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The Binding of Cu<sup>2+</sup> to Lipid Membranes Is Not Substantially Influenced by Electrostatic Screening

Journal of the American Chemical Society Christopher M. Reynolds, Olivia C. Fiebig, Alexa Marroquin et al. Mar 12, 2025 DOI: 10.1021/jacs.4c16066

Asymmetric Counteranion-Directed Halogen Bonding Catalysis

Journal of the American Chemical Society Dominik L. Reinhard, Anna Iniutina, Sven Reese et al. Mar 12, 2025 DOI: 10.1021/jacs.4c18378

The Temporal Organization of Learned Vocal Behavior Is Predicted by Species Rather Than Experience

Journal of Neuroscience Jacob A. Edwards, Moises Rivera, Sarah M. N. Woolley Mar 12, 2025 DOI: 10.1523/jneurosci.0576-24.2025

Birdsong is hierarchically organized in time, like speech and other communication behaviors. Syllables are produced in sequences to form song motifs and bouts. While syllables are copied from tutors, the factors that determine song temporal organization, including syllable sequencing (syntax), are unknown. Here, we tested the roles of learning and species genetics in song organization. We manipulated juvenile song experience and genetics in three species of estrildid finches (zebra finches, Taeniopygia guttata castanotis ; long-tailed finches, Poephila acuticauda ; Bengalese finches, Lonchura striata var. domestica ). We analyzed the adult songs of male birds that were: (1) tutored by conspecifics; (2) untutored; (3) tutored by heterospecifics; and (4) genetic hybrids. Song macrostructure, syllable sequencing, and syllable timing were quantified and compared within and across species. Results showed that song organization was consistent within a species and differed across species, regardless of experience. Temporal features did not differ between tutored and untutored birds of the same species. The songs of birds tutored by other species were composed of heterospecific syllables produced in sequences typical of conspecific songs. The songs of genetic hybrids showed the organization of both parental species, despite the fact that only males sing. Results indicate that song organization is predicted by species rather than experience.

An archaic European face more than one million years old

Nature Mar 12, 2025 DOI: 10.1038/d41586-025-00678-z

Tracking the Fate of Therapeutic Proteins Using Ratiometric Imaging of Responsive Shortwave Infrared Probes

Journal of the American Chemical Society Pradeep Shrestha, Nimit L. Patel, Joseph D. Kalen et al. Mar 12, 2025 DOI: 10.1021/jacs.4c15614

Fungal RiPPs Side Chain Macrocyclization Catalyzed by Copper-Dependent DUF3328 Enzyme

Journal of the American Chemical Society Chen-Yu Chiang, Masao Ohashi, Yi Tang Mar 12, 2025 DOI: 10.1021/jacs.4c18770

Kinetics Compensation Mechanism in Cosolvent Electrolyte Strategy for Aqueous Zinc Batteries

Journal of the American Chemical Society Jianlong Cong, Yueda Wang, Xing Lin et al. Mar 12, 2025 DOI: 10.1021/jacs.4c16880

Fresh ‘quantum advantage’ claim made by computing firm D-Wave

Nature Davide Castelvecchi Mar 12, 2025 DOI: 10.1038/d41586-025-00765-1

Watch DeepMind’s AI robot slam-dunk a basketball

Nature Elizabeth Gibney Mar 12, 2025 DOI: 10.1038/d41586-025-00777-x

Pd-Catalyzed Strain-Releasing Dyotropic Rearrangement: Ring-Expanding Amidofluorination of Methylenecyclobutanes

Journal of the American Chemical Society Baochao Yang, Guoqiang Yang, Qian Wang et al. Mar 12, 2025 DOI: 10.1021/jacs.5c01108

Revealing the Relationship between Publication Bias and Chemical Reactivity with Contrastive Learning

Journal of the American Chemical Society Wenhao Gao, Priyanka Raghavan, Ron Shprints et al. Mar 12, 2025 DOI: 10.1021/jacs.5c01120

Efficient Metabolomics Profiling from Plasma Extracellular Vesicles Enables Accurate Diagnosis of Early Gastric Cancer

Journal of the American Chemical Society Fanqin Bu, Xinyi Shen, Haosu Zhan et al. Mar 12, 2025 DOI: 10.1021/jacs.4c18110

Sapphire anvils squeeze metals atomically-thin

Nature Benjamin Thompson, Shamini Bundell Mar 12, 2025 DOI: 10.1038/d41586-025-00776-y

Two Birds, One Stone: Microsecond Dark Excited-State Lifetime and Large Cage Escape Yield Afforded by an Iron–Anthracene Molecular Dyad

Journal of the American Chemical Society Felix Glaser, Simon De Kreijger, Ludovic Troian-Gautier Mar 12, 2025 DOI: 10.1021/jacs.4c17167

Ligand Influence on the Performance of Cesium Lead Bromide Perovskite Quantum Dots in Photocatalytic C(sp<sup>3</sup>)–H Bromination Reactions

Journal of the American Chemical Society Willi M. Amberg, Henry Lindner, Yesim Sahin et al. Mar 12, 2025 DOI: 10.1021/jacs.4c17013

High Entropy Oxide-Polyoxometalate Sub-1 nm Hetero-Nanowires as Cathode Catalysts in Li–O<sub>2</sub> Batteries

Journal of the American Chemical Society Huaiyun Ge, Wenxiong Shi, Junli Liu et al. Mar 12, 2025 DOI: 10.1021/jacs.4c15979

Single-Handed Helical Polymer-Based Polycarboxylate with Achiral Triarylphosphine Pendants as Chiral Catalysts for Asymmetric Cross-Coupling Reactions in Pure Water

Journal of the American Chemical Society Naoaki Kamiya, Takuma Kuroda, Yuuya Nagata et al. Mar 12, 2025 DOI: 10.1021/jacs.4c16952

Interfacing Flexible Design and Social Self-Sorting Enables Comprehensive Control over Photophysical and Self-Assembly Properties of Supramolecular Polymers

Journal of the American Chemical Society Nils Bäumer, Saeko Yamada, Soichiro Ogi et al. Mar 12, 2025 DOI: 10.1021/jacs.4c15766

Characterizing Olfactory Brain Responses in Young Infants

Journal of Neuroscience Laura K. Shanahan, Leena B. Mithal, Marci Messina et al. Mar 12, 2025 DOI: 10.1523/jneurosci.1780-24.2025

Odor perception plays a critical role in early human development, but the underlying neural mechanisms are not fully understood. To investigate these, we presented appetitive and aversive odors to infants of both sexes at 1 month of age while recording functional magnetic resonance imaging (fMRI) and nasal airflow data. Infants slept during odor presentation to allow MRI scanning. We found that odors evoke robust fMRI activity in the bilateral olfactory cortex and thalamus and that fMRI response magnitudes in the olfactory cortex differ across odors. However, in contrast to prior work in adults, we did not find compelling evidence that odor stimuli evoke discriminable fMRI activity patterns in the olfactory cortex or thalamus using two different multivariate pattern analysis techniques. Finally, the average inhale airflow rate was higher for appetitive odors than aversive odors, which tentatively suggests that infants could modulate their respiration to reflect odor valence. Overall, these results show strong neural responses to odors at this early developmental stage and highlight nasal airflow as a behavioral metric for assessing odor preference in infants.

Medical records from the Center for the Study of Temporal Disorders, Pediatric Department

Nature Diana Peterfreund Mar 12, 2025 DOI: 10.1038/d41586-025-00626-x