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Mass Transport-Dependent C–C Bond Formation for CO Electroreduction with Alkali Cations

Journal of the American Chemical Society Wen Yan, Tiantian Wu, Jia Liu et al. Mar 19, 2025 DOI: 10.1021/jacs.5c01464

The association between body mass index and asthma in children: a cross‑sectional study from NHANES 1999 to 2020

Scientific Reports Cuiyun Fang, Zhongli Jiang, Xiaoxue Su et al. Mar 19, 2025 DOI: 10.1038/s41598-025-92619-z

Coherent Vibrational Dynamics in an Isolated Peptide Captured with Two-Dimensional Infrared Spectroscopy

Journal of the American Chemical Society Zifan Ma, Laura M. McCaslin, Joseph A. Fournier Mar 19, 2025 DOI: 10.1021/jacs.4c17464

Comprehensive analysis of senescence-related genes identifies prognostic clusters with distinct characteristics in glioma

Scientific Reports Wenyuan Wei, Ying Dang, Gang Chen et al. Mar 19, 2025 DOI: 10.1038/s41598-025-93482-8

C–C Cleavage/Cross-Coupling Approach for the Modular Synthesis of Medium-to-Large Sized Rings: Total Synthesis of Resorcylic Acid Lactone Natural Products

Journal of the American Chemical Society Lucas T. Göttemann, Charis Amber, Khalid Mahmood et al. Mar 19, 2025 DOI: 10.1021/jacs.5c00801

Leaf rust resistance in wheat and interpretation of the antifungal activity of silver and copper nanoparticles

Scientific Reports Atwa A. Atwa, Shreen S. Ahmed, Gehan H. Abd El-Aziz et al. Mar 19, 2025 DOI: 10.1038/s41598-025-91127-4

Abstract Wheat production is jeopardized by Puccinia triticina, the pathogen responsible for wheat leaf rust. This study assessed the impact of silver (Ag) and copper (Cu) nanoparticles (NPs) on the control of wheat leaf rust disease and the underlying mechanisms of disease resistance. The application of the two nanoparticles resulted in a reduction of spore germination and an extension of both incubation and latent periods. A common type of infection resulted in a reduction in both the length and width of pustules. It reduced receptivity value (number of pustule cm2) compared to untreated wheat plants by altering the physiological and biochemical responses of wheat plants and cell walls’ physical and mechanical strength. The application of Ag + Cu NPs stimulates the biosynthesis of defense-related molecules crucial for P. triticina inoculation and latent periods. Furthermore, molecular docking studies were conducted to assess the effects of Cu-chitosan nanoparticles (Ag & CuNp) and their mechanisms in disease management.

Less-Dominant Resonance Configuration of Propargyl Radical Leads to a Growth Mechanism for Polycyclic Aromatic Hydrocarbons that Preserves the Cyclopenta Ring

Journal of the American Chemical Society Jinyang Zhang, Jiao Gao, Hong Wang et al. Mar 19, 2025 DOI: 10.1021/jacs.4c15155

Assessment of surface sediment properties and heavy metal contamination in typical urban areas of the Yellow River, China

Scientific Reports Junzhang Wang, Ling Tao, Hanru Ren et al. Mar 19, 2025 DOI: 10.1038/s41598-025-87503-9

Structure and pH Dependence of Membranolytic Mechanisms by Truncated Oxidized Phospholipids

Journal of the American Chemical Society Min Xie, Maik G. N. Derks, Eveline H. W. Koch et al. Mar 19, 2025 DOI: 10.1021/jacs.4c12543

Investigation of risk-aware dynamic accident monitoring and early warning technologies for chemical production processes

Scientific Reports Chen Lv, Xiaolu Wang, Sheng Xue et al. Mar 19, 2025 DOI: 10.1038/s41598-025-93880-y

Off-Equilibrium Hydrothermal Synthesis of High-Entropy Alloy Nanoparticles

Journal of the American Chemical Society Zhixue Zhang, Peiping Yu, Zhaojun Liu et al. Mar 19, 2025 DOI: 10.1021/jacs.4c17756

