Stable magnetocaloric effect over an ultrawide temperature range of 146–320 K via hydrostatic pressure in kagome magnets

J Junchao Sheng (Anhui Provincial Key Laboratory of Magnetic Functional Materials and Devices, School of Materials Science and Engineering, Anhui University Hefei 1 , Anhui 230601,) J Jiawang Xu (Anhui Provincial Key Laboratory of Magnetic Functional Materials and Devices, School of Materials Science and Engineering, Anhui University Hefei 1 , Anhui 230601,) L Lei Xi S Shouyuan Xing (Anhui Provincial Key Laboratory of Magnetic Functional Materials and Devices, School of Materials Science and Engineering, Anhui University Hefei 1 , Anhui 230601,) S Shihao Li (Biotechnology Research Institute, Chinese Academy of Agricultural Sciences) X Xucai Kan (School of Materials Science and Engineering, Anhui University 6 , Hefei 230601,) X Xinqi Zheng (School of Materials Science and Engineering) H He Huang L Lichen Wang (Ningbo Institute of Materials Technology & Engineering, Chinses Academy of Sciences Ningbo 3 , Zhejiang 315201,) Y Yuyan Han S Shiming Zhou (Hefei National Research Center for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, National Synchrotron Radiation Laboratory, Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, Department of Chemical Physics) B Baogen Shen (Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences) S Shouguo Wang

Abstract

Solid-state refrigeration leveraging the magnetocaloric effect (MCE) presents a sustainable and energy-efficient alternative to traditional gas compression refrigeration technologies. However, the practical utility of most magnetocaloric materials is restricted by their narrow operational temperature window. In this work, a stable magnetocaloric effect across an ultrawide temperature range of 146–320 K was achieved in Hf0.85Ta0.15Fe2 magnet via the hydrostatic pressure manipulation. Furthermore, the underlying mechanism for the extended and stable MCEs under hydrostatic pressure has been revealed by magnetization measurements and first-principles calculations. The material systems characterized by strong spin–lattice coupling exhibit considerable potential for externally manipulated hybrid-field-tuned magnetic properties and magnetocaloric performance, providing a convenient and practical approach for advancing applications in magnetic refrigeration technologies.

Article Details

Volume / Issue Vol. 126, Issue 3
Published January 20, 2025
ISSN 0003-6951
Publisher American Institute of Physics

Journal Info

Applied Physics Letters

American Institute of Physics

ISSN: 0003-6951 Physical Sciences

Authors (13)

J

Junchao Sheng

Anhui Provincial Key Laboratory of Magnetic Functional Materials and Devices, School of Materials Science and Engineering, Anhui University Hefei 1 , Anhui 230601,

J

Jiawang Xu

Anhui Provincial Key Laboratory of Magnetic Functional Materials and Devices, School of Materials Science and Engineering, Anhui University Hefei 1 , Anhui 230601,

L

Lei Xi

S

Shouyuan Xing

Anhui Provincial Key Laboratory of Magnetic Functional Materials and Devices, School of Materials Science and Engineering, Anhui University Hefei 1 , Anhui 230601,

S

Shihao Li

Biotechnology Research Institute, Chinese Academy of Agricultural Sciences

X

Xucai Kan

School of Materials Science and Engineering, Anhui University 6 , Hefei 230601,

X

Xinqi Zheng

School of Materials Science and Engineering

H

He Huang

L

Lichen Wang

Ningbo Institute of Materials Technology & Engineering, Chinses Academy of Sciences Ningbo 3 , Zhejiang 315201,

Y

Yuyan Han

S

Shiming Zhou

Hefei National Research Center for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, National Synchrotron Radiation Laboratory, Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, Department of Chemical Physics

B

Baogen Shen

Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences

S

Shouguo Wang