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Metal Doping Activation of Anion-Mediated Electron Transfer in Catalytic Reactions

Journal of the American Chemical Society Chao Yue Zhang, Jing Yu, Chen Huang et al. Feb 26, 2025 DOI: 10.1021/jacs.4c18236

MEMS vibrometer: Dynamic modeling of multimodal inertial transducers

Scientific Reports Jan Niklas Haus, Zhengchun Zhu, Thomas Roloff et al. Feb 26, 2025 DOI: 10.1038/s41598-025-90976-3

Abstract Guided ultrasonic wave-based structural health monitoring utilizes propagating elastic waves to identify, locate, and characterize damage within aviation structures. Fiber metal laminates, which are composite materials made by layering metal sheets with fiber-reinforced polymers, combine the high strength of composites with the ductility and impact resistance of metals. However, structural health monitoring methods suitable for these materials have to be developed, allowing to monitor also the inner laminate layers. Therefore, laminate-embedded MEMS vibrometers have been introduced recently. Due to the quasi-free operation of these inertial sensors, they are directly sensitive to the displacement induced by propagating guided ultrasonic waves. However, the multimodal excitation of the sensor’s core resonator, when exposed to ultrasound bursts, leads to a pseudo-nonlinear sensor response, which is attributed to the spectrum of guided ultrasonic waves and their interference with higher harmonics of the continuum resonator. The transfer behavior of the sensor can be improved by implementing electrical mode suppression. This research involves analytically modeling the continuous resonator with multiple aggregated resonators, numerically simulating sensor responses to 100 kHz ultrasound bursts, and using a laser scanning micro vibrometer setup for experimental validation, providing a deeper understanding of MEMS vibrometer dynamics for ultrasonic monitoring and demonstrating their applicability.

Biosynthesis of Dothideomins Reveals a Fungal P450 That Constructs the Tricyclo[5.2.2.0.<sup>4,8</sup>]undecane-Imbedded Core Skeleton

Journal of the American Chemical Society Falei Zhang, Chuanteng Ma, Meilin Zhu et al. Feb 26, 2025 DOI: 10.1021/jacs.4c18595

Author Correction: Naja sputatrix Venom Preconditioning Attenuates Neuroinflammation in a Rat Model of Surgical Brain Injury via PLA2/5-LOX/LTB4 Cascade Activation

Scientific Reports Yuechun Wang, Prativa Sherchan, Lei Huang et al. Feb 26, 2025 DOI: 10.1038/s41598-025-88937-x

Machine Learning-Based SERS Chemical Space for Two-Way Prediction of Structures and Spectra of Untrained Molecules

Journal of the American Chemical Society Jaslyn Ru Ting Chen, Emily Xi Tan, Jingxiang Tang et al. Feb 26, 2025 DOI: 10.1021/jacs.4c15804

Investigation of spinopelvic sagittal alignment and its correlations in asymptomatic pediatric populations

Scientific Reports Hao Qi, ZengHui Zhao, Feiyu Zu et al. Feb 26, 2025 DOI: 10.1038/s41598-025-91481-3

Rational Design of Aqueous Na Ion Batteries Toward High Energy Density and Long Cycle Life

Journal of the American Chemical Society Chunliu Xu, Yuan Liu, Shuai Han et al. Feb 26, 2025 DOI: 10.1021/jacs.4c18168

The development of media truth discernment and fake news detection is related to the development of reasoning during adolescence

Scientific Reports Marine Lemaire, Steeven Ye, Lorna Le Stanc et al. Feb 26, 2025 DOI: 10.1038/s41598-025-90427-z

Abstract The spread of online fake news is emerging as a major threat to human society and democracy. Previous studies have investigated media truth discernment among adults but not among adolescents. Adolescents might face a greater risk of believing fake news, particularly fake news that is shared via social media, because of their vulnerabilities in terms of reasoning. In the present study, we investigated (1) the development of media truth discernment and the illusory truth effect from adolescence to adulthood and (2) whether the development of media truth discernment and the illusory truth effect are related to the development of reasoning ability. To accomplish this task, we recruited 432 adolescents aged 11 to 14 years as well as 132 adults. Participants were asked to rate the perceived accuracy of both real and fake news headlines. Participants were exposed to half of the news items before entering the rating phase. Finally, participants completed the Cognitive Reflection Test (CRT). Media truth discernment (i.e., the difference between participants’ ratings of fake and real news) developed linearly with increasing age, and participants rated familiarized headlines as more accurate than novel headlines at all ages (i.e., the illusory truth effect). Finally, media truth development (but not the illusory truth effect) was related to the development of reasoning abilities with increasing age. Our findings highlight the urgent need to improve logical thinking among adolescents to help them detect fake news online.

