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Trimethylaluminum Activates Zeolite-Confined Lanthanum Borohydrides to Enhance Catalytic C–H Borylation

Journal of the American Chemical Society Yuting Li, Takeshi Kobayashi, Debora M. Meira et al. Apr 16, 2025 DOI: 10.1021/jacs.4c18569

Behavioral patterns of Chum salmon (Oncorhynchus keta) during spawning migration across the coastal water-river continuum in Northeastern Korea

Scientific Reports Beom-Sik Kim, Chang-Keun Kang, Hae Kun Jung et al. Apr 16, 2025 DOI: 10.1038/s41598-025-97890-8

Cooperative Heterobimetallic CO<sub>2</sub> Activation Involving a Mononuclear Aluminum(II) Intermediate

Journal of the American Chemical Society Roushan Prakash Singh, Kevin P. Quirion, Joshua Telser et al. Apr 16, 2025 DOI: 10.1021/jacs.5c00944

Hydroseismograms at Gran Sasso aquifer, central Italy, for earthquake hydrology studies

Scientific Reports Domenico Isaya, Gaetano De Luca, Giuseppe Di Carlo et al. Apr 16, 2025 DOI: 10.1038/s41598-025-96113-4

Abstract The use of hydroseimograms (i.e., high frequency pore pressure monitoring in wells in rock) emerges as a promising tool for a better understanding of the physics underlying earthquakes, as well as for seismic activity monitoring and/or prediction. This study investigates the earthquake detection capability of a hydraulic pressure device (HPD) installed in the Gran Sasso aquifer (GSA), Italy. The HPD, located in boreholes S13 and S14, near the INGV seismic station, GIGS, monitors hydraulic pressure changes within the aquifer. We compared data from the HPD and from GIGS to assess the HPD’s ability to detect earthquakes. The analysis covered the period from May 2015 to December 2023. The HPD successfully identified 148 out of 1068 analyzed earthquakes. Compared to previous studies, our HPD displayed significantly higher sensitivity, particularly for crustal earthquakes. These HPD devices show distinctive features, such as deep location, high frequency sampling (20 Hz), and hosting wells intercepting the main fault network. The unique location of the HPD, combined with its sensitivity to seismic events, makes it a valuable tool for continuous monitoring of earthquake activity, coupled with pore pressure trends and anomalies, in the region. These results confirm the potential of the HPD system for earthquake detection within the GSA. Future studies will continue to evaluate the HPD’s capabilities and its role in earthquake hazard assessment, as well as its potential use in other areas worldwide.

Characterization of the Biosynthesis of Pimprinine-Type Indolyloxazoles Unravels an Unusual <scp>d</scp>-Configurational Substrate Metabolic Streamline

Journal of the American Chemical Society Yuyang Zhang, Yanni Zhao, Ningning Wang et al. Apr 16, 2025 DOI: 10.1021/jacs.5c01705

Transmissibility of a new Plasmodium falciparum 3D7 bank for use in malaria volunteer infection studies evaluating transmission blocking interventions

Scientific Reports Sean A. Lynch, Azrin N. Abd-Rahman, Jenny M. Peters et al. Apr 16, 2025 DOI: 10.1038/s41598-025-97282-y

Few-Atom Copper Cluster Facilitates H<sub>2</sub>O<sub>2</sub> Activation to Promote Selective Oxidation of Benzene to Phenol

Journal of the American Chemical Society Ting Zhang, Haishan Su, Xianwen Zhang et al. Apr 16, 2025 DOI: 10.1021/jacs.5c00340

Influence of tillage methods on transplanter performance with different transplanting mechanisms

Scientific Reports Hakdan Aytem, Davut Karayel, Egidijus Šarauskis Apr 16, 2025 DOI: 10.1038/s41598-025-98146-1

Low serum neopterin early indicates durable benefits of atezolizumab and pembrolizumab therapy in advanced lung cancer

Scientific Reports Anna Siemiątkowska, Barbara Kuźnar-Kamińska, Maciej Bryl et al. Apr 16, 2025 DOI: 10.1038/s41598-025-97792-9

Phenothiazine Sulfoxides as Active Photocatalysts for the Synthesis of γ-Lactones

Journal of the American Chemical Society Niklas Hölter, Nils H. Rendel, Leander Spierling et al. Apr 16, 2025 DOI: 10.1021/jacs.5c01988

Metal-Based Approaches for the Fight against Antimicrobial Resistance: Mechanisms, Opportunities, and Challenges

Journal of the American Chemical Society Chenyuan Wang, Xueying Wei, Liang Zhong et al. Apr 16, 2025 DOI: 10.1021/jacs.4c16035

AJUBA promotes the proliferation, invasion and migration of NSCLC cells by activating the ERK/β-catenin pathway

Scientific Reports Lianyue Qu, Fan Wang, Yuxiang Wang et al. Apr 16, 2025 DOI: 10.1038/s41598-025-98156-z

Abstract Accumulating evidence indicates that AJUBA acts as a potential target for new therapeutics to treat cancers. Nevertheless, the role of AJUBA in non-small cell lung cancer (NSCLC) remains unclear. In the current study, immunohistochemistry (IHC) showed that expression of AJUBA was upregulated in 67.55% of NSCLC tumor samples and was associated with tumor size, lymph node metastasis, advanced tumor stage, poor differentiation and poor prognosis. Loss-of-function assays of AJUBA produced by silencing RNA (siAJUBA) significantly inhibited the proliferation, invasion and migration of H1299 and A549 cell lines. Mechanistically, inhibition of extracellular signal-regulated kinases (ERKs) blocked the AJUBA-induced proliferation, invasion and migration of NSCLC cells, and decreased the expression of proteins related to the endothelial-mesenchymal transition (EMT). Silencing of AJUBA repressed tumor growth and led to a decrease in p-ERK, β-catenin and N-cadherin in vivo. In conclusion,, overexpression of AJUBA facilitates the proliferation and motility of NSCLC cells via the ERK and Wnt/β-catenin pathways. AJUBA may be useful as a prognostic marker which may provide a promising approach for the treatment of NSCLC.

