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Stiboviologens-Decorated Sb <sub>4</sub> O <sub>6</sub> Clusters for Electrocatalytic Proton Reduction via Coupled Electron Sponge and Proton Engine

Journal of the American Chemical Society Liang Xu, Jianyue He, Yi Qiao et al. Oct 29, 2025 DOI: 10.1021/jacs.5c13539

Non-adherence with the treatment regimen and its associated factors among patients with schizophrenia in Sub-Saharan Africa: a systematic review and meta-analysis

Scientific Reports Zenaw Debasu Addisu, Desalegn Getnet Demsie, Chernet Tafere et al. Oct 29, 2025 DOI: 10.1038/s41598-025-21647-6

Interstellar Formation of the Elusive Phosphanyloxyphosphane (H <sub>2</sub> POPH <sub>2</sub> ) and Phosphanylphosphinous Acid (H <sub>2</sub> PPHOH) via Nonequilibrium Chemistry: Precursors to the Phosphate Backbone of Nucleotides

Journal of the American Chemical Society Jia Wang, Bing-Jian Sun, Alexandre Bergantini et al. Oct 29, 2025 DOI: 10.1021/jacs.5c12481

Self-balanced switched capacitors based thirteen level three-fold multilevel inverter for solar PV applications

Scientific Reports Niraj Kumar Dewangan, Kasinath Jena, Tarun Kumar Tailor et al. Oct 29, 2025 DOI: 10.1038/s41598-025-21760-6

Abstract While the conventional topologies of multilevel inverters (MLIs) operate with unity voltage gain, switched capacitors-based MLIs (SCMLIs) offer a solution to realize an inherent voltage gain of more than one, thereby stepping up the voltage in the process of DC to AC conversion. This work proposes a novel SCMLI constituting thirteen levels, requiring only one DC input and 3-capacitors to achieve an inclusive three-fold gain in voltage. The number of power switches employed in the proposed module is thirteen, where nine switches peak-inverse-voltage (PIV) is considered as one-third of the output voltage amplitude. Experimental results validate the proposed inverter (PI), demonstrating its efficacy. The superior performance of the PI with respect to component count, power switch voltage ratings, and cost function (CF) is highlighted by comparison with other SCMLIs. The total standing voltage (TSV) per level, expressed in per unit with respect to $${V}_{in}$$ is 1.307, while the PIV per level is 0.153, which is competitive with recent literature. Additionally, the CF is 4.538, lower than other designs, enhancing the performance of the structure for real-time applications.

SCBM-Net: a multimodal feature fusion-based dual-channel method for bearing fault diagnosis

Scientific Reports Qiang Liu, Weiyan Tong, Hongwei Bai et al. Oct 29, 2025 DOI: 10.1038/s41598-025-21665-4

Efficient and Selective Photocatalytic Conversion of Low-Concentration CO <sub>2</sub> to CO Using Mn-Complex Catalysts

Journal of the American Chemical Society Kei Kamogawa, Hiroki Koizumi, Osamu Ishitani Oct 29, 2025 DOI: 10.1021/jacs.5c10694

Proteome of seminal plasma and sperm associated with sperm survival following cryopreservation in the Red Wolf (Canis rufus)

Scientific Reports Jasmin J. Celedon, Molly L. Corder, Meghann McConnell et al. Oct 29, 2025 DOI: 10.1038/s41598-025-21778-w

Abstract Understanding of the impacts of seminal plasma and sperm proteins on both animal and human fertility has expanded rapidly in the last decade. However, little is known about the reproductive proteomes of endangered species. In this study, we characterized for the first time the seminal plasma and sperm proteomes of the critically endangered Red Wolf and evaluated differences in proteomic signatures between ejaculates which experienced “High” versus “Baseline” ( i.e . population average) sperm cryo-resilience. Highly cryo-resilient ejaculates (High_CR, n  = 5) maintained &gt; 50% sperm total motility relative to fresh samples following cryopreservation and post-thaw incubation, as well as acrosome integrity post-thaw. These samples had significantly higher expression of A1BG, APBB1, KRT1, KRT10, LOC609402 and LOC100685620 (AGP) proteins in seminal plasma, and significantly reduced expression of RHOA, NUP62, SMYD4, ARHGD1B, CAPG, CSTB, and CFL1 proteins in sperm compared with Baseline cryo-resilient samples (Base_CR, n  = 5). Differences in protein expression indicated that alterations in physiological pathways including blood clotting cascades (seminal plasma) and both actin dynamics and immune pathways (sperm) are associated with sperm cryo-resilience. This new knowledge may prove useful in future optimization of semen cryopreservation and assisted reproductive technologies for the critically endangered Red Wolf.

Mechanistic Insights into Nitroarene Hydrogenation Dynamics on Pt(111) via <i>In Situ</i> Tip-Enhanced Raman Spectroscopy

Journal of the American Chemical Society Zhen-Feng Cai, Meghna A. Manae, Zi-Xi Tang et al. Oct 29, 2025 DOI: 10.1021/jacs.5c14338

Exogenous phosphatidylserine protects against mesenteric ischemia-reperfusion with associated Akt/mTOR pathway upregulation

Scientific Reports Amirabbas Mohammadi Hamaneh, Moein Ghasemi, Mohammad Mahdi Mehrabi et al. Oct 29, 2025 DOI: 10.1038/s41598-025-21750-8

Pt Particles on a Dynamic TiO <sub>2</sub> Support in Near-Ambient Conditions–Disentangling Size, Pressure, and Support Effects

Journal of the American Chemical Society Florian Kraushofer, Matthias Krinninger, Marina de la Higuera-Domingo et al. Oct 29, 2025 DOI: 10.1021/jacs.5c14353

Band level similarity reduction and deep dual signal fusion for reliable diagnosis of power insulator defects

Scientific Reports Mohamed Islam Bentaleb, Tao Zhang, Yanzhang Geng et al. Oct 29, 2025 DOI: 10.1038/s41598-025-21674-3

Hydrogen Bond Reconstruction Maneuver in Eutectic Electrolyte Enables Ultralong-Lifespan Zinc-Ion Batteries

Journal of the American Chemical Society Xuemei Zhang, Qiang Tang, Hang Luo et al. Oct 29, 2025 DOI: 10.1021/jacs.5c12021

Applicability of phase 3 trial selection criteria to real-world transthyretin amyloid cardiomyopathy patients

Scientific Reports Michael Poledniczek, Lena Marie Schmid, Christina Kronberger et al. Oct 29, 2025 DOI: 10.1038/s41598-025-21779-9

Boosting the Brightness of Covalent Organic Frameworks by Integration of Dual-Docking Luminogens with Aggregation-Induced Emission Effect

Journal of the American Chemical Society Liang Zhang, Weihang Geng, Xinwen Ou et al. Oct 29, 2025 DOI: 10.1021/jacs.5c16217

Exploring the electrocatalytic potential of CdTiO3 for sustainable overall water splitting

Scientific Reports Eshagh Irandoost, Neda Sadat Barekati, Hossein Farsi et al. Oct 29, 2025 DOI: 10.1038/s41598-025-11358-3

Multiconfigurational Ground State of a Diradicaloid Characterized at the Atomic Scale

Journal of the American Chemical Society Elia Turco, Lara Tejerina, Gonçalo Catarina et al. Oct 29, 2025 DOI: 10.1021/jacs.5c13039

Factors influencing the intention to use telemedicine services among older adults in China

Scientific Reports Huiqian He, Raja Ariffin Raja Ghazilla, Salwa Hanim Abdul‑Rashid Oct 29, 2025 DOI: 10.1038/s41598-025-14630-8

Catalytic Enantioselective Perezone-Type [5 + 2] Cycloaddition

Journal of the American Chemical Society Liangliang Yang, Chaoshen Zhang, Jianwei Sun Oct 29, 2025 DOI: 10.1021/jacs.5c14484

Digital slit lamp derived parameters in shallow anterior chamber screening

Scientific Reports Jiahui Zhao, Xingru He, Guangzheng Dai et al. Oct 29, 2025 DOI: 10.1038/s41598-025-21781-1

Two Flavoenzymes Convert Fungal Polyketide-Nonribosomal Peptide to <i>cis</i> -2-Butene-1,4-dial-Type Carcinogen via Olefin Dihydroxylation and C–C Bond Cleavage

Journal of the American Chemical Society Jin-Mei Zhang, Guan-Yin Yuan, Min-Xiu Shi et al. Oct 29, 2025 DOI: 10.1021/jacs.5c11221