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Enzymatic tailoring of anionic glycans for characterizing lectin and antibody specificities in a microarray format
A pilot study on the prevalence and patterns of haemoglobinopathies in Datia District, Madhya Pradesh, India
Substrate recognition by the human mitochondrial processing peptidase and its processing of PINK1
Decision support model for blockchain adoption using EDAS technique in the complex q-rung orthopair fuzzy structure
Visible‐Light‐Induced [2π+2σ] Cycloaddition Enabled by Cage‐Confined Photocatalysis for Precise Bicyclo[2.1.1]Hexane Construction
Abstract We disclose a visible‐light‐induced, diastereoselective [2π+2σ] photocycloaddition between readily available chalcones and 1,3‐disubstituted bicyclo[1.1.0]butanes (BCBs) promoted by photoactive metal–organic cage (PMOC). This confined supramolecular catalysis method enables efficient synthesis of pharmaceutically relevant bicyclo[2.1.1]hexane (BCH) bioisosteres with remarkable atom economy and excellent diastereoselectivities, necessitating only 0.1 mol% catalyst loading. The success of this organic transformation arises from the synergistic action of the PMOC as a nanoreactor to combine selective substrate preorganization through host–guest interactions, efficient Ru(II)‐mediated triplet energy transfer, and nano‐spatial confinement effect that precisely control [2π+2σ] cyclization geometry while preventing competitive homodimerization.
StayRose: A photostable StayGold derivative redshifted by genetic code expansion
Topographic correction for ground penetrating radar for enhanced detection of dike subsurface anomalies
Prognostic and immunological potential of AC012236.1/hsa-miR-30d-5p CeRNA of AVEN by integrated analysis of single-cell and bulk RNA-seq in lung adenocarcinoma
Postoperative radiotherapy for ductal carcinoma in situ: survival prediction and clinical decision support using a nomogram-based approach
Statistical Sampling‐Driven Design for Supported Bimetallic Nanocatalysts for CO <sub>2</sub> Reduction
Abstract Tailoring supported bimetals to alloyed or phase‐separated structures is of vital importance while this process is blocked by the support interferences during universal impregnation processes. Conventional trial‐and‐error approaches rooted in chemical intuition often lack efficiency and generality. Here, we present a design strategy guided by the statistical sampling of comparative ease of alloy formation through the metadynamics‐based gas–solid nanoreactor approach, which enables the rational and systematic development of bimetallic nanocatalysts (NCs). Using metal oxide‐supported PdAu coupling with model CO 2 reduction as a proof‐of‐concept system, the integrated theoretical and experimental results not only validated the reliability of simulation results but also successfully predicted and realized the alloy formation or phase separation of supported PdAu NCs. The generated PdAu alloys over CeO 2 weaken the metallicity of supported Pd species and thus the catalytic hydrogenation property, but increase moderate basicity, contributing to activated CO 2 hydrogenation to CO via a formate intermediate. However, the phase separation of Pd and Au over TiO 2 support promotes formic acid production efficiency attributed to increasing weak basicity to accelerate CO 2 activation during a bicarbonate pathway. These findings highlight statistical sampling as a general broadly applicable framework for the rational design of advanced bimetallic NCs.
Development of functional meat products based on the food safety system
The 23 <sup>rd</sup> European Symposium on Organic Chemistry (ESOC‐2025) in Copenhagen
Abstract The 23 rd in the series of “European Symposium on Organic Chemistry” (ESOC) was held at Tivoli Congress Center in Copenhagen from June 29 th to July 3 rd of 2025. ESOC was held for the first time in Cologne, Germany, in 1979, and has since been held approximately every other year. This year, Christian Marcus Pedersen and Michael Pittelkow from the Department of Chemistry at the University of Copenhagen hosted the event, and there were 619 registered participants from 49 countries. There were 13 plenary lectures, 13 invited lectures, and 21 “oral communications” that had been selected on the basis of applications. There were two poster sessions with a total of 350 posters. A total of six poster prizes were awarded, two awarded by the attendees via the app and four awarded by the poster prize committee. Among the total of 47 lectures, the “Patai‐Rappoport lecture award” was presented by Eric Jacobsen from Harvard University, “Dr. The Margaret Faul Women in Chemistry award” lectures given by Franziska Schoenebeck from Aachen University (Academia Award), and Dani Schultz from Merck (Industry Award). EuChemS awarded the “Award for research 2024” to Ilan Marek from Technion and the ‘Young investigator award 2024′ to Aurélien de la Torre from d'Orsay. The EuChemS Award for ‘Award for service 2024′ was awarded to Berit Olofsson from Stockholm University.
Desalination of seawater via the freeze-thaw method based on density functional theory
Aggregation‐Enhanced‐Emission Polymer Donor Improves the Efficiency of Organic Solar Cells by Suppressing Nonradiative Recombination
Abstract Nonradiative voltage loss (Δ V nr ) is a critical factor that limits the efficiency of organic solar cells (OSCs). Introducing highly luminescent materials is a promising approach to reduce Δ V nr . The majority of prior works have focused on enhancing luminescence of low‐bandgap nonfullerene acceptors, whereas highly luminescent donors have received far less attention. Herein, we designed and synthesized a highly luminescent polymer donor with aggregation‐enhanced emission property, namely PiNTSO‐F, and incorporated it into PM6:BTP‐eC9‐based system. Interestingly, PiNTSO‐F was found to locate at the donor–acceptor interface, where it optimizes the interfacial morphology, energetic landscape, and charge dynamics of the active layer. Consequently, the nonradiative recombination rate in the ternary system is significantly reduced, while the interfacial charge generation efficiency is simultaneously improved to nearly unity, effectively minimizing Δ V nr of the device. As a result, the ternary devices achieve a low Δ V nr of 0.192 V and a high efficiency of 20.36%. This work demonstrates an effective strategy for suppressing Δ V nr through developing the highly luminescent polymer donors as a third component, providing mechanistic insights that enable high‐performance OSCs with minimized voltage loss.