Electronic properties of extended surface defects in homoepitaxial GaN diodes

A Andrew J. Winchester (Physical Measurement Laboratory, National Institute of Standards and Technology 2 , Gaithersburg, Maryland 20899,) V Valery Ortiz Jimenez (Nanoscale Device and Characterization Division, National Institute of Standards and Technology (NIST) 1 , Gaithersburg, Maryland 20899,) D Dara Weiss (Building Energy and Environment Division, National Institute of Standards and Technology (NIST) 2 , Gaithersburg, Maryland 20899,) C Curt A. Richter (Nanoscale Device and Characterization Division, National Institute of Standards and Technology (NIST) 1 , Gaithersburg, Maryland 20899,) B Behrang H. Hamadani (Engineering Laboratory, National Institute of Standards & Technology 9 , Gaithersburg, Maryland 20899,) M Michael A. Mastro (Power and Advanced Materials Branch, US Naval Research Laboratory 3 , Washington, District of Columbia 20375,) T Travis J. Anderson (Power and Advanced Materials Branch, US Naval Research Laboratory 3 , Washington, District of Columbia 20375,) J Jennifer K. Hite (Power and Advanced Materials Branch, US Naval Research Laboratory 3 , Washington, District of Columbia 20375,) S Sujitra Pookpanratana (Physical Measurement Laboratory, National Institute of Standards and Technology 2 , Gaithersburg, Maryland 20899,)

Abstract

GaN on GaN vertical power devices are promising for high voltage applications beyond Si and SiC. Developing GaN substrates with low defect densities for high-quality epitaxial growth has been an ongoing challenge. Consequently, extended defects are a concern for high power device performance and reliability and must be mitigated. In particular, newer ammonothermally grown GaN substrates with lower extended defect densities have not yet been evaluated as extensively as hydride vapor phase epitaxy GaN. Here, we identify different electrically active defects on epitaxial p-GaN layers grown on strain-patterned (dot-core) and ammonothermal GaN substrates. On dot-core substrates, “star” defects were observed that consist of pits and cracks, have an increased hole carrier density, display occupied bandgap states, and show reduced and variable forward bias currents. In contrast, on ammonothermal substrates, triangular patches were found on certain rough epitaxy ridges and show increased gap states along with a lower carrier density and reduced conductivity. The star and triangular defects likely correspond to threading dislocations and stacking faults, respectively, and may act as killer defects. As a result, p–i–n diode devices on ammonothermal substrates frequently exhibited poor reverse and forward bias behavior due to the random extended defect distribution that cannot be intentionally avoided as in patterned dot-core substrates, as well as different impurity defects in the epitaxy. Therefore, we have found that ammonothermal GaN substrates require tighter control over both point and extended defect distributions in order to achieve reliable high power electronic devices.

Article Details

Volume / Issue Vol. 127, Issue 3
Published July 21, 2025
ISSN 0003-6951
Publisher American Institute of Physics

Journal Info

Applied Physics Letters

American Institute of Physics

ISSN: 0003-6951 Physical Sciences

Authors (9)

A

Andrew J. Winchester

Physical Measurement Laboratory, National Institute of Standards and Technology 2 , Gaithersburg, Maryland 20899,

V

Valery Ortiz Jimenez

Nanoscale Device and Characterization Division, National Institute of Standards and Technology (NIST) 1 , Gaithersburg, Maryland 20899,

D

Dara Weiss

Building Energy and Environment Division, National Institute of Standards and Technology (NIST) 2 , Gaithersburg, Maryland 20899,

C

Curt A. Richter

Nanoscale Device and Characterization Division, National Institute of Standards and Technology (NIST) 1 , Gaithersburg, Maryland 20899,

B

Behrang H. Hamadani

Engineering Laboratory, National Institute of Standards & Technology 9 , Gaithersburg, Maryland 20899,

M

Michael A. Mastro

Power and Advanced Materials Branch, US Naval Research Laboratory 3 , Washington, District of Columbia 20375,

T

Travis J. Anderson

Power and Advanced Materials Branch, US Naval Research Laboratory 3 , Washington, District of Columbia 20375,

J

Jennifer K. Hite

Power and Advanced Materials Branch, US Naval Research Laboratory 3 , Washington, District of Columbia 20375,

S

Sujitra Pookpanratana

Physical Measurement Laboratory, National Institute of Standards and Technology 2 , Gaithersburg, Maryland 20899,