Enhanced negative terahertz photoconductivity enabled by interfacial charge transfer in Te/graphene mixed-dimensional heterojunction

P Pujing Zhang L Longyu Shi Z Zhiyuan Zhang H Huiwen Shi (Key Laboratory of Terahertz Optoelectronics, Ministry of Education, and Beijing Advanced Innovation Center for Imaging Theory and Technology, Department of Physics, Capital Normal University 1 , Beijing 100048,) H Haojing Wang (Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences 3 , Beijing 100190,) G Guangwei She (Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences 3 , Beijing 100190,) P Peijie Wang (Key Laboratory of Terahertz Optoelectronics, Ministry of Education, and Beijing Advanced Innovation Center for Imaging Theory and Technology, Department of Physics, Capital Normal University 1 , Beijing 100048,) W Wensheng Shi (Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences 3 , Beijing 100190,) C Cunlin Zhang Q Qingli Zhou

Abstract

Negative terahertz photoconductivity is a rare effect that holds great significance for numerous applications. However, the maintenance and enhancement of negative photoconductivity response still face a huge challenge. Here, combined with material selection and band alignment engineering, we have proposed a mixed-dimensional heterostructure comprised of 1D tellurium (Te) nanowires and 2D monolayer graphene. Intriguingly, the Te/graphene heterojunction could enhance negative terahertz photoconductivity by twice compared with graphene, following a transition from negative to positive photoconductivities. We have further performed first-principles calculations and characterizations to elucidate the type-I band alignment at the heterointerface, revealing the phenomena attributed to interfacial charge transfer. Our results provide in-depth physical insights into the carrier transport mechanism, which is crucial for further exploration of optoelectronic devices based on mixed-dimensional heterostructures.

Article Details

Volume / Issue Vol. 127, Issue 11
Published September 15, 2025
ISSN 0003-6951
Publisher American Institute of Physics

Journal Info

Applied Physics Letters

American Institute of Physics

ISSN: 0003-6951 Physical Sciences

Authors (10)

P

Pujing Zhang

L

Longyu Shi

Z

Zhiyuan Zhang

H

Huiwen Shi

Key Laboratory of Terahertz Optoelectronics, Ministry of Education, and Beijing Advanced Innovation Center for Imaging Theory and Technology, Department of Physics, Capital Normal University 1 , Beijing 100048,

H

Haojing Wang

Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences 3 , Beijing 100190,

G

Guangwei She

Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences 3 , Beijing 100190,

P

Peijie Wang

Key Laboratory of Terahertz Optoelectronics, Ministry of Education, and Beijing Advanced Innovation Center for Imaging Theory and Technology, Department of Physics, Capital Normal University 1 , Beijing 100048,

W

Wensheng Shi

Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences 3 , Beijing 100190,

C

Cunlin Zhang

Q

Qingli Zhou