Surface termination of <b> <i>β</i> </b> -Ga2O3(100) as-cleaved single crystals
Abstract
The surface of β-Ga2O3 single crystals cleaved along their (100) plane is investigated using surface x-ray diffraction and atomic force microscopy. The results show the surface to consist of a single, so-called B-termination, which means that the crystal cleaves at planes formed by edge-sharing oxygen octahedra, thereby breaking the longest and weakest Ga–O bonds. Refinement of the atomic positions results in small displacements from the bulk structure, at most approximately 0.01 Å. Atomic force microscopy suggests that relatively large terraces form together with steps of half the a-axis length of approximately 0.6 nm, which means that terraces have the same atomic termination, related by the crystal symmetry. These results are important as a fundamental property of β-Ga2O3 when processed or used in various semiconductor applications.
Article Details
Journal Info
Applied Physics Letters
American Institute of Physics
Authors (12)
Ming-Chao Kao
Centre for X-ray and Nano Science CXNS, Deutsches Elektronen-Synchrotron DESY 1 , Notkestraße 85, 22607 Hamburg,
Lukas Paul Schewe
Applied Physics and Semiconductor Spectroscopy, Brandenburg University of Technology Cottbus-Senftenberg 3 , D-03046 Cottbus,
Arub Akhtar
Leibniz-Institut für Kristallzüchtung 4 , Max-Born-Straße 2, D-12489 Berlin,
Alina Vlad
Synchrotron SOLEIL 5 , L'Orme des Merisiers, 91190 Saint-Aubin,
Thomas F. Keller
Centre for X-ray and Nano Science CXNS, Deutsches Elektronen-Synchrotron DESY 1 , Notkestraße 85, 22607 Hamburg,
Karsten Henkel
Applied Physics and Semiconductor Spectroscopy, Brandenburg University of Technology Cottbus-Senftenberg 3 , D-03046 Cottbus,
Saud Bin Anooz
Leibniz-Institut für Kristallzüchtung 4 , Max-Born-Straße 2, D-12489 Berlin,
Andreas Popp
Leibniz-Institut für Kristallzüchtung 4 , Max-Born-Straße 2, D-12489 Berlin,
Zbigniew Galazka
Leibniz-Institut für Kristallzüchtung (IKZ) 2 , Max-Born-Straße 2, 12489 Berlin,
Jan Ingo Flege
Applied Physics and Semiconductor Spectroscopy, Brandenburg University of Technology Cottbus-Senftenberg 3 , D-03046 Cottbus,
Andreas Stierle
Centre for X-ray and Nano Science CXNS
Vedran Vonk