Atomic-scale mechanisms of stress-controlled nanocrystal nucleation in amorphous alloys

X Xiaozhen Fan (College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,) Y Yanjun Qin (College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,) J Jingui Li (College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,) W Wenzhong Li Y Yibin Liu (State Key Laboratory of Metabolism and Regulation in Complex Organisms, College of Chemistry and Molecular Sciences, Taikang Center for Life and Medical Sciences) Z Ziyue Zhang (State Key Laboratory of Reproductive Medicine and Offspring Health, Key Laboratory of Infection Immunity and Disease Intervention of Shandong Province, Key Laboratory for Experimental Teratology of Ministry of Education, Shandong University) J Jianqiang Zhang Z Zhenghang Wei (College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,) H Huiqun Ye (College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,) Y Yunzhang Fang (College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,)

Abstract

Stress annealing offers a powerful route to control nanocrystallization in amorphous alloys, yet the atomic-scale mechanisms remain poorly understood. Here, we reveal that tensile stress significantly increases the density of preordered Cu clusters and induces their anisotropic alignment along the stress direction. These clusters act as preferential nucleation sites for Fe–Si nanocrystals, promoting directional growth and resulting in pronounced structural anisotropy. In the stress-annealed samples, the parallel-to-perpendicular cluster orientation ratio reaches 1.86, confirming the strong directional influence of applied stress. This stress-mediated enhancement of nucleation, coupled with suppression of isotropic crystal growth, leads to refined grains and controllable nanocrystallization pathways. These results provide critical atomic-scale insights into stress-directed microstructural evolution and establish a fundamental basis for engineering the nanocrystallization of amorphous alloys through stress-based processing.

Article Details

Volume / Issue Vol. 127, Issue 18
Published November 03, 2025
ISSN 0003-6951
Publisher American Institute of Physics

Journal Info

Applied Physics Letters

American Institute of Physics

ISSN: 0003-6951 Physical Sciences

Authors (10)

X

Xiaozhen Fan

College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,

Y

Yanjun Qin

College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,

J

Jingui Li

College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,

W

Wenzhong Li

Y

Yibin Liu

State Key Laboratory of Metabolism and Regulation in Complex Organisms, College of Chemistry and Molecular Sciences, Taikang Center for Life and Medical Sciences

Z

Ziyue Zhang

State Key Laboratory of Reproductive Medicine and Offspring Health, Key Laboratory of Infection Immunity and Disease Intervention of Shandong Province, Key Laboratory for Experimental Teratology of Ministry of Education, Shandong University

J

Jianqiang Zhang

Z

Zhenghang Wei

College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,

H

Huiqun Ye

College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,

Y

Yunzhang Fang

College of Physics and Electronic Information Engineering, Zhejiang Normal University 1 , Jinhua 321004,