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Controlling Interlayer Disorder Toward Reversible Phase Transition in a Layered Sodium Manganese Oxide Cathode

Journal of the American Chemical Society Seongkoo Kang, Jihyun Kim, Youngju Choi et al. Feb 26, 2025 DOI: 10.1021/jacs.4c15913

Engineering the Lewis Acidity of Fe Single-Atom Sites via Atomic-Level Tuning of Spatial Coordination Configuration for Enhanced Oxygen Reduction

Journal of the American Chemical Society Qingyun Qu, Yu Mao, Shufang Ji et al. Feb 26, 2025 DOI: 10.1021/jacs.4c17444

Enhancing Selective Hydrofluorocarbon Greenhouse Gas Capture via Halogenation of Metal–Organic Frameworks

Journal of the American Chemical Society Ronald T. Jerozal, Jaehwan Kim, Carolyn Ma et al. Feb 26, 2025 DOI: 10.1021/jacs.5c00393

Self-Assembled Subwavelength Nanophotonic Structures for Spatial Object Localization and Tracking

Journal of the American Chemical Society Jianpeng Ma, Ziguang Zhao, Yingjie Zhao et al. Feb 26, 2025 DOI: 10.1021/jacs.4c14899

The Role of Interfaces and Charge for Chemical Reactivity in Microdroplets

Journal of the American Chemical Society R. Allen LaCour, Joseph P. Heindel, Ruoqi Zhao et al. Feb 26, 2025 DOI: 10.1021/jacs.4c15493

Chemical Synthesis Reveals Pathogenic Role of <i>N</i>-Glycosylation in Microtubule-Associated Protein Tau

Journal of the American Chemical Society Wyatt C. Powell, Ruiheng Jing, Morgane Herlory et al. Feb 26, 2025 DOI: 10.1021/jacs.4c17873

Optimization, application effects and improved microecology of a composite microbial agent containing oyster shells

Scientific Reports Ya-Ting Yang, Xin-Peng Li, Li-Cheng Gao et al. Feb 26, 2025 DOI: 10.1038/s41598-025-91165-y

Three-Coordinate Iron(0) Complex-Catalyzed Regioselective C–H Alkylation of Indole Derivatives

Journal of the American Chemical Society Zi-Jing Zhang, Stéphane Golling, Silvia Cattani et al. Feb 26, 2025 DOI: 10.1021/jacs.4c17316

The effect of cysteine oxidation on conformational changes of SARS-CoV-2 spike protein using atomistic simulations

Scientific Reports Maryam Ghasemitarei, Hoda Taeb, Tayebeh Ghorbi et al. Feb 26, 2025 DOI: 10.1038/s41598-025-90918-z

Recombination of Autodissociated Water Ions in a Nanoscale Pure Water Droplet

Journal of the American Chemical Society Soonho Kwon, Prabhat Prakash, Yixiang Cao et al. Feb 26, 2025 DOI: 10.1021/jacs.4c15103

Early detection of feline chronic kidney disease via 3-hydroxykynurenine and machine learning

Scientific Reports Ellen Vanden Broecke, Laurens Van Mulders, Ellen De Paepe et al. Feb 26, 2025 DOI: 10.1038/s41598-025-90019-x

Enabling Thermally Stimulated Delayed Phosphorescence in Cu(I) Cyclic Trinuclear Complexes with Near-Unity Quantum Yield

Journal of the American Chemical Society Guo-Quan Huang, Ri-Qin Xia, Xu Chen et al. Feb 26, 2025 DOI: 10.1021/jacs.4c09907

Study on energy-autonomous technology for energy consumption performance and climate adaptation in independent public toilets based on DesignBuilder simulation

Scientific Reports Dapeng Bi, Zhonghua Zhao, Qunwu Huang et al. Feb 26, 2025 DOI: 10.1038/s41598-025-91215-5

If your heart stops, this smartwatch-AI can call for help

Nature Benjamin Thompson, Nick Petrić Howe Feb 26, 2025 DOI: 10.1038/d41586-025-00601-6

Copper-Catalyzed Selective Amino-alkoxycarbonylation of Unactivated Alkenes with CO