Growth of Atomically Thin Metastable β-Tungsten in Single-Walled Carbon Nanotubes for Stable One-Dimensional Ferromagnets

Journal of the American Chemical Society Xin Zhao, Kun Wang, Bowen Li et al. Feb 26, 2025 DOI: 10.1021/jacs.4c18128

Concept of a demand-response model for smart community construction: a case study in Ningbo, China

Scientific Reports Chong Gao, Xiaolong Zhao Feb 26, 2025 DOI: 10.1038/s41598-025-91241-3

Strong Electron-Withdrawing Effect Activates Metal-Free Carboxylate Anion into Efficient Active Sites for Electrocatalytic Acetylene Semihydrogenation

Journal of the American Chemical Society Rui Bai, Zhi-Hao Zhao, Mingxuan Liu et al. Feb 26, 2025 DOI: 10.1021/jacs.4c17260

Diagnostic limitations in advanced stage peripheral arterial disease in a cadaveric study comparing photon-counting and energy-integrating CT detectors

Scientific Reports Viktor Hartung, Henner Huflage, Anne Marie Augustin et al. Feb 26, 2025 DOI: 10.1038/s41598-025-91239-x

Abstract To evaluate the limits of 1st-generation dual-source photon-counting detector CT (PCD-CT) and 3rd-generation dual-source energy-integrating-detector (EID-CT) regarding imaging of advanced stage peripheral arterial disease (ASPAD) of the femoral runoff. One human cadaver with ASPAD of the superficial femoral arteries was surgically prepared to establish continuous extracorporeal perfusion of the right upper leg. In addition to one stent already in place, three more stents were deployed in positions with severe calcification and stenosis to create thirteen different scenarios of ASPAD. CT angiographies with different radiation dose (CTDIvol 10, 5, 3 mGy) and matching convolution kernels were performed with PCD-CT and EID-CT. In-stent lumen visibility, signal-to-noise ratio (SNR), and luminal attenuation were assessed quantitatively. Results were compared using analyses of variance with a PCD-CT maximum dose and resolution scan (96 mGy, BV89) serving as standard of reference. Highest and lowest stent lumen visibility was observed with PCD-CT BV76 (97 ± 2%) and EID BV40 (77 ± 5%), respectively. Severe stent underexpansion in conjunction with heavy calcification resulted in the worst lumen visibility. PCD-CT displayed superior dose efficiency, yielding comparable SNR at 3 mGy to EID-CT at 10 mGy (p = 0.27). Luminal attenuation was higher for PCD-CT regardless of dose and reconstruction settings (max. 369 ± 19 HU, BV76, 5 mGy vs. 329 ± 12 HU for EID, BV59, 5 mGy; p &lt; 0.001). PCD-CT realises substantially higher image quality than EID-CT, thereby enhancing assessment of the femoral vasculature in ASPAD. Furthermore, this indicates substantial radiation dose and contrast agent volume saving potential. Both scanners show limitations in very low luminal diameters.

Hydrophobized Metal–Organic Frameworks as Versatile Building Blocks for Tailored Nanocrystal Superlattices

Journal of the American Chemical Society Xuesong Wu, Yutong Gao, Hao Wang et al. Feb 26, 2025 DOI: 10.1021/jacs.4c17724

Optimizing the utilization of Metakaolin in pre-cured geopolymer concrete using ensemble and symbolic regressions

Scientific Reports Kennedy C. Onyelowe, Viroon Kamchoom, Ahmed M. Ebid et al. Feb 26, 2025 DOI: 10.1038/s41598-025-91049-1

Classification and Identification of Facet- and Edge-Specific γ-Al <sub>2</sub> O <sub>3</sub> Surface Sites from <sup>1</sup> H/ <sup>27</sup> Al NMR Cross-Signatures and DFT Modeling

Journal of the American Chemical Society Domenico Gioffrè, Pierre Florian, Thomas Pigeon et al. Feb 26, 2025 DOI: 10.1021/jacs.4c17358

Single cell analysis identifies distinct CD4 + T cells associated with the pathobiology of pediatric obesity related asthma

Scientific Reports David A. Thompson, Yvonne B. Wabara, Sarai Duran et al. Feb 26, 2025 DOI: 10.1038/s41598-025-88423-4

Mechanical Interlocking of 144 Symmetrical <sup>19</sup>F and Tetraphenylethylene for Magnetic Resonance-Fluorescence Dual Imaging

Journal of the American Chemical Society Lan Yang, Fang Wang, Yu Li et al. Feb 26, 2025 DOI: 10.1021/jacs.5c00429

Author Correction: DNA barcoding of invasive Gambusia holbrooki Girard, 1859 and Atherina boyeri Risso, 1810 inhabiting Upper Euphrates River Basin, Türkiye

Scientific Reports Mücahit Eroğlu, Işılay Çelik, Mustafa Düşükcan et al. Feb 26, 2025 DOI: 10.1038/s41598-025-91131-8

Water-Intercalated and Humidity-Responsive Lamellar Materials by Self-Assembly of Sodium Acrylate Random Copolymers

Journal of the American Chemical Society Yuki Horiike, Hiroyuki Aoki, Makoto Ouchi et al. Feb 26, 2025 DOI: 10.1021/jacs.4c16219

Author Correction: Tennis expert-novice difference in motion-in-depth perception is associated with early inhibition of invalid attention

Scientific Reports Xiaona Wei, Congyi Wang, Yirui Song et al. Feb 26, 2025 DOI: 10.1038/s41598-025-91182-x