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Synthesis of Telechelic Isotactic Polypropylenes for Circular Polypropylene-like Materials via Chain Transfer Polymerization

Journal of the American Chemical Society Zonglun Yu, Xing-Wang Han, Peizhi Li et al. Feb 05, 2025 DOI: 10.1021/jacs.4c15910

New exact soliton wave solutions appear in optical fibers with Sardar sub equation and new auxiliary equation techniques

Scientific Reports Umair Asghar, Muhammad Imran Asjad, Yasser Salah Hamed et al. Feb 05, 2025 DOI: 10.1038/s41598-024-84651-2

Circular Polymer Designed by Regulating Entropy: Spiro-Valerolactone-Based Polyesters with High Gas Barriers and Adhesion Strength

Journal of the American Chemical Society Cui-Ting Han, Kai Ma, Zhen Zhang et al. Feb 05, 2025 DOI: 10.1021/jacs.4c16260

Assessing the effects of partially substituting chicken breast meat with oyster mushroom stalk powder on the quality attributes of mushroom-chicken burgers

Scientific Reports Sabah Mounir, Randa Mohamed, K. V. Sunooj et al. Feb 05, 2025 DOI: 10.1038/s41598-025-86127-3

Abstract This study aimed to evaluate the effect of a partial substitution of chicken breast meat with oyster mushroom stalk powder on the quality attributes of mushroom-chicken burgers. Chicken breast meat was substituted with oyster mushroom stalk powder at different levels ranging from 2.5 to 10%, with an interval increase of 2.5%. The substitution level had a significant effect on the different characteristics studied. A decrease in both crude protein and crude lipid was observed as the substitution level increased from 2.5 to 10%. However, a contradictory trend was observed for crude fiber, ash, carbohydrates, antioxidant properties, water-binding capacity, and browning index. The cooking loss and shrinkage were reduced by about 81.6% and 72.6%, respectively, for the formulation prepared with 10% compared to the control sample. The formulation prepared with 2.5% showed the lowest hardness, chewiness, and shear force, which increased as the substitution level increased to 10%. The oyster mushroom stalk powder can be used at a level ranging from 2.5 to 5% to substitute chicken breast meat in the preparation of healthier and more functional chicken burgers.

Folding and Functionalizing DNA Origami: A Versatile Approach Using a Reactive Polyamine

Journal of the American Chemical Society Alejandro Postigo, Carlos Marcuello, William Verstraeten et al. Feb 05, 2025 DOI: 10.1021/jacs.4c12637

Integrative analysis of 5-methylcytosine associated signature in papillary thyroid cancer

Scientific Reports Ying Ding, Xinying Li, Wenlong Wang et al. Feb 05, 2025 DOI: 10.1038/s41598-025-88657-2

Gold(I)-Catalyzed 2-Deoxy-β-glycosylation via 1,2-Alkyl/Arylthio Migration: Synthesis of Velutinoside A Pentasaccharide

Journal of the American Chemical Society Xianyang Wang, Han Ding, Aoxin Guo et al. Feb 05, 2025 DOI: 10.1021/jacs.4c15805

Cancer stem cell populations are resistant to 5-aminolevulinic acid-photodynamic therapy (5-ALA-PDT)

Scientific Reports Chantel P. J. Rice, Vipin Shankar Chelakkot, Noah T. Conohan et al. Feb 05, 2025 DOI: 10.1038/s41598-025-88173-3

Activation of Primary C–H Bonds in Oxidative Cyclizations of Tambjamines Catalyzed by Rieske Oxygenases TamC and <i>Pt</i> TamC

Journal of the American Chemical Society Manasa Ramachandra, Joshua L. M. Innis, Jian Yu et al. Feb 05, 2025 DOI: 10.1021/jacs.4c17468

Correlation of clinically significant prostate cancer sites across multiparametric MRI, prostate biopsy, and whole-mount pathology for optimal prostate biopsy strategy

Scientific Reports Matteo Pacini, Alessandro Zucchi, Riccardo Morganti et al. Feb 05, 2025 DOI: 10.1038/s41598-025-88463-w

Molecular Processes That Control Organic Electrosynthesis in Near-Electrode Microenvironments

Journal of the American Chemical Society Ricardo Mathison, Rasha Atwi, Hannah B. McConnell et al. Feb 05, 2025 DOI: 10.1021/jacs.4c14420

Constructing a machine learning model for systemic infection after kidney stone surgery based on CT values

Scientific Reports Jiaxin Li, Yao Du, Gaoming Huang et al. Feb 05, 2025 DOI: 10.1038/s41598-025-88704-y

Short and long-range magnetic ordering and emergent topological transition in (Mn1−xNix)2P2S6

Scientific Reports Nasaru Khan, Deepu Kumar, Shantanu Semwal et al. Feb 05, 2025 DOI: 10.1038/s41598-025-88586-0

Analysis of quality of life and periodontal health with an eight-unit maxillary fixed retainer through a prospective clinical trial

Scientific Reports Mohamed H. Abbas, Essam M. Abdalla, Nadia M. El Harouni et al. Feb 05, 2025 DOI: 10.1038/s41598-025-88309-5

Abstract Retention is crucial in orthodontics, aiming to preserve treatment outcomes and enhance patient satisfaction with permanent fixed retainers. However, a removable retainer may be needed with fixed retainers to prevent unwanted changes. An eight-unit extended fixed retainer is proposed to eliminate the need for a removable retainer, addressing the undesired changes associated with six-unit fixed retainers. The impact of extended retainers on periodontium and quality of life remains unexplored. This study evaluates the periodontal response and patient-reported quality of life with an eight-unit maxillary fixed retainer. A single-arm prospective clinical trial with only twenty-eight test group patients (6 males, 22 females) who finished active orthodontic treatment were recruited. The mean age was (19.8 ± 4.5 years). This research was approved by the institutional review board of the Faculty of Dentistry, Alexandria University (IORG:0008839, No-0479-8/2022). The registration date of this study was (5/06/2023). An eight-unit maxillary fixed retainer was bonded to the palatal surface of the maxillary incisors, canines, and first or second premolars directly after debonding the brackets. The periodontal assessment and quality of life were carried out through clinical examination and valid questionnaires and the patients were followed up for 12 months. The periodontal response improved significantly at 1-year follow-up. The Probing depth, Gingival index, Plaque index, Bleeding index, and mobility index were significantly lower in these patients. Quality of life was assessed by the OHIP-14. The mean score decreased by -1.86 (SD = 4.19), and the acceptance of the orthodontic appliance scale score increased by 0.68 (SD = 0.86), which was significant with a p-value &lt; 0.001. For 12 months of follow-up, an eight-unit maxillary retainer did not adversely affect the periodontal ligaments. meets patients’ expectations and maintains a high quality of life.

Probing the Influence of the Protein Scaffold on H-Cluster Reactivity via Gain-of-Function Studies─Improved H<sub>2</sub> Evolution and O<sub>2</sub> Tolerance through Rational Design of [FeFe] Hydrogenase

Journal of the American Chemical Society Princess R. Cabotaje, Alina Sekretareva, Moritz Senger et al. Feb 05, 2025 DOI: 10.1021/jacs.4c17364

Using the clustering method to find the final environmental parameters coefficients in road construction projects

Scientific Reports Eshagh Rasouli Sarabi, Ramin Vafaei Poursorkhabi, Mehdi Ravanshadnia Feb 05, 2025 DOI: 10.1038/s41598-025-88737-3

A Granzyme B-Cleavable T Cell-Targeted Bispecific Cell Vesicle Connector for Reversing New-Onset Type 1 Diabetes

Journal of the American Chemical Society Yanfang Wang, Yanping Sun, Xiuwen Zhang et al. Feb 05, 2025 DOI: 10.1021/jacs.4c13644

Differential resistance to nematode infection is associated with the genotype- and age-dependent pace of intestinal T cell homing

Scientific Reports Joshua Adjah, Bhavya Kapse, Hongwei Zhang et al. Feb 05, 2025 DOI: 10.1038/s41598-024-76204-4

Abstract The resistance of inbred mice to nematode infections varies depending on the extent of protective Th2 responses. Here, we compared two mouse lines differing in resistance to infection with the enteric nematode Heligmosomoides polygyrus bakeri despite the similar instruction of GATA-3+ T effector cells. Resistant BALB/c mice rapidly recruited high numbers of Th2 cells to the gut within the 1-week time frame required for larval development in the intestinal submucosa. C57BL/6 mice failed in the optimal control of early nematode fitness, with mucosal Th2 response peaking after 2 weeks when the larvae had left the tissue and relocated to the gut lumen as adult worms. The faster homing of Th2 cells to the gut of BALB/c mice is related to the extensive expression of the chemokine receptor CCR9 in GATA-3+ cells and higher frequencies of aldehyde dehydrogenase expressing dendritic cells present in mesenteric lymph nodes. Furthermore, nematode-infected older BALB/c mice displayed impaired resistance due to delayed mucosal homing of effector cells, which synergized with more numerous Th2/1 hybrid cells acting as IFN-γ-dependent confounders of type 2 responses. Hence, the distinct kinetics of effector cell recruitment to the infected gut and the quality of GATA-3+ T cell responses contribute to the genotype- and age-dependent resistance to intestinal nematode infections.

Peptide-Based Complex Coacervates Stabilized by Cation−π Interactions for Cell Engineering

Journal of the American Chemical Society Yue Sun, Xi Wu, Jianguo Li et al. Feb 05, 2025 DOI: 10.1021/jacs.4c14469

Inverse power XLindley distribution with statistical inference and applications to engineering data

Scientific Reports Amal S. Hassan, Najwan Alsadat, Christophe Chesneau et al. Feb 05, 2025 DOI: 10.1038/s41598-025-87023-6