Journal of the American Chemical Society Si-Shun Yan, Ralf Jackstell, Matthias Beller Feb 26, 2025 DOI: 10.1021/jacs.4c13723

Acute effects of footwear and surface condition on sport specific performance in athletes

Scientific Reports Stanislav Dimitri Siegel, Mareike Sproll, Astrid Zech Feb 26, 2025 DOI: 10.1038/s41598-025-91515-w

Abstract This study examined the acute effects of minimalist shoes, standard sport shoes, and barefoot conditions on sports-specific performance in forty-eight team and racket sport athletes across three testing sessions. Biomechanical laboratory assessments included 90° cutting maneuvers (90°COD) and jump tests. Linear (LS) and multidirectional sprint (MS) performances were evaluated in a second session on an indoor sports floor. In the third session, LS and MS performance were tested exclusively in minimalist shoes on tartan and artificial turf. Performance was quantified as test completion time and jump height. Significant footwear effects were observed for 90°COD, MS, and LS, with minimalist shoes and barefoot conditions reducing performance by up to 9% compared to standard sport shoes. Jumping performance was unaffected by footwear. Surface conditions significantly influenced LS and MS, with tartan and artificial turf improving performance by up to 9% compared to indoor surfaces. Significant sex differences were observed in all tests except for 90°COD. These findings suggest that the effects of footwear are context-dependent and should not be generalized without considering specific surfaces, movements, and individual factors. Future research should investigate whether long-term habituation can alter these outcomes.

Polyelectrolyte Membrane Enables Highly Reversible Zinc Battery Chemistry via Immobilizing Anion and Stabilizing Water

Journal of the American Chemical Society Yubin He, Rui Zhang, Peichao Zou et al. Feb 26, 2025 DOI: 10.1021/jacs.4c12409

Ultralow Coordination Copper Sites Compartmentalized within Ordered Pores for Highly Efficient Electrosynthesis of <i>n</i>-Propanol from CO<sub>2</sub>

Journal of the American Chemical Society Qun Li, Jiabin Wu, Caoyu Yang et al. Feb 26, 2025 DOI: 10.1021/jacs.4c16129

Inhibition of autophagy in platelets as a therapeutic strategy preventing hypoxia induced thrombosis

Scientific Reports Propanna Bandyopadhyay, Yash T. Katakia, Sudeshna Mukherjee et al. Feb 26, 2025 DOI: 10.1038/s41598-025-91181-y

Abstract Hypoxia triggers activation of platelets, leading to thrombosis. If not addressed clinically, it can cause severe complications and fatal consequences. The current treatment regime for thrombosis is often palliative and include long-term administration of anticoagulants, causing over-bleeding risk and other secondary effects as well. This demands a molecular understanding of the process and exploration of an alternative therapeutic avenue. Interestingly, recent studies demonstrate that platelets exhibit functional autophagy. This cellular homeostatic process though well-studied in non-platelet cells, is under-explored in platelets. Herein, we report autophagy activation under physiologically relevant hypoxic condition (10% O2; associated with high altitude) in ex-vivo platelets and in vivo as well. We show that autophagy inhibition using chloroquine (CQ), a repurposed FDA-approved drug, can significantly reduce platelet activation, both in ex-vivo and in-vivo settings. Further, surgical ligation of inferior vena cava (IVC) was performed to induce thrombus formation. Interestingly, CQ pre-treated rats showed reduced clotting ability in surgical animals as well. Importantly, thrombosis inhibitory dose of CQ was considerably lower than the currently used drug-acetazolamide; CQ was also found to be non-toxic to the tissues. Hence, we propose that repurposing of CQ can attenuate hypoxia-induced thrombosis through inhibition of autophagy and can be explored as an effective therapeutic alternative.

Cyclic (Alkenyl)(Amino)Carbene (<sup><i>SMe</i></sup>CA<sub>en</sub>AC): Introducing a Member to the Cyclic (Alkyl)(Amino)Carbenes Family Featuring a Narrow Energy Gap

Journal of the American Chemical Society Chinmoy Majumder, Ankita Sharma, Bindusagar Das et al. Feb 26, 2025 DOI: 10.1021/jacs.4c17319