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Tetra-Cationic Distibane Stabilized by Bis(α-iminopyridine) and Its Reactivity

Journal of the American Chemical Society Hritwik Haldar, Satyabrata Das, Haakon T. A. Wiedemann et al. Jan 29, 2025 DOI: 10.1021/jacs.4c12354

Fermi Level Equilibration and Charge Transfer at the Exsolved Metal-Oxide Interface

Journal of the American Chemical Society Jiayue Wang, Jing Yang, Jenna L. Wardini et al. Jan 29, 2025 DOI: 10.1021/jacs.4c14695

Emergence of Chirality in an Optically Active Two-Dimensional Crystal with a Spiral Surface Pattern

Journal of the American Chemical Society Hubiao Huang, Gangfeng Chen, Manabu Hoshino et al. Jan 29, 2025 DOI: 10.1021/jacs.4c12631

Crafting Hollow Spheres via Bulk Ice Melting with ppb-Level Gas Sensing Performance

Journal of the American Chemical Society Zhuo Chen, Jinrong Wang, Xing Liu et al. Jan 29, 2025 DOI: 10.1021/jacs.4c14808

3D Covalent Organic Framework Membrane with Interactive Ion Nanochannels for Hydroxide Conduction

Journal of the American Chemical Society Jia Chen, Zhuozhuo Tang, Li Sheng et al. Jan 29, 2025 DOI: 10.1021/jacs.4c16029

Readily Accessible, Versatile, and Adaptive Biaxially Chiral Chromophores

Journal of the American Chemical Society Summer J. Brown, Jiaoyan Zhao, Ellen Forehand et al. Jan 29, 2025 DOI: 10.1021/jacs.4c16566

Supramolecularly Built Local Electric Field Microenvironment around Cobalt Phthalocyanine in Covalent Organic Frameworks for Enhanced Photocatalysis

Journal of the American Chemical Society Yi Zhang, Xinyu Guan, Zheng Meng et al. Jan 29, 2025 DOI: 10.1021/jacs.4c16538

B, N Codoped Defective Reduced Graphene Oxide as a Highly Efficient Frustrated Lewis Pairs Catalyst for the Selective Hydrogenation of α,β-Unsaturated Aldehydes to Unsaturated Alcohols

Journal of the American Chemical Society Linhao Zhong, Xiaoqing Liao, Huaquan Huang et al. Jan 29, 2025 DOI: 10.1021/jacs.4c17103

Pseudopterosin Biosynthesis: Unravelling a Decades Old Problem in Animal Specialized Metabolism

Journal of the American Chemical Society Paul D. Scesa, Eric W. Schmidt Jan 29, 2025 DOI: 10.1021/jacs.4c09925

Facile Access to Quaternary Carbon Centers via Ni-Catalyzed Arylation of Alkenes with Organoborons

Journal of the American Chemical Society Zi-Chao Wang, Lei Gao, Song-Yang Liu et al. Jan 29, 2025 DOI: 10.1021/jacs.4c17313

Dual Activation Modes Enable Bifunctional Catalysis of Aldol Reactions by Flexible Dihydrazides

Journal of the American Chemical Society Philip P. Lampkin, Samuel H. Gellman Jan 29, 2025 DOI: 10.1021/jacs.4c16143

Complementary Organization of Mouse Driver and Modulator Cortico-thalamo-cortical Circuits

Journal of Neuroscience Rachel M. Cassidy, Angel V. Macias, Willian N. Lagos et al. Jan 29, 2025 DOI: 10.1523/jneurosci.1167-24.2024

Corticocortical (CC) projections in the visual system facilitate hierarchical processing of sensory information. In addition to direct CC connections, indirect cortico-thalamo-cortical (CTC) pathways through the pulvinar nucleus of the thalamus can relay sensory signals and mediate cortical interactions according to behavioral demands. While the pulvinar connects extensively to the entire visual cortex, it is unknown whether transthalamic pathways link all cortical areas or whether they follow systematic organizational rules. Because mouse pulvinar neurons projecting to different areas are spatially intermingled, their input/output relationships have been difficult to characterize using traditional anatomical methods. To determine the organization of CTC circuits, we mapped the higher visual areas (HVAs) of male and female mice with intrinsic signal imaging and targeted five pulvinar→HVA pathways for projection-specific rabies tracing. We aligned postmortem cortical tissue to in vivo maps for precise quantification of the areas and cell types projecting to each pulvinar→HVA population. Layer 5 corticothalamic (L5CT) “driver” inputs to the pulvinar originate predominantly from primary visual cortex (V1), consistent with the CC hierarchy. L5CT inputs from lateral HVAs specifically avoid driving reciprocal connections, consistent with the “no-strong-loops” hypothesis. Conversely, layer 6 corticothalamic (L6CT) “modulator” inputs are distributed across areas and are biased toward reciprocal connections. Unlike previous studies in primates, we find that every HVA receives disynaptic input from the superior colliculus. CTC circuits in the pulvinar thus depend on both target HVA and input cell type, such that driving and modulating higher-order pathways follow complementary connection rules similar to those governing first-order CT circuits.

Concise Synthesis of (−)-Veratramine and (−)-20-<i>iso</i>-Veratramine via Aromative Diels–Alder Reaction

Journal of the American Chemical Society Michael D. Zott, Daniel W. Zuschlag, Dirk H. Trauner Jan 29, 2025 DOI: 10.1021/jacs.4c16495

OPTO: Automated Optimization for Solid-State NMR Spectroscopy

Journal of the American Chemical Society Collin G. Borcik, Barry DeZonia, Thirupathi Ravula et al. Jan 29, 2025 DOI: 10.1021/jacs.4c13295

Integration of Motion and Stillness: A Paradigm Shift in Constructing Nearly Planar NIR-II AIEgen with Ultrahigh Molar Absorptivity and Photothermal Effect for Multimodal Phototheranostics

Journal of the American Chemical Society Shiping Yang, Qian Jia, Xinwen Ou et al. Jan 29, 2025 DOI: 10.1021/jacs.4c15216

Molecule-Based Proton–Electron Mixed Conductor with the Highest Ambipolar Conductivity

Journal of the American Chemical Society Peng-Hao Wang, Yukihiro Yoshida, Soichiro Yasaka et al. Jan 29, 2025 DOI: 10.1021/jacs.4c16779

Proton-Induced Switching of Paramagnetism: Reversible Conversion between a Low and High Spin Co<sup>III</sup> Center within a Heterobimetallic Core

Journal of the American Chemical Society Phan N. Phu, Justin L. Lee, Saborni Biswas et al. Jan 29, 2025 DOI: 10.1021/jacs.4c12327

Modular Construction of Multivariate Metal–Organic Frameworks for Luminescent Sensing

Journal of the American Chemical Society Zongsu Han, Kun-Yu Wang, Rong-Ran Liang et al. Jan 29, 2025 DOI: 10.1021/jacs.4c17248

Be Aware of Transient Dissolution Processes in Co<sub>3</sub>O<sub>4</sub> Acidic Oxygen Evolution Reaction Electrocatalysts

Journal of the American Chemical Society Tatiana Priamushko, Evanie Franz, Anja Logar et al. Jan 29, 2025 DOI: 10.1021/jacs.4c14952

The Role of Torsion on the Force-Coupled Reactivity of a Fluorenyl Naphthopyran Mechanophore

Journal of the American Chemical Society Skylar K. Osler, Nathan A. Ballinger, Maxwell J. Robb Jan 29, 2025 DOI: 10.1021/jacs.4c18395