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Homonuclear/Heteronuclear Bimetallic Conjugated Coordination Polymers with Customized Oxygen Evolution Pathway

Journal of the American Chemical Society Yuhao Weng, Lizhi Sun, Hao Jia et al. Apr 23, 2025 DOI: 10.1021/jacs.5c02700

PM2.5 exposure modifies the association of physical activity with depressive symptoms and glaucoma in middle aged and elderly Chinese

Scientific Reports Xianzhi Li, Yajie Li, Bin Yu et al. Apr 23, 2025 DOI: 10.1038/s41598-025-98711-8

Sulfenylcarbene-Mediated Carbon Atom Insertion for the Late-Stage Functionalization of <i>N</i>-Heterocycles

Journal of the American Chemical Society Prakash Kafle, Deacon Herndon, Indrajeet Sharma Apr 23, 2025 DOI: 10.1021/jacs.5c02012

Role of lactate dehydrogenase A in the regulation of podocyte metabolism and glucose uptake under hyperglycemic conditions

Scientific Reports Audzeyenka Irena, Grochowalska Klaudia, Szrejder Maria et al. Apr 23, 2025 DOI: 10.1038/s41598-025-98797-0

Abstract Lactate is a cellular product of glycolytic metabolism, serving as both an additional oxidative energy substrate and a signaling molecule in metabolic regulation. Plasma lactate levels are elevated in diabetes, and chronic extracellular lactic acidosis is recognized as a negative prognostic marker for the disease. The development of diabetic kidney disease is closely associated with podocyte injury, which forms a crucial layer of the glomerular filtration barrier. Given that high extracellular glucose concentrations also induce lactate production and excretion in podocytes, we hypothesize that an appropriate LDH expression pattern is crucial for maintaining proper podocyte metabolism and function. Our research shows that hyperglycemia significantly decreases lactate dehydrogenase activity in podocytes. Specifically, reduced LDHA expression under hyperglycemic conditions contributes to metabolic disturbances in these cells. Lower LDH activity results in decreased glycolytic activity, altered expression of monocarboxylate transporters, reduced insulin-dependent glucose uptake, and a decrease in the number of podocyte foot processes. These findings underscore the essential role of LDHA in the metabolic adaptation of podocytes to elevated glucose levels typical of diabetes. By elucidating the molecular mechanisms underlying podocyte injury, our study provides new insights into potential therapeutic targets for preventing or mitigating diabetic kidney disease.

Magnetite Nanodiscs Activate Mechanotransductive Calcium Signaling in Diverse Cell Types

Journal of the American Chemical Society Jacob L. Beckham, Ye Ji Kim, Emmanuel Vargas Paniagua et al. Apr 23, 2025 DOI: 10.1021/jacs.4c18227

Effect of maternal gestational diabetes mellitus on neurodevelopment in late preterm infants at the corrected age of 12 months

Scientific Reports Lidan Qian, Tiantian Xin, Weidong Xu et al. Apr 23, 2025 DOI: 10.1038/s41598-025-98987-w

Versatile Solid-State Medical Superglue Precursors of α-Lipoic Acid

Journal of the American Chemical Society Subhajit Pal, Erika E. Salzman, Dominic Ramirez et al. Apr 23, 2025 DOI: 10.1021/jacs.4c18448

Incorporation of explainable artificial intelligence in ensemble machine learning-driven pancreatic cancer diagnosis

Scientific Reports Faisal Abdulaziz Almisned, Natacha Usanase, Dilber Uzun Ozsahin et al. Apr 23, 2025 DOI: 10.1038/s41598-025-98298-0

Abstract Despite the strides made in medical science, pancreatic cancer continues to be a threat, highlighting the urgent need for creative strategies to address this concern. Recently, a potential approach that has attracted significant attention is using machine learning in clinical decision-making. This research aims to analyze six machine learning algorithms, and an ensemble voting classifier, develop hybrid models for the early detection of pancreatic cancer based on several clinical characteristics and interpret their performance with Shapley Additive Explanations (SHAP). A publicly available dataset composed of 590 patient urine samples was utilized to develop six conventional models for the classification of cancerous from non-cancerous pancreatic cases through the analysis of specific attributes. An ensemble voting classifier was developed from the best-performed single models, which were later hybridized to form six novel hybrid models. The ensemble voting classifier outperformed all stand-alone models with an accuracy of 96.61% and a precision of 98.72%. The six novel hybrid models exhibited higher performance than single models with voting classifier random forest hybridized model outperforming others with an AUC of 99.05% (95% confidence interval (CI): 0.93-1.00) and an interpretation was given by SHAP showing top influential features in pancreatic cancer diagnosis that exhibited the greatest positive SHAP values. Employing rapid sophisticated models with high accuracy and precision holds significant promise in facilitating the effective detection of various diseases, including pancreatic cancer.

Retraction of “Room Temperature Metallic Conductivity in a Metal–Organic Framework Induced by Oxidation”

Journal of the American Chemical Society Andrew J. Clough, Nicholas M. Orchanian, Jonathan M. Skelton et al. Apr 23, 2025 DOI: 10.1021/jacs.5c00681

Publisher Correction: Psychometric properties of the Arabic emotional and behavioral reaction to intrusions questionnaire among sample of Arabic speaking adults

Scientific Reports Emmanuelle Awad, Diana Malaeb, Amthal Alhuwailah et al. Apr 23, 2025 DOI: 10.1038/s41598-025-99081-x

Single Catalyst with Dynamic Ligands Enabled Synthesis of Olefin Block Copolymers

Journal of the American Chemical Society Lanfei Lu, Yu Li, Chenxiaoning Meng et al. Apr 23, 2025 DOI: 10.1021/jacs.4c18606

Research on optimization of temperature sensitive points of machine tool thermal error based on independent variable selection criteria

Scientific Reports Huadong Li, Jingjun Liu, Yang Li Apr 23, 2025 DOI: 10.1038/s41598-025-98143-4

Rh-Catalyzed Enantioselective Aryl C–H Bond Cyclopropylation

Journal of the American Chemical Society Eric Palomo, Anastasiya Krech, Yu Jen Hsueh et al. Apr 23, 2025 DOI: 10.1021/jacs.5c02331

Characterization of 45 cases of congenital lung malformation and association of inflammation with symptomatology

Scientific Reports Susanna Nuutinen, Elisa Lappi-Blanco, Eveliina Ronkainen et al. Apr 23, 2025 DOI: 10.1038/s41598-025-98743-0

Molecular insights into antibiofilm inhibitors of Streptococcus mutans glucosyltransferases through in silico approaches

Scientific Reports Lubna Atta, Ali Raza Siddiqui, Mamona Mushtaq et al. Apr 23, 2025 DOI: 10.1038/s41598-025-98927-8

Ligand Shell Thickness of Colloidal Nanocrystals: A Comparison of Small-Angle Neutron and X-ray Scattering

Journal of the American Chemical Society Eliza K. Price, Guilherme Bejar, Jimin Kwag et al. Apr 23, 2025 DOI: 10.1021/jacs.5c02070

The effect of incorporating whole body vibration into exercise therapy on the corticomotor excitability of the quadriceps in athletes following anterior cruciate ligament reconstruction

Scientific Reports Roya Khanmohammadi, Sahar Zare, Ali Musavi et al. Apr 23, 2025 DOI: 10.1038/s41598-025-98134-5

Aqueous-Phase Synthesis of Cyclic Trinuclear Cluster-Based Metal–Organic Frameworks

Journal of the American Chemical Society Kun Wu, Wei Zhao, Ling Huang et al. Apr 23, 2025 DOI: 10.1021/jacs.5c01434

Neutron diffraction evidence of the 3-dimensional structure of Ba2MnTeO6 and misidentification of the triangular layers within the face-centred cubic lattice

Scientific Reports Otto H. J. Mustonen, Charlotte E. Pughe, Helen C. Walker et al. Apr 23, 2025 DOI: 10.1038/s41598-025-97181-2

Rational Control of Ionic Conduction of Encapsulated Ionic Liquid by Fluorination of Isoreticular Metal–Organic Frameworks

Journal of the American Chemical Society Tuo Di, Yukihiro Yoshida, Hiroshi Kitagawa Apr 23, 2025 DOI: 10.1021/jacs.5c02879