Unraveling the Roles of Amines in Atom Transfer Radical Polymerization in the Dark

Journal of the American Chemical Society Arman Moini Jazani, Gorkem Yilmaz, Mitchell Baumer et al. Apr 16, 2025 DOI: 10.1021/jacs.4c18496

Enhanced aquila optimizer for global optimization and data clustering

Scientific Reports Laith Abualigah, Saleh Ali Alomari, Mohammad H. Almomani et al. Apr 16, 2025 DOI: 10.1038/s41598-025-95888-w

Abstract The Aquila Optimizer (AO) is a newly proposed, highly capable metaheuristic algorithm based on the hunting and search behavior of the Aquila bird. However, the AO faces some challenges when dealing with high-dimensional optimization problems due to its narrow exploration capabilities and a tendency to converge prematurely to local optima, which can decrease its performance in complex scenarios. This paper presents a modified form of the previously proposed AO, the Locality Opposition-Based Learning Aquila Optimizer (LOBLAO), aimed at resolving such issues and improving the performance of tasks related to global optimization and data clustering in particular. The proposed LOBLAO incorporates two key advancements: the Opposition-Based Learning (OBL) strategy, which enhances solution diversity and balances exploration and exploitation, and the Mutation Search Strategy (MSS), which mitigates the risk of local optima and ensures robust exploration of the search space. Comprehensive experiments on benchmark test functions and data clustering problems demonstrate the efficacy of LOBLAO. The results reveal that LOBLAO outperforms the original AO and several state-of-the-art optimization algorithms, showcasing superior performance in tackling high-dimensional datasets. In particular, LOBLAO achieved the best average ranking of 1.625 across multiple clustering problems, underscoring its robustness and versatility. These findings highlight the significant potential of LOBLAO to solve diverse and challenging optimization problems, establishing it as a valuable tool for researchers and practitioners.

AI-driven energy management system based on hesitant bipolar complex fuzzy Hamacher power aggregation operators and their applications in MADM

Scientific Reports Walid Emam, Hafiz Muhammad Waqas, Tahir Mahmood et al. Apr 16, 2025 DOI: 10.1038/s41598-025-94340-3

In Situ Neutron Reflectometry Reveals the Interfacial Microenvironment Driving Electrochemical Ammonia Synthesis

Journal of the American Chemical Society Valerie A. Niemann, Mathieu Doucet, Peter Benedek et al. Apr 16, 2025 DOI: 10.1021/jacs.4c16636

MC4-R variant confirms its association with obesity during progression from childhood to adolescence

Scientific Reports Angelika Mohn, Armando Di Ludovico, Nella Polidori et al. Apr 16, 2025 DOI: 10.1038/s41598-025-96408-6

Excess Cations Alter *CO Intermediate Configuration and Product Selectivity of Cu in Acidic Electrochemical CO<sub>2</sub> Reduction Reaction

Journal of the American Chemical Society Suhwan Yoo, Sejin Park, Jihoon Son et al. Apr 16, 2025 DOI: 10.1021/jacs.5c02954

Defining the genetics of the widely used G3 strain of the mosquito, Anopheles gambiae

Scientific Reports Melina Campos, Marc Crepeau, Gregory C. Lanzaro Apr 16, 2025 DOI: 10.1038/s41598-025-96391-y

Abstract Mosquito species in the Anopheles gambiae complex have been referred to as “the deadliest animals in the world” due to their role as vectors of malaria throughout sub-Saharan Africa. Consequently, An. gambiae was among the first species to have its whole genome sequenced in 2002 and it continues to be the subject of intense study. An. gambiae is one member of a nine member species complex and, along with its sister species, An. coluzzii, is among the most important vectors of human malaria. Laboratory research on malaria vectors across a broad range of disciplines utilizes a strain known as G3, which was established in 1975 from mosquitoes collected from McCarthy Island, The Gambia. This strain is well known to be a mongrel strain, nonetheless it is often referred to as An. gambiae, which it is not. The issue with G3 goes far beyond the typical inbreeding associated with long-standing laboratory colonies. G3 is an An. gambiae/An. coluzzii interspecific hybrid. Although these two species are known to hybridize in nature, the pattern of interspecific introgression in G3 we describe in this paper is unlike any observed in natural populations. In this report we provide an in-depth analysis of the genetics of the G3 strain and compare it with natural populations of its two parental species. We discuss potential concerns that results obtained from research using the G3 strain may not apply to populations of these mosquito species as they occur in nature.

Chiral Lewis Acid-Catalyzed Intramolecular [2 + 2] Photocycloaddition: Enantioselective Synthesis of Azaarene-Functionalized Azabicyclo[2.1.1]hexanes and Bicyclo[1.1.1]pentanes

Journal of the American Chemical Society Dong Tian, Yixing Pan, Xiaowei Zhao et al. Apr 16, 2025 DOI: 10.1021/jacs.5c03542