Kerr electro-optic properties of rare-earth doped Pb(Mg1/3Nb2/3)O3-PbTiO3 crystals

H Hongjiang Wu R Ruibin Xiong (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences 1 , Fuzhou 350002,) R Rongbing Su (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences 1 , Fuzhou 350002,) Z Zujian Wang B Bin Su L Lingfei Lv (State Key Laboratory of Functional Crystals and Devices Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou China) C Chao He (Department of Chemistry)

Abstract

Pb(Mg1∕3Nb2∕3)O3-PbTiO3 (PMN-PT) crystals exhibit significant potential for applications in the electro-optical (EO) field, owing to their low half-wave voltage and high electro-optic coefficients, ease of miniaturization, and integration. However, the ferroelectric phase PMN-PT crystals exhibit a low extinction ratio due to light scattering and reflection by domain walls. In this study, high-transmittance paraelectric phase PMN-PT crystals were synthesized through compositional optimization and rare-earth ion doping. The optical and Kerr electro-optic properties of the crystals were systematically analyzed, considering the PT composition and doping with La3+ and Sm3+ ions. The La-PMN-8PT crystals demonstrated a transmission rate of 75%, a quadratic electro-optic coefficient of 4.28 × 10−16 m2/V2, an extinction ratio of 29 dB, and a half-wave voltage of 270 V. Additionally, the electro-optical performance of the crystals was evaluated over a range of temperatures, revealing excellent temperature stability in the La-doped crystals. These results highlight the promising potential of La-doped PMN-PT crystals for advanced electro-optical applications.

Article Details

Volume / Issue Vol. 126, Issue 15
Published April 01, 2025
ISSN 0003-6951
Publisher American Institute of Physics

Journal Info

Applied Physics Letters

American Institute of Physics

ISSN: 0003-6951 Physical Sciences

Authors (7)

H

Hongjiang Wu

R

Ruibin Xiong

Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences 1 , Fuzhou 350002,

R

Rongbing Su

Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences 1 , Fuzhou 350002,

Z

Zujian Wang

B

Bin Su

L

Lingfei Lv

State Key Laboratory of Functional Crystals and Devices Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou China

C

Chao He

Department of Chemistry