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Why Do Weak-Binding M–N–C Single-Atom Catalysts Possess Anomalously High Oxygen Reduction Activity?

Journal of the American Chemical Society Di Zhang, Fangxin She, Jiaxiang Chen et al. Feb 19, 2025 DOI: 10.1021/jacs.4c16733

Mastitis-related Staphylococcus aureus-derived extracellular vesicles induce a pro-inflammatory response in bovine monocyte-derived macrophages

Scientific Reports Mara D. Saenz-de-Juano, Giulia Silvestrelli, Samuel Buri et al. Feb 19, 2025 DOI: 10.1038/s41598-025-90466-6

Abstract Staphylococcus aureus (S. aureus) is one of the most common causative agents of mammary gland infection and mastitis, but the specific role of S. aureus-derived extracellular vesicles (SaEVs) in mastitis has been poorly studied to date. Here, we aimed to investigate the response of bovine monocyte-derived macrophages (boMdM) to SaEVs of the genotype B (GTB) mastitis-related strain M5512B. Specifically, we evaluated the effects on the actin cytoskeleton, gene expression, and the SaEV proteomic cargo. Furthermore, we assessed to what extent the cellular and molecular response of boMdM to SaEVs differed from peripheral mononuclear blood cells (PBMCs) used for in vitro derivation of the former. We observed that SaEVs induced morphological changes in boMdM, leading to a pro-inflammatory and pyroptosis-related increased gene expression. Additionally, our study revealed that boMdM and PBMCs exhibited stimulus-specific differing responses. The proteomic analysis of SaEVs identified clusters of proteins related to virulence and antibiotic resistance, supporting the theory that S. aureus might use EVs to evade host defences and colonize the mammary gland. Our results bring new insights into how SaEVs might impact the host during an S. aureus infection, which can be useful for future S. aureus vaccine development.

In-Situ Thermometry Reveals Fragmentation Behavior Based on Local Temperature in α-Olefin Polymerization Catalysts

Journal of the American Chemical Society Joren M. Dorresteijn, Bas Terlingen, Koen W. Bossers et al. Feb 19, 2025 DOI: 10.1021/jacs.4c11357

Titania nanotubes with aminated reduced graphene oxide as efficient photocatalysts for antibacterial application under visible light

Scientific Reports Kyoung-Suk Moon, Ji-Myung Bae, Eun-Joo Choi et al. Feb 19, 2025 DOI: 10.1038/s41598-025-90270-2

Low-Temperature Exsolution of Rh from Mixed ZnFeRh Oxides toward Stable and Selective Catalysts in Liquid-Phase Hydroformylation

Journal of the American Chemical Society Daniel Delgado, Gregor Koch, Shan Jiang et al. Feb 19, 2025 DOI: 10.1021/jacs.4c14839

Numerical and machine learning based evaluation of ethylene glycol based hybrid nano-structured (TiO2-SWCNTs) fluid flow

Scientific Reports Hijaz Ahmad, Kamel Guedri, Sohail Ahmad et al. Feb 19, 2025 DOI: 10.1038/s41598-025-88789-5

Beyond the Vibrational Stark Effect: Unraveling the Large Redshifts of Alkyne C–H Bond in Solvation Environments

Journal of the American Chemical Society Chu Zheng, Yuezhi Mao, Thomas E. Markland et al. Feb 19, 2025 DOI: 10.1021/jacs.4c18102

Author Correction: Optimization of process parameters of catalytic pyrolysis using natural zeolite and synthetic zeolites on yield of plastic oil through response surface methodology

Scientific Reports Pitchaiah Sudalaimuthu, Usman Ali, Ravishankar Sathyamurthy Feb 19, 2025 DOI: 10.1038/s41598-025-88771-1

Bio-orthogonal Labeling of Chitin in Native Pathogenic Candida Species via the Chitin Scavenge Pathway

Journal of the American Chemical Society Caroline Williams, Bella R. Carnahan, Stephen N. Hyland et al. Feb 19, 2025 DOI: 10.1021/jacs.4c11554

Publisher Correction: Repurposing raltegravir for reducing inflammation and treating cancer: a bioinformatics analysis

Scientific Reports Zahra Nikfarjam, Reza Rakhshi, Farshid Zargari et al. Feb 19, 2025 DOI: 10.1038/s41598-025-90717-6

