Synergistic Ti3C2 MXene/MoS2 heterostructure: Unlocking ultra-fast, durable, and high-efficiency energy storage for next-generation supercapacitors

S Shalini Shanmuganathi (Functional Nanomaterials (FuN) Laboratory, Department of Physics and Nanotechnology, Faculty of Engineering and Technology, SRM Institute of Science and Technology 1 , Kattankulathur 603203,) T Tharani Selvam (Functional Nanomaterials (FuN) Laboratory, Department of Physics and Nanotechnology, Faculty of Engineering and Technology, SRM Institute of Science and Technology 1 , Kattankulathur 603203,) D Durgalakshmi Dhinasekaran (Department of Medical Physics, Anna University 2 , Chennai 600 025,) A Ashwin Kishore Munusamy Rajendran (Department of Chemical Engineering, University of Seoul 3 , Seoul 02504,) B Balakumar Subramanian (National Centre for Nanoscience and Nanotechnology, University of Madras 4 , Chennai 600 025,) A Ajay Rakkesh Rajendran (Functional Nanomaterials (FuN) Laboratory, Department of Physics and Nanotechnology, Faculty of Engineering and Technology, SRM Institute of Science and Technology 1 , Kattankulathur 603203,)

Abstract

Developing advanced electrode materials with high energy storage capacity, excellent cycling stability, and rapid charge–discharge capabilities is pivotal for next-generation supercapacitors. In this study, we present a stable Ti3C2 MXene/MoS2 heterostructure synthesized via a facile hydrothermal method, and the synergistic interaction between MoS2 and Ti3C2 MXene prevents structural collapse and was found to enhance pseudocapacitive charge storage through reversible redox reactions at Mo-active sites. The heterostructure exhibits an impressive specific capacitance of 679.9 F g−1 at 1 A g−1, attributed to its unique 2D/2D architecture that ensures efficient ion diffusion, rapid charge transfer, and abundant electroactive sites. Furthermore, the material demonstrates outstanding cycling stability, retaining 83.81% of its efficiency and 88.45% of its initial capacitance after 10 000 cycles at 20 A g−1. This work highlights the importance of the structural design of the electrode material for robust durability and high performance. Thus, this work paves the path for the next-generation Ti3C2 MXene/MoS2 heterostructure electrodes, making it a promising candidate for ultra-fast, long-lasting, and high-efficiency hybrid materials for advanced supercapacitor technologies.

Article Details

Volume / Issue Vol. 126, Issue 10
Published March 01, 2025
ISSN 0003-6951
Publisher American Institute of Physics

Journal Info

Applied Physics Letters

American Institute of Physics

ISSN: 0003-6951 Physical Sciences

Authors (6)

S

Shalini Shanmuganathi

Functional Nanomaterials (FuN) Laboratory, Department of Physics and Nanotechnology, Faculty of Engineering and Technology, SRM Institute of Science and Technology 1 , Kattankulathur 603203,

T

Tharani Selvam

Functional Nanomaterials (FuN) Laboratory, Department of Physics and Nanotechnology, Faculty of Engineering and Technology, SRM Institute of Science and Technology 1 , Kattankulathur 603203,

D

Durgalakshmi Dhinasekaran

Department of Medical Physics, Anna University 2 , Chennai 600 025,

A

Ashwin Kishore Munusamy Rajendran

Department of Chemical Engineering, University of Seoul 3 , Seoul 02504,

B

Balakumar Subramanian

National Centre for Nanoscience and Nanotechnology, University of Madras 4 , Chennai 600 025,

A

Ajay Rakkesh Rajendran

Functional Nanomaterials (FuN) Laboratory, Department of Physics and Nanotechnology, Faculty of Engineering and Technology, SRM Institute of Science and Technology 1 , Kattankulathur 603203,