Author Correction: Complete chloroplast genomes of 13 species of the Impatiens genus for genomic features and phylogenetic relationships studies

Scientific Reports Qinqin Yong, Meijun Li, Zhi Li et al. Mar 19, 2025 DOI: 10.1038/s41598-025-94281-x

Solution Synthesis of Single Crystalline Zinc Nanowires

Journal of the American Chemical Society Dasai Ban, Mingtao Chen, Fan Guo et al. Mar 19, 2025 DOI: 10.1021/jacs.4c18640

Dynamic sealing simulation and performance optimization of conical rubber core in rotary blowout preventer

Scientific Reports Lianglin Guo, Zhiqiang Huang, Hao Huang et al. Mar 19, 2025 DOI: 10.1038/s41598-025-86462-5

Impact of Reaction Environment on Photogenerated Charge Transfer Demonstrated by Sequential Imaging

Journal of the American Chemical Society Qian Li, Chenwei Ni, Junhao Cui et al. Mar 19, 2025 DOI: 10.1021/jacs.4c10300

Insights into GLP-1 and insulin secretion mechanisms in pasireotide-induced hyperglycemia highlight effectiveness of Gs-targeting diabetes treatment

Scientific Reports Junichiro SATO, Katsunori MANAKA, Hirofumi HORIKOSHI et al. Mar 19, 2025 DOI: 10.1038/s41598-025-90896-2

Design of thin, wideband electromagnetic absorbers with polarization and angle insensitivity using deep learning

Scientific Reports Atefe Shahsavaripour, Mohammad Hossein Badiei, Ahmad Kalhor et al. Mar 19, 2025 DOI: 10.1038/s41598-025-94116-9

Abstract Metamaterial-based electromagnetic absorbers, despite being thin and lightweight, typically suffer from narrow-band frequency bandwidth and sensitivity to polarization and incident angle due to their resonant nature. Previous methods to increase bandwidth have shown improvements but have not fully succeeded in developing wide-band, thin metamaterial-based absorbers suitable for mass production. In this study, we introduce a novel approach that leverages artificial intelligence to design a thin, wideband metamaterial-based absorber covering the entire frequency range of 8-12 GHz. The proposed method utilizes a Generative Adversarial Network (GAN), given the need for precise structural details and computational efficiency, which globally outperform variational autoencoders (VAEs) and diffusion models, for parameter estimation and a Multi-Layer Perceptron (MLP) network as a simulator to predict the electromagnetic response of the designed absorber and provide feedback to the generative network. Numerical full-wave electromagnetic simulations serve as the training data and ground truth for both the GAN and MLP networks. This training enables the generative network to produce structures with high absorption, while the MLP predicts the corresponding absorbance value for each structure. This approach allows for the rapid design of various real-world structures, quick calculation of their absorption values using the MLP network, and selection of the most optimal structures for fabrication. The performance of the designed metamaterial-based absorber is verified both numerically and experimentally. Results show an absorption rate above 90% for all frequencies in the range of 8-12 GHz. The structure also operates effectively for both TE and TM polarizations and for all incident angles between 0-45 degrees. Additionally, the designed structure can be easily fabricated using printed circuit board (PCB) technology, making it practical and suitable for mass production.

Importance of the Ferryl Quintet State in Determining the Electronic Properties of P450 Compound I

Journal of the American Chemical Society Elizabeth L. Onderko, Mackenzie J. Field, Alexey Silakov et al. Mar 19, 2025 DOI: 10.1021/jacs.4c11688

Predicting intra-abdominal hypertension using anthropometric measurements and machine learning

Scientific Reports Salar Tayebi, Rob Wise, Niels Van Regenmortel et al. Mar 19, 2025 DOI: 10.1038/s41598-025-93823-7

High-Energy Density Li-Ion Battery Cathode Using Only Industrial Elements

Journal of the American Chemical Society Eshaan S. Patheria, Pedro Guzman, Leah S. Soldner et al. Mar 19, 2025 DOI: 10.1021/jacs.4c18440