSTRACT The stereoselective synthesis of 1,2‐ cis glycosidic bonds is a significant challenge in carbohydrate chemistry....
A Chalcogen Bonding Catalysis Platform for Isoprenoid Cyclization: Broad Scope and Diverse Product Frameworks
ABSTRACT Cyclization of isoprenoids is one of the most important biosynthetic events that yields the largest class of natural products. Yet, a noncovalent catalysis strategy for isop...
Mechanical Peeling of Anthracene Dimers
ABSTRACT In polymer mechanochemistry, mechanophores are activated by the pulling action of polymer arms. This activation can be achieved from various pulling geo...
Isolable Monocyclic <i>N</i> ‐Heterocyclic Radicals Supported by Rare‐Earth Organometallics
ABSTRACT Monocyclic N ‐heterocyclic radicals are the elementary reactive intermediates in synthetic chemistry and biochem...
Residue‐Specific Signatures of Structural Water Identified by Dissolution Dynamic Nuclear Polarization with UV‐Generated Radicals
ABSTRACT Conserved structural water molecules stabilize protein folds and modulate their function, yet remain difficult to observe in solution because exchange‐based readouts favor s...
Hydrophilic Janus Micelles From an ABC Triblock Copolymer
ABSTRACT We describe the creation of an amphiphilic triblock copolymer that drives lateral phase separation within micelle coronas. The design combines a hydroph...
Solvation‐Mediated Assembly for Large‐Scale Synthesis of Covalent Organic Framework Membranes
ABSTRACT Covalent organic framework (COF) membranes featuring rigid frameworks and ordered channels have surmounted the dilemma of ion permeability and selectivi...
Industrial‐scale Aldehydes Electrification Via Localized Hydrogen‐affinity Engineering
ABSTRACT Electrifying aldehydes into high‐value chemicals presents a sustainable solution for environmental remediation, resource recovery and upgrade, yet its p...
Uniform and Stable Dual Frustrated Lewis Pairs Enabling Highly Efficient Conversion of CO <sub>2</sub> With Hydrogen‐rich Molecules
ABSTRACT Catalytic reduction of CO 2 with hydrogen‐rich small molecules (e.g., H 2...
Photoinduced Dynamic Electronic Asymmetry of Cu Dual‐Atom Sites Within Covalent Organic Frameworks Boosts Hydrogen Production
ABSTRACT The development of efficient and cost‐effective alternatives to noble metal cocatalysts for photocatalytic hydrogen evolution remains a significant chal...
Achieving Stable and Fast Ion Transport in Regenerated LiFePO <sub>4</sub> Via Vacancy‐Mediated Upcycling
ABSTRACT The high stability and low cost of LiFePO 4 batteries have fueled their rapid expansion, resulting in a growing...
Single‐Nanoparticle Collision Revealing High‐Entropy Suppression of Elemental Segregation in Multi‐Element Alloys During Oxygen Evolution Reaction
ABSTRACT In the oxygen evolution reaction (OER), the structural reconstruction and elemental segregation of alloy catalysts are key factors influencing their activity and stability,...
A Stable, Mesoporous Three‐Dimensional Covalent Organic Framework as a Versatile Functional Platform
ABSTRACT Introducing functionality into the pore channels of covalent organic frameworks (COFs) without compromising their crystallinity and porosity remains a f...
Self‐Assembled Ionic Clusters Accelerate Li‐Ion Transport Through Microphase‐Separated Polyelectrolytes
ABSTRACT Precise, molecular‐level control of ion coordination and mesoscale morphology is essential for pushing solid polymer electrolytes toward the conductivit...