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Discover research articles across all indexed journals

Control on the Stacking Mode in a Sulfonic Covalent Organic Framework Enabling a Precise Uranyl-Identified Pocket for Ultrahigh-Capacity Uranium Extraction from Seawater

Journal of the American Chemical Society Liecheng Guo, Yuxuan Liu, Yuanzhe Jia et al. Aug 27, 2025 DOI: 10.1021/jacs.5c10932

Analysis of hybrid integer wavelet transform and singular value decomposition for image steganography under various noise conditions

Scientific Reports Manikandan Chinnusami, Dyutisri Kolli, S. Shreela et al. Aug 27, 2025 DOI: 10.1038/s41598-025-17020-2

sln-Topological Covalent Organic Frameworks with Shape Dimorphism and Dipolar Rotors

Journal of the American Chemical Society Xiaohan Wang, Syunto Goto, Takejiro Ogawa et al. Aug 27, 2025 DOI: 10.1021/jacs.5c10010

Proteomic analysis of differential responses to norflurazon herbicide in the model green alga Chlamydomonas reinhardtii

Scientific Reports Kantinan Leetanasaksakul, Thanaporn Intha, Sittiruk Roytrakul et al. Aug 27, 2025 DOI: 10.1038/s41598-025-17119-6

Abstract Norflurazon is a widely utilized pesticide in agriculture for weed management. The mechanism of action involves the inhibition of an initial step in carotenoid synthesis. This inhibition results in the instability of the photosynthetic machinery and subsequent cell bleaching. Microalgae have attracted significant interest for the production of valuable products. Nonetheless, the mass cultivation of microalgae continues to encounter many challenges that result in high production costs. A potential issue in photobioreactor and open pond cultivation is contamination by other microalgae, which can destroy the mass culture entirely. Strains exhibiting greater resistance to specific chemicals may be beneficial in reducing contamination from other algae. Furthermore, integrating microalgal production with phycoremediation constitutes a sustainable approach to the circular economy. Many norflurazon-resistant microalgae strains have been developed, including the model unicellular green microalga Chlamydomonas reinhardtii. In previous studies, mutant and transgenic strains resistant to high concentrations of norflurazon have been generated to study herbicide tolerance in Chlamydomonas reinhardtii. Nonetheless, the application of genetically engineered organisms should remain cautious. Moreover, mutant strains generated through conventional methods were created using very high chemical concentrations. The effects of introducing such strains on the composition of organisms in the environment remain a concern. This study investigated the feasibility of utilizing natural isolates of this alga for mass production in the presence of norflurazon. Twenty isolates of this alga were evaluated for tolerance to norflurazon. The two most tolerant isolates demonstrated the ability to withstand 5–10 µM of norflurazon, a concentration previously employed to select mutants and transformants resistant to norflurazon. Physiological and proteomic data revealed an enhancement of photosynthesis and photoprotection processes as the primary mechanism for norflurazon tolerance in one isolate, whereas another isolate demonstrated a reduction in protein synthesis, photosynthesis, and cell motility.

Local Symmetry Breaking and Hidden Spin Polarization in 2D Hybrid Perovskites with Nonprimary Ammonium Cations

Journal of the American Chemical Society Rayan Chakraborty, David B. Mitzi Aug 27, 2025 DOI: 10.1021/jacs.5c05250

Synthesis and characterization of bio-based eco-friendly biofilm composites reinforced with waste eggshell powder

Scientific Reports Asmare Tezera Admase, Tesfa Nega Gesese, Solomon Workneh Fanta et al. Aug 27, 2025 DOI: 10.1038/s41598-025-00398-4

Unexpected Generation of Singlet Oxygen at the Air–Water Interface of Aqueous Microdroplets

Journal of the American Chemical Society Feifei Li, Jitao Lv, Anen He et al. Aug 27, 2025 DOI: 10.1021/jacs.5c02431

Differential gene expression drives muscle metabolic and structural differences in Liang Guang small spotted vs. large white pigs

Scientific Reports Zheng Feng, Wen-Jing Wang, Nan Wang et al. Aug 27, 2025 DOI: 10.1038/s41598-025-17179-8

Solvation Free Energies of Anions: From Curated Reference Data to Predictive Models

Journal of the American Chemical Society Thomas Nevolianis, Jonathan W Zheng, Simon Müller et al. Aug 27, 2025 DOI: 10.1021/jacs.5c02578

Winding fault detection based on current information of induction motors

Scientific Reports Fei Liu, Chenggang Hou, Lin Liang et al. Aug 27, 2025 DOI: 10.1038/s41598-025-17368-5

Ir( <i>hkl</i> ) Surface Electrochemistry in a Nonadsorbing Acidic Medium

Journal of the American Chemical Society Kaline Nascimento da Silva, Kavyasree Anjanarambath, Caroline K. W. Lee et al. Aug 27, 2025 DOI: 10.1021/jacs.5c04909

Temporal metabolomic fingerprinting identifies adenine as a novel biomarker for early detection of Escherichia coli infection in broiler chickens

Scientific Reports Asha Ranaraja, Iresha Subhasinghe, Shaik Noor Ahmad et al. Aug 27, 2025 DOI: 10.1038/s41598-025-16873-x

Abstract Avian pathogenic Escherichia coli causes septicemia in broiler chickens leading to high mortality and economic losses. Current diagnostic methods, such as serology and culture, cannot detect infections during early asymptomatic stages. Hence, this study focused on identifying novel serum metabolic biomarkers and pathways as an early detection prediction tool. Ross broiler chicks were challenged with E. coli at 3 or 5 d of age, and blood samples collected at 8 and 24 h following infection. Serum samples were analyzed for metabolite alterations using targeted The Metabolomics Innovation Centre (TMIC) mega metabolomics assay. Data was processed through comprehensive statistical analyses, including univariate, multivariate, and meta-analysis approaches. At 8 h post-infection, top metabolites like adenine, N-acetyl-alanine, N-acetyl-soleucine, N-acetyl-valine, and orotic acid related to nucleotide and amino acid metabolisms were downregulated (p = &lt; 0.05). At 24 h, a distinct metabolic shift emerged with hippuric acid increasing, while adenine showed further depletion, accompanied by decreases in N1-acetylspermidine, N-acetylputrescine, and a modest increase in picolinic acid related to nucleotide, polyamine and immune response pathways (p = &lt; 0.05). Correlation metabolite networks show that at 8 h post-infection, broiler chicken showed enhanced metabolic coordination, while at 24 h, disruptions in polyamine, nucleoside, and fatty acid pathways reflected systemic rewiring. The progressive depletion of adenine at both 8 and 24 h post-infection supports it as a novel metabolite signature for E. coli infection.

Catalytic Markovnikov Hydrothiolation of Dehydroamino Acids: Unified Total Synthesis of Enteropeptin Sactipeptides

Journal of the American Chemical Society Yiwei Zhang, Shuvendu Saha, Yesen Cheng et al. Aug 27, 2025 DOI: 10.1021/jacs.5c03669

Predictive analysis of concrete tensile strength using metaheuristic algorithms helping a neural network

Scientific Reports Xun Dong Aug 27, 2025 DOI: 10.1038/s41598-025-13634-8

Direct Synthesis of Bicyclo[1.1.1]pentanes by Sequential C═C, C–C Functionalization Reactions

Journal of the American Chemical Society Joshua K. Sailer, Duc Ly, Djamaladdin G. Musaev et al. Aug 27, 2025 DOI: 10.1021/jacs.5c09039

Duplex digital PCR assay on microfluidic chamber arrays for total HIV DNA reservoir quantification in persons with HIV

Scientific Reports Lucía Gutiérrez-García, Andrés Esteban-Cantos, Javier Rodríguez-Centeno et al. Aug 27, 2025 DOI: 10.1038/s41598-025-17392-5

Heterolytic Cleavage of L<sub>n</sub>Pd–SiR<sub>3</sub><sup>+</sup> Bonds Enable the Ring-Opening C–C Functionalization of Nonstrained Ethers

Journal of the American Chemical Society Bradley A. Owen, Kevin Basemann, William A. Hearne et al. Aug 27, 2025 DOI: 10.1021/jacs.5c12528

Synthesis and computational investigation of novel 2-mercaptoimidazolones as dual antimicrobial and anti-proliferative agents with potential multitargeting kinase inhibitory activity

Scientific Reports Essam A. Ali, Aisha A. K. Al-Ashmawy, Manal M. Anwar et al. Aug 27, 2025 DOI: 10.1038/s41598-025-17260-2

Rewire

Nature Kathleen Schaefer Aug 27, 2025 DOI: 10.1038/d41586-025-02689-2

Correction: Digital mental health intervention for well-being among low-distress workers in small enterprises on a secondary analysis of an RCT

Scientific Reports Natsu Sasaki, Utako Sawada, Sayaka Ogawa et al. Aug 27, 2025 DOI: 10.1038/s41598-025-17306-5