Angewandte Chemie International Edition
Articles in this Issue
Spontaneous, Catalyst‐Free Co‐Polymerization of Ionic Liquids With CO <sub>2</sub> Toward Polycarbonate
ABSTRACT The conversion of carbon dioxide (CO 2 ) into value‐added polymer is a cornerstone of sustainable chemistry, yet...
Metallaphotoredox‐Catalyzed Acceptorless Dehydrogenative Carbonylation Employing Benzylic C─H Bonds as Limiting Substrates
ABSTRACT We report a visible light‐driven, metallaphotoredox‐catalyzed acceptorless dehydrogenative carbonylation of benzylic C─H bonds with carbon monoxide and...
Wrinkled Strain‐Enriched High‐Entropy Metallene Enables Cross‐Site Tandem Nitrate‐to‐Ammonia
ABSTRACT High‐entropy alloys (HEAs) are interesting for sustainable electrocatalytic nitrate‐to‐ammonia but suffer from low atom utilization and insufficient exp...
Supramolecular Modulation of Photoinduced Charge Transfer: Tuning Between Tunneling and Incoherent Hopping
ABSTRACT Photoinduced charge transfer (CT) underpins photosynthesis and solar energy conversion technologies. However, achieving comprehensive control over CT in...
Outside Back Cover: Unlocking Efficient Spontaneous Deracemization: A MOF‐Mediated Heterogeneous System Overcomes Catalytic Incompatibility in Cocrystallization (Angew. Chem. Int. Ed. 27/2026)
Alkane as Hydrogen Source: Pd/Photoredox Dual‐Catalysis Enables Mild Olefin Hydrogenation
ABSTRACT The development of safe and economical catalytic hydrogenation is a persistent challenge. The direct use of abundant alkanes as hydrogen donors under mi...
A Unified Radical C–SuFEx Platform via Catalytic EDA Complex‐Mediated S(VI)─F Bond Activation
ABSTRACT Sulfur(VI) Fluoride Exchange (SuFEx) chemistry has emerged as a powerful tool for forging diverse molecular architectures. While sulfur(VI) fluorides ar...
Local Electronic Modulation in Pillararene‐Based Donor–Acceptor Conjugated Polymers for Selective Photocatalytic Oxygen Reduction
ABSTRACT Constructing donor–acceptor (D–A) architectures is a widely adopted strategy for modulating the global band structures of photocatalytic polymers. Howev...
Inside Front Cover: Specific Ion Effects of Chaotropic and Superchaotropic Anions Probed by Raman Hydration‐Shell Spectroscopy (Angew. Chem. Int. Ed. 27/2026)
Unlocking Surface Sodiation Threshold of Titanium Dioxide via Coupled Electrochemical‐Thermal Activation
ABSTRACT Titanium dioxide anodes for sodium‐ion batteries undergo an electrochemically‐induced phase transformation from crystalline to active amorphous phase in...
Fully Planarized Donor Enables Record‐High Efficiency for Blue Through‐Space Charge Transfer Emission
ABSTRACT Through‐space charge transfer (TSCT) emitters featuring spatially separated donor‐acceptor architecture offer a promising strategy for designing thermal...
Direct Seawater Hydrogen Evolution via Atomically Precise Regulation of Interfacial pH and Ion‐Water Interactions
ABSTRACT Direct seawater electrolysis offers a sustainable route to green hydrogen production from abundant saline water resources, yet industrial applications a...
SPECTRAL: An Intelligent and Ultra‐Sensitive Photonic Hydrogel Platform for Biomarker‐Based Cancer Prediction
ABSTRACT Point‐of‐care (POC) biosensing holds great promise for noninvasive cancer diagnostics, as circulating tumor DNA (ctDNA) serves as a minimally invasive biomarker for early de...
Compatible Dynamically Wetting Electrolyte–Electrode Interface Design for Solid‐State Lithium–Sulfur Batteries
ABSTRACT Solid‐state lithium–sulfur batteries feature high energy density and stability, but their practical application is constrained by limited ion transport...
Regulating π–π Stacking Interactions to Boost Near‐Infrared Light‐Driven CO <sub>2</sub> Reduction
ABSTRACT Developing highly efficient photocatalysts to achieve near‐infrared (NIR) light‐driven CO 2 reduction is of grea...
Correction to “Thermally‐Stable Single‐Site Pd on CeO <sub>2</sub> Catalyst for Selective Amination of Phenols to Aromatic Amines Without External Hydrogen”
A Deep‐Red‐Absorbing Osmium(II) Complex as a Photosensitizer for Photodynamic Therapy Inducing Immunogenic Cell Death
ABSTRACT Immunogenic cell death (ICD), which converts tumor cells into their own vaccine, plays a pivotal role in the development of novel anticancer therapies....
Ultrahigh‐Efficiency and Long‐Calendar‐Life Aqueous Cadmium Metal Batteries Under Extremely Harsh Conditions
ABSTRACT Aqueous multivalent metal batteries (AMMBs) hold great promise for non‐flammable, cost‐effective, and scalable energy storage. However, the parasitic hy...
Beyond Hyperfluorescence: Leveraging a Host‐Guest Exciplex to Significantly Suppress the Efficiency Roll‐Off and Improve the Operational Stability in Narrowband Emissive Devices
ABSTRACT Narrowband emissive devices using multiple resonance (MR) thermally activated delayed fluorescence (TADF) emitters show strong efficiency roll‐offs and...
Poisoning‐Resistant Complete Hydrogenation of Liquid Organic Hydrogen Carriers Over Ni‐Based Inverse Catalysts
ABSTRACT Efficient hydrogen storage using liquid organic hydrogen carriers (LOHCs) requires catalysts that combine high low‐temperature activity with robustness...
Asymmetric α‐Alkylation With Activated and Unactivated Electrophiles by a Highly Productive and Recyclable Lewis Acid/Imidazolium Catalyst
ABSTRACT Asymmetric alkylation is widely used for the construction of α‐stereogenic carbonyl compounds, yet existing catalytic protocols typically suffer from se...
Electron‐Localized RuNi Nanosheet Assemblies Enable Low‐Overpotential Mg‐CO <sub>2</sub> Battery
ABSTRACT Mg‐CO 2 battery is emerging as a promising energy storage system that simultaneously converts CO...
Proteolysis‐Assisted Cyclization Facilitates Site‐Centric Target Deconvolution of Isothiocyanates
ABSTRACT Isothiocyanates (ITCs) are a unique class of electrophilic natural products that exert biological effects by reacting with proteinous cysteines to generate thionoacyl adduct...
Threading an Aluminum Molecular Ring Onto a Chemically Growing Copper‐Directed Polyrotaxane
ABSTRACT Controlled assembly of advanced mechanically interlocked architectures remains a major challenge in supramolecular chemistry. Inspired by the hard and soft acids and bases p...
Highly Selective On‐Surface Synthesis of sp <sup>2</sup> /sp‐Hybridized Heterochiral Triangular Nanorings
ABSTRACT A central challenge in on‐surface synthesis of topologically unique carbon nanostructures lies in the precise and selective construction of triangular n...