Three-Dimensional Covalent Organic Frameworks with lil Topology

Journal of the American Chemical Society Xinyu Wu, Hanwen Wang, Ning Huang Feb 19, 2025 DOI: 10.1021/jacs.4c16422

Information seeking and the expected utility of information about COVID-19 can be associated with uncertainty and related attitudes

Scientific Reports Nathan T. Torunsky, Kara Kedrick, Iris Vilares Feb 19, 2025 DOI: 10.1038/s41598-025-89781-9

Self-Assembled Monolayers of Triazolylidenes on Gold and Mixed Gold/Dielectric Substrates

Journal of the American Chemical Society Dana A.R. Nanan, Justin T. Lomax, Jordan Bentley et al. Feb 19, 2025 DOI: 10.1021/jacs.4c11125

Development of a new hybrid model to enhance streamflow estimation using artificial neural network and reptile search algorithm

Scientific Reports Mohammad Javad Bahmani, Zahra Kayhomayoon, Sami Ghordoyee Milan et al. Feb 19, 2025 DOI: 10.1038/s41598-025-90550-x

Abstract A new metaheuristic optimizer combined with artificial neural networks is proposed for streamflow prediction. Hence, the study aimed to forecast monthly streamflow of the main rivers in Urmia, Iran, by considering data shortage and using artificial neural network (ANN) models. By combining three variables: temperature, precipitation, and streamflow, we formulated five patterns, where 70% of the data were used for model training, and 30% for model testing. To improve the performance of ANN, we evaluated a new optimization algorithm, reptile search algorithm (RSA), and compared the results with combinations of ANN, particle swarm optimization algorithm (PSO), and whale optimization algorithm (WOA) models. The results of the ANN + RSA were promising at most stations and patterns. At Band station streamflow simulation testing gave RMSE, MAE, and NSE of 1.65, 1.21 MCM/month, and 0.80, respectively. At Babaroud station they were 4.01, 3.0 MCM/month and 0.68, respectively, at Nazlo station 5.62, 3.79 MCM/month, and 0.69, respectively, and at Tapik station 5.69, 3.82 MCM/month, and 0.59, respectively. However, the results of the ANN + PSO hybrid model were better than ANN + RSA. The impact of different parameters on the accuracy of streamflow prediction varied depending on model and streamflow station, indicating that the models do not perform consistently across different locations, times, and conditions. The inclusion of lagged monthly streamflow in the model was an influential input parameter. The results demonstrated that the new algorithm consistently improved predictions, enhancing the performance of traditional algorithms. The findings of this study highlight advantage of the ANN + RSA hybrid model for specific areas, suggesting its potential application in other similar hydrological problems for further validation.

A Holistic Data-Driven Approach to Synthesis Predictions of Colloidal Nanocrystal Shapes

Journal of the American Chemical Society Ludovic Zaza, Bojana Ranković, Philippe Schwaller et al. Feb 19, 2025 DOI: 10.1021/jacs.4c17283

Establishment of an experimental model of canine apocrine gland anal sac adenocarcinoma organoid culture using a three-dimensional culture method

Scientific Reports Yuko Nagashima, Haru Yamamoto, Mohamed Elbadawy et al. Feb 19, 2025 DOI: 10.1038/s41598-025-90623-x

Fluorination: Simple Change but Complex Impact on Ferroelectric Nematic and Smectic Liquid Crystal Phases

Journal of the American Chemical Society Grant J. Strachan, Ewa Górecka, Jordan Hobbs et al. Feb 19, 2025 DOI: 10.1021/jacs.4c16802

Semantic segmentation feature fusion network based on transformer

Scientific Reports Tianping Li, Zhaotong Cui, Hua Zhang Feb 19, 2025 DOI: 10.1038/s41598-025-90518-x

Reversible Angle Distortion-Dependent Electrochemical CO<sub>2</sub> Reduction on Cobalt Phthalocyanine

Journal of the American Chemical Society Bingbao Mei, Jianing Mao, Zhaofeng Liang et al. Feb 19, 2025 DOI: 10.1021/jacs.4c14409

Prediction criterion of the interaction between hydraulic fractures and bedding planes via theoretical and simulation approaches

Scientific Reports Xiaoxi Men, Yu Zhang, Di Zuo Feb 19, 2025 DOI: 10.1038/s41598-025-90422-4