Formation and stability of Ge nanocrystals in polymorph converted Ga2O3: Temperature-driven journey

J J. Garcia-Fernàndez S S. B. Kjeldby (Department of Physics and Centre for Materials Science and Nanotechnology, University of Oslo 1 , Oslo 0315,) L L. J. Zeng (Department of Physics, Chalmers University of Technology 2 , Gothenburg 41296,) E E. Olsson (Department of Physics, Chalmers University of Technology 2 , Gothenburg 41296,) L L. Vines (Department of Physics and Centre for Materials Science and Nanotechnology, University of Oslo 1 , Oslo 0315,) Ø. Prytz (Department of Physics and Centre for Materials Science and Nanotechnology, University of Oslo 1 , Oslo 0315,)

Abstract

The influence of germanium (Ge) implantation on β-Ga2O3 followed by ex situ annealing through polymorph conversion in air at various temperatures (600–1100 °C) is studied. Atomic resolution aberration-corrected scanning transmission electron microscopy is employed to examine the structural and microstructural changes induced by the annealing process. The results show that the thermal annealing process leads to the formation of Ge nanocrystals, which subsequently disappear, leaving nano-voids inside the Ge-doped Ga2O3 matrix. In addition, the microstructure displays distinct crystallographic relationships in annealed β-Ga2O3 forming layers with well-defined interfaces. This work reveals the unique effects of Ge-implantation, demonstrating the possible functionalization of Ga2O3 with Ge nanocrystals.

Article Details

Volume / Issue Vol. 126, Issue 5
Published February 03, 2025
ISSN 0003-6951
Publisher American Institute of Physics

Journal Info

Applied Physics Letters

American Institute of Physics

ISSN: 0003-6951 Physical Sciences

Authors (6)

J

J. Garcia-Fernàndez

S

S. B. Kjeldby

Department of Physics and Centre for Materials Science and Nanotechnology, University of Oslo 1 , Oslo 0315,

L

L. J. Zeng

Department of Physics, Chalmers University of Technology 2 , Gothenburg 41296,

E

E. Olsson

Department of Physics, Chalmers University of Technology 2 , Gothenburg 41296,

L

L. Vines

Department of Physics and Centre for Materials Science and Nanotechnology, University of Oslo 1 , Oslo 0315,

Ø. Prytz

Department of Physics and Centre for Materials Science and Nanotechnology, University of Oslo 1 , Oslo 0315,