HM-C21: A three-dimensional carbon with abundant p-electron-induced magnetic states for spintronics

J Junjie Zhao M Mingqing Liao (School of Materials Science and Engineering) J Jiayu Zhang Y Yuehua Wang (State Key Laboratory of Chemo and Biosensing, Hunan Provincial Key Laboratory of Plant Functional Genomics and Developmental Regulation, College of Biology, Longping Agricultural College, Hunan University) C Chenggang Wu (School of Materials Science and Engineering, Jiangsu University of Science and Technology 1 , Zhenjiang 212100,) H Haoxin Jiang (School of Materials Science and Engineering, Jiangsu University of Science and Technology 1 , Zhenjiang 212100,) F Fei Zhou J Jintong Guan (School of Materials Science and Engineering, Jiangsu University 3 , Zhenjiang 212013,) D Danni Yang (Chongqing Key Laboratory of Natural Product Synthesis and Drug Research, School of Pharmaceutical Sciences) N Nan Qu (School of Materials Science and Engineering, Harbin Institute of Technology 5 , Harbin 150001,) F Fengjiang Wang (School of Materials Science and Engineering, Jiangsu University of Science and Technology 1 , Zhenjiang 212100,)

Abstract

Due to their long-distance spin transport and long spin lifetime, p-electron-induced spintronic materials have been attracting increasing attention. As the most common d-electron-free elements, carbon allotropes present many excellent properties. However, pure three-dimensional carbon spintronics material has not been reported so far. Here, we proposed a superhard (HV = 60 GPa) carbon material named half-metal (HM)-C21, which presents multi-stable magnetic states and unexpected properties, such as those of half-metal, half-semiconductor, bipolar magnetic semiconductor, and asymmetric antiferromagnetic semiconductors. The mechanical, dynamical, and thermodynamical stabilities of HM-C21 are confirmed. Moreover, HM-C21 is considered to be a promising candidate for an unidentified cubic-form carbon reported in previous experiments. Hence, the present work holds great promise for discovering spintronic materials in pure three-dimensional carbon.

Article Details

Volume / Issue Vol. 126, Issue 16
Published April 21, 2025
ISSN 0003-6951
Publisher American Institute of Physics

Journal Info

Applied Physics Letters

American Institute of Physics

ISSN: 0003-6951 Physical Sciences

Authors (11)

J

Junjie Zhao

M

Mingqing Liao

School of Materials Science and Engineering

J

Jiayu Zhang

Y

Yuehua Wang

State Key Laboratory of Chemo and Biosensing, Hunan Provincial Key Laboratory of Plant Functional Genomics and Developmental Regulation, College of Biology, Longping Agricultural College, Hunan University

C

Chenggang Wu

School of Materials Science and Engineering, Jiangsu University of Science and Technology 1 , Zhenjiang 212100,

H

Haoxin Jiang

School of Materials Science and Engineering, Jiangsu University of Science and Technology 1 , Zhenjiang 212100,

F

Fei Zhou

J

Jintong Guan

School of Materials Science and Engineering, Jiangsu University 3 , Zhenjiang 212013,

D

Danni Yang

Chongqing Key Laboratory of Natural Product Synthesis and Drug Research, School of Pharmaceutical Sciences

N

Nan Qu

School of Materials Science and Engineering, Harbin Institute of Technology 5 , Harbin 150001,

F

Fengjiang Wang

School of Materials Science and Engineering, Jiangsu University of Science and Technology 1 , Zhenjiang 212100,