Perspectives on various-temperature stability of p-i-n perovskite solar cells

Abstract

Despite the significant breakthroughs in photoelectric conversion efficiency achieved by perovskite solar cells, their temperature stability remains a significant bottleneck to commercialization. Temperature fluctuations typically lead to structural changes and phase transformations in perovskites. Additionally, thermal stress can facilitate ion migration within the perovskite material, resulting in interface charge accumulation and electrode corrosion, which ultimately undermines the performance of perovskite devices. This brief perspective systematically discusses the mechanisms behind device performance degradation under temperature cycling conditions and presents potential improvement strategies to address these issues. Finally, we elaborate on the future challenges that must be overcome for the successful commercialization of these devices.