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Constraining Interlayer Slipping in P2-Type Layered Oxides with Oxygen Redox by Constructing Strong Covalent Bonds

Journal of the American Chemical Society Xinyin Cai, Zulipiya Shadike, Nan Wang et al. Feb 19, 2025 DOI: 10.1021/jacs.4c14587

Publisher Correction: Annual migrations, vertical habitat use and fidelity of Atlantic bluefin tuna tracked from waters off the United Kingdom

Scientific Reports Thomas W. Horton, Francis C. T. Binney, Samantha Birch et al. Feb 19, 2025 DOI: 10.1038/s41598-025-90365-w

Mechanism of Hydrogen Generation Catalyzed by a Single Atom and Its Spin Regulation

Journal of the American Chemical Society Mingyao Li, Weilin Hu, Boyu Wang et al. Feb 19, 2025 DOI: 10.1021/jacs.4c17722

Sensor-assessed grasping time as a biomarker of functional impairment in rheumatoid arthritis

Scientific Reports Birte Coppers, Simon Heinrich, Koray Tascilar et al. Feb 19, 2025 DOI: 10.1038/s41598-025-90295-7

Abstract Quantifying physical impairment in rheumatoid arthritis (RA) is important to determine disease burden and disability. Therefore, we aimed to define hand function impairments in RA patients using an opto-electronic measurement system (OMS). In this cross-sectional pilot study, spatio-temporal and hand segment data were collected during the fine motor skill Moberg Picking-Up Test (MPUT) and two elementary hand movement tasks in RA patients and healthy controls (HC) using a marker-based OMS. The duration of two MPUT movement phases (grasping, transporting 12 objects) and kinematic characteristics during the elementary movements were evaluated. We analyzed between-group differences using linear mixed-effects models accounting for within-participant clustering of hands and adjusting for age and sex. Measurements were obtained from 24 RA and 23 HC. The mean duration of the grasping phase of MPUT was longer in RA patients compared to HC while transporting times were identical, showing a significant group-phase interaction (p < 0.001). Interphalangeal joint angle ratios were similar in RA and HC (p > 0.05) with a lower ratio in both groups for the task thumb-finger opposition compared to flexion of joints. In RA patients especially grasping objects was impaired, and performance time for a subset of objects may serve as a quantitative biomarker of functional impairment.

Spatiotemporal variation and dynamic simulation of carbon stock based on PLUS and InVEST models in the Li River Basin, China

Scientific Reports Yu Bai, Xiangling Tang, Feng Xue et al. Feb 19, 2025 DOI: 10.1038/s41598-025-86226-1

Enantioselective Synthesis of Chiral 1,4-Dihydroquinolines via Iridium-Catalyzed Asymmetric Partial Hydrogenation of Quinolines

Journal of the American Chemical Society Chang-Liang Zhu, Xueyuan Yan, Huai-Yu Bin et al. Feb 19, 2025 DOI: 10.1021/jacs.4c13618

Neuroprotective effect of NSCs-derived extracellular vesicles in Parkinson’s disease models

Scientific Reports Mercyleidi Díaz Reyes, Sabrina Gatti, Susana Delgado Ocaña et al. Feb 19, 2025 DOI: 10.1038/s41598-025-87238-7

Covalent Dynamic DNA Networks to Translate Multiple Inputs into Programmable Outputs

Journal of the American Chemical Society Simone Brannetti, Serena Gentile, Erica Del Grosso et al. Feb 19, 2025 DOI: 10.1021/jacs.4c13854

Author Correction: Involvement of 8-O-acetylharpagide for Ajuga taiwanensis mediated suppression of senescent phenotypes in human dermal fibroblasts

Scientific Reports Wei‑Hsiang Hsu, Bing‑Ze Lin, Jyh‑Der Leu et al. Feb 19, 2025 DOI: 10.1038/s41598-025-90257-z

Proline <i>cis</i>/<i>trans</i> Conformational Selection Controls 14–3–3 Binding

Journal of the American Chemical Society Frederik F. Theisen, Andreas Prestel, Nina L. Jacobsen et al. Feb 19, 2025 DOI: 10.1021/jacs.4c13462

Robust recursive estimation for the errors-in-variables nonlinear systems with impulsive noise

Scientific Reports Xuehai Wang, Fang Zhu Feb 19, 2025 DOI: 10.1038/s41598-025-89969-z

Anion-Guided Hierarchical Assembly of Heterometallic Clusters

Journal of the American Chemical Society Weiming Huang, Qingsong Yang, Wanmin Chen et al. Feb 19, 2025 DOI: 10.1021/jacs.4c16564

Genomic profiling of pediococcus acidilactici BCB1H and identification of its key features for Biotechnological innovation, food technology and medicine

Scientific Reports Tariq Aziz, Muhammad Naveed, Muhammad Aqib Shabbir et al. Feb 19, 2025 DOI: 10.1038/s41598-025-90633-9

Tailoring CO<sub>2</sub> Adsorption Configuration with Spatial Confinement Switches Electroreduction Product from Formate to Acetate

Journal of the American Chemical Society Huaqin Wang, Heyu Sui, Yalong Ding et al. Feb 19, 2025 DOI: 10.1021/jacs.4c17295

Underwater image enhancement via multiscale disentanglement strategy

Scientific Reports Jiaquan Yan, Hao Hu, Yijian Wang et al. Feb 19, 2025 DOI: 10.1038/s41598-025-89109-7

Sialylation Shields Glycoproteins from Oxidative Stress: Mechanistic Insights into Sialic Acid Oxidation and Structural Stability

Journal of the American Chemical Society Yamei Wang, Dongbei Jin, Lifang Ren et al. Feb 19, 2025 DOI: 10.1021/jacs.4c14454

A taguchi neural network–based optimization of a dual-port, dual-band MIMO antenna encompassing the 28/34 GHz millimeter wave regime

Scientific Reports Ajay Kumar Dwivedi, Vivek Singh, Yazeed AlZahrani et al. Feb 19, 2025 DOI: 10.1038/s41598-025-90103-2

Abstract This study presents a novel printed antenna design that operates at the millimeter-wave frequencies of 28 and 34 GHz, which are crucial for the current and upcoming mobile communication generations. The radiating component in the antenna is a slot-etched rectangular ring that is fed through a stepped impedance microstrip line feed. Using advanced machine learning techniques, the design parameters of the suggested antenna have been fine-tuned to ensure optimal impedance matching at 28 GHz within the frequency range of 27.61–28.49 GHz. Additionally, the antenna also provides excellent impedance matching at 34.5 GHz within the frequency range of 33.61–34.27 GHz. Using the designated antenna, a Multiple Input Multiple Output (MIMO) system with two ports is constructed. The MIMO system’s performance is evaluated by analyzing channel capacity loss (CCL), diversity gain (DG), and envelope correlation coefficient (ECC), which showcases outstanding outcomes. The study further explores the optimization of a antenna’s structure using a Taguchi-based Neural Network (Taguchi NN) approach to predict the reflection coefficient (|S11|) across a frequency range of 27–35 GHz. By systematically varying the gap width (∆w) and shift (∆t), a dataset was generated and used to train the network. The optimal model configuration achieved a validation Mean Square Error (MSE) of 2.244 and an R² of 0.848 enabling reliable prediction of the reflection coefficient (|S11|) without extensive simulations. The findings further highlight the construction and experimental assessment of a single-element antenna and MIMO system, which exhibit excellent impedance matching across both lower and higher frequency bands. The antenna displays a maximum gain of 8.75 and 5.5 dBi at frequencies of 28 and 34 GHz, respectively. The recommended antenna exhibits excellent radiation efficiency across both lower and higher frequency bands, with rates of 98.46% and 99.17%, respectively. In addition, the experimental measurements of the coupling coefficients between the MIMO antenna systems indicate extremely low coupling values. This results in an efficient MIMO system that is well-suited for future millimeter-wave (mm-wave) applications.

Accelerating Ion Desolvation via Bioinspired Ion Channel Design in Nonconcentrated Aqueous Electrolytes

Journal of the American Chemical Society Jiangbin Deng, Guanfeng Xue, Chen Li et al. Feb 19, 2025 DOI: 10.1021/jacs.4c15443

Validation of SSDE calculation in a modern CT scanner and correlation with effective dose

Scientific Reports Nicola Zancopè, Francesca De Monte, Erica Simeone et al. Feb 19, 2025 DOI: 10.1038/s41598-025-90509-y

Ligand-Governed Regio- and Enantioselective [2 + 2 + 2] Cycloaddition of 1,7-Enynes: Assembly of the Benzo[<i>c</i>]chromen-1-ol Backbone and Access to Enantioenriched Cannabinol Bioisostere

Journal of the American Chemical Society King Hung Nigel Tang, Taichi Kishi, Natsuhiko Sugimura et al. Feb 19, 2025 DOI: 10.1021/jacs.4c18319