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C2-Selective Palladium-Catalyzed C–S Cross-Coupling of 2,4-Dihalopyrimidines

Journal of the American Chemical Society Oliver D. Jackson, Albert Reyes, Collin D. Stein et al. Jan 29, 2025 DOI: 10.1021/jacs.4c17020

An Icosahedral 55-Atom Iron Hydride Cluster Protected by Tri-<i>tert</i>-butylphosphines

Journal of the American Chemical Society Tatsuya Higaki, Kanata Tanaka, Hitoshi Izu et al. Jan 29, 2025 DOI: 10.1021/jacs.4c12759

Hyperconjugation Engineering of π-Extended Azaphosphinines for Designing Tunable Thermally Activated Delayed Fluorescence Emitters

Journal of the American Chemical Society Zhaoxin Liu, Lingqiang Meng, Yanrong Jiang et al. Jan 29, 2025 DOI: 10.1021/jacs.4c15651

Unraveling Various Stacking Modes and Local Structures in Poly(triazine imide) Materials via Low-Dose Electron Microscopy

Journal of the American Chemical Society Guanxing Li, Cailing Chen, Hui Zhang et al. Jan 29, 2025 DOI: 10.1021/jacs.4c17928

Chain Shuttling Enantioselective Polymerization: An Effective Strategy for Synthesizing Stereoblock Polythioethers

Journal of the American Chemical Society Tian-Jun Yue, Yu Xiao, Bai-Hao Ren et al. Jan 29, 2025 DOI: 10.1021/jacs.4c15343

A Protein Cleavage Platform Based on Selective Formylation at Cysteine Residues

Journal of the American Chemical Society Naoki Zenmyo, Yuya Matsumoto, Akihiro Yasuda et al. Jan 29, 2025 DOI: 10.1021/jacs.4c10991

Ab Initio Predictions of Adsorption in Flexible Metal–Organic Frameworks for Water Harvesting Applications

Journal of the American Chemical Society Ruben Goeminne, Veronique Van Speybroeck Jan 29, 2025 DOI: 10.1021/jacs.4c15287

Peroxycarbenium-Mediated Asymmetric Synthesis of 1,2-Dioxanes and 1,2-Dioxolanes

Journal of the American Chemical Society Bastien Champciaux, Nicolas Jamey, Bruno Figadère et al. Jan 29, 2025 DOI: 10.1021/jacs.4c13899

Guest Segregation in Heteromeric Multicage Systems

Journal of the American Chemical Society Elie Benchimol, Andrea Rivoli, Michele Kabiri et al. Jan 29, 2025 DOI: 10.1021/jacs.4c16971

Modular Synthesis of Planar-Chiral Cyclononenes via <i>trans</i>-Retentive Trapping of π-Allyl-Pd Dipoles

Journal of the American Chemical Society Zheng-Xin Zhou, Yue-Liu-Ting Fu, Chen Zhang et al. Jan 29, 2025 DOI: 10.1021/jacs.4c12892

Taming Highly Enolizable Aldehydes via Enzyme Catalysis for Enantiocomplementary Construction of β-Hydroxyphosphonates

Journal of the American Chemical Society Huangong Li, Zheng Zhu, Dongqi Wu et al. Jan 29, 2025 DOI: 10.1021/jacs.4c11957

Substituent and Heteroatom Effects on π–π Interactions: Evidence That Parallel-Displaced π-Stacking is Not Driven by Quadrupolar Electrostatics

Journal of the American Chemical Society Brandon Schramm, Montgomery Gray, John M. Herbert Jan 29, 2025 DOI: 10.1021/jacs.4c13291

Cu-Catalyzed Diastereo- and Enantioselective Synthesis of Borylated Cyclopropanes with Three Contiguous Stereocenters

Journal of the American Chemical Society Chao Gao, Kai Tang, Xi Yang et al. Jan 29, 2025 DOI: 10.1021/jacs.4c14158

Manganese(I)-Catalyzed Enantioselective Alkylation To Access P-Stereogenic Phosphines

Journal of the American Chemical Society Bin Wan, Marta Castiñeira Reis, Tizian-Frank Ramspoth et al. Jan 29, 2025 DOI: 10.1021/jacs.4c16130

Atmospheric Hydroxyl Radical Route Revealed: Interface-Mediated Effects of Mineral-Bearing Microdroplet Aerosol

Journal of the American Chemical Society Le Yang, Yangyang Liu, Qiuyue Ge et al. Jan 29, 2025 DOI: 10.1021/jacs.4c14149

Secondary Alkylation of Arenes via the Borono–Catellani Strategy

Journal of the American Chemical Society Haiyun Peng, Dandan Wang, Jinxiang Ye et al. Jan 29, 2025 DOI: 10.1021/jacs.4c15956

Selective Synthesis of Cyclopeptides with a 2-Oxindole or 3a-Hydroxy-hexahydropyrrolo-[2,3-<i>b</i>]indole Structure by Cytochrome P450 Enzymes

Journal of the American Chemical Society Chao Li, Junying Ma, Lu Guo et al. Jan 29, 2025 DOI: 10.1021/jacs.4c13535

Ordered Interfacial Water Generated at Poly(ionic liquid) Membrane Surface Imparts Ultrafast Water Transport and Superoleophobicity

Journal of the American Chemical Society Luqi Xiao, Xiaoxuan Zheng, Ju Bai et al. Jan 29, 2025 DOI: 10.1021/jacs.4c14897

Ambient Temperature Isolation of a Monatomic Boron(0) Complex

Journal of the American Chemical Society William Kennedy, Vignesh Pattathil, Yuxiang Wei et al. Jan 29, 2025 DOI: 10.1021/jacs.4c14915

Improved Ammonia Synthesis and Energy Output from Zinc-Nitrate Batteries by Spin-State Regulation in Perovskite Oxides

Journal of the American Chemical Society Hele Guo, Yazhou Zhou, Kaibin Chu et al. Jan 29, 2025 DOI: 10.1021/jacs.